气相色谱-质谱法同时测定河流沉积物中多环芳烃和有机氯农药

建立了用加速溶剂萃取,气相色谱-质谱法同时测定河流沉积物中16种多环芳烃和19种有机氯农药的分析方法,优化了萃取溶剂、萃取温度和时间、凝胶渗透色谱收集时间、固相萃取洗脱溶剂和洗脱体积等条件。16种多环芳烃的方法检出限在0.15~0.59 ng/g,加标回收率为82%~102%,相对标准偏差(RSD,n=5)为1.1%~4.5%。19种有机氯农药的方法检出限在0.14~2.23 ng/g,加标回收率为71%~108%,相对标准偏差(RSD,n=5)为1.0%~4.5%。实际样品的测定结果表明,该方法分离效果较好,能够满足沉积物样品中多环芳烃和有机氯农药的分析要求。     

新疆西克尔地区下奥陶统鹰山组岩溶分带性研究

塔里木盆地岩溶缝洞型储层作为重要的油气储层备受关注,而目前预测此类型储层的方法较有限。在新疆伽什县西克尔野外露头区地表岩溶现象丰富,志留系地层以填平补齐的方式充填在一系列的溶沟和溶槽中,部分洼地中还有志留系地层残留,表明该区发育加里东中期岩溶。在本区岩溶古地貌的基础上,基于排泄基准面的分析,划分出3级岩溶台面并对应发育3期岩溶。据现代地貌学和岩溶学理论,按照水动力条件的不同并结合本区岩溶发育特征,运用岩溶旋回的观点将第二期岩溶剖面分为表层岩溶带、垂直渗滤带和水平潜流带,认识到西克尔地区古岩溶地下水发育规律及洞穴发育程度。构造运动是垂向岩溶分带性的主控因素;因此,在大的构造背景的前提下,可以有效地预测巴楚地区的缝洞型储层。     

木本植被覆盖岸坡上波浪爬升过程的数值模拟研究

近岸木本植物构成的生态缓冲带作为新型的海岸软防护结构,兼具功能性和生态友好性,在沿海工程建设中愈发受到关注,如何深入开展其防护效果的机理研究是目前亟待解决的问题。本文采用数值模拟方法,在N-S方程中分别考虑树枝和树干的拖曳力影响,提出了木本植被作用下波浪沿斜坡爬升的表面波衰减的连续介质等效模型,并采用MAC法来跟踪自由曲面上的水颗粒轨迹。本文以波浪沿1/30的斜坡爬升为算例,对比讨论了有无植被作用下波浪的传播过程,并将算例结果与以往试验结果规律进行对照,验证了数值模型的有效性。最后,分别讨论了植物枝干的高度、密度、树枝倾斜角度等植被特性和波浪因素对植被消浪效果的影响,得到植被消浪的基本规律。文中的计算结果也可为实际的护岸工程和生态景观设计提供参考。     

Flow resistance adjustments of channel and bars in the middle reaches of the Yangtze River in response to the operation of the Three Gorges Dam

Journal of Geographical Sciences - Since the Three Gorges Dam (TGD) was put into operation, the flood water level at an identical discharge rate has not displayed a decreasing trend along the...     

北京天文台的WET三通道高速光度计

对北京天文台新近改造成的三通道高速光度计的结构和性能进行介绍,并给出了在兴隆站85公分望远镜的一些实测结果.     

巴黎能力建设委员会助力全球气候治理

在全球气候治理中,能力建设涉及减缓、适应等多个方面.相对于发达国家,发展中国家在应对气候变化能力方面存在更多挑战,也亟待支持.巴黎能力建设委员会(PCCB)是《联合国气候变化框架公约》(以下简称公约)下属能力建设议题唯一的常设机构.在《巴黎协定》的授权下, PCCB于2016年成立,致力于解决发展中国家在实施和加强应对...     

东北地区水稻障碍型低温冷害变化对区域气候增暖的响应

利用东北地区153个气象站1961—2010年逐日气温资料,采用统计学方法分析了水稻障碍型低温冷害的气候变化特征及其对区域气候变暖的响应情况。结果表明,东北大部地区水稻障碍型低温冷害事件呈减少趋势,但区域性较为明显;障碍型低温冷害对关键发育期气温变化响应较为敏感,二者呈显著的负相关关系,表现为气温每升高1 ℃,东北地区冷害减少35个站次。东北地区关键发育期气温均呈上升趋势,但吉林西部地区障碍型冷害却随之增加,分析了关键发育期气温变率和气候变率,将其解释为局地障碍型冷害增加主要受气候变率增大的影响,逐日气温变率对其影响不大。     

Comparison of parameter uncertainty analysis techniques for a TOPMODEL application

Parameter uncertainty in hydrologic modeling is crucial to the flood simulation and forecasting. The Bayesian approach allows one to estimate parameters according to prior expert knowledge as well as observational data about model parameter values. This study assesses the performance of two popular uncertainty analysis (UA) techniques, i.e., generalized likelihood uncertainty estimation (GLUE) and Bayesian method implemented with the Markov chain Monte Carlo sampling algorithm, in evaluating model parameter uncertainty in flood simulations. These two methods were applied to the semi-distributed Topographic hydrologic model (TOPMODEL) that includes five parameters. A case study was carried out for a small humid catchment in the southeastern China. The performance assessment of the GLUE and Bayesian methods were conducted with advanced tools suited for probabilistic simulations of continuous variables such as streamflow. Graphical tools and scalar metrics were used to test several attributes of the simulation quality of selected flood events: deterministic accuracy and the accuracy of 95 % prediction probability uncertainty band (95PPU). Sensitivity analysis was conducted to identify sensitive parameters that largely affect the model output results. Subsequently, the GLUE and Bayesian methods were used to analyze the uncertainty of sensitive parameters and further to produce their posterior distributions. Based on their posterior parameter samples, TOPMODEL’s simulations and the corresponding UA results were conducted. Results show that the form of exponential decline in conductivity and the overland flow routing velocity were sensitive parameters in TOPMODEL in our case. Small changes in these two parameters would lead to large differences in flood simulation results. Results also suggest that, for both UA techniques, most of streamflow observations were bracketed by 95PPU with the containing ratio value larger than 80 %. In comparison, GLUE gave narrower prediction uncertainty bands than the Bayesian method. It was found that the mode estimates of parameter posterior distributions are suitable to result in better performance of deterministic outputs than the 50 % percentiles for both the GLUE and Bayesian analyses. In addition, the simulation results calibrated with Rosenbrock optimization algorithm show a better agreement with the observations than the UA’s 50 % percentiles but slightly worse than the hydrographs from the mode estimates. The results clearly emphasize the importance of using model uncertainty diagnostic approaches in flood simulations.     

跨越断层埋地管线地震反应研究述评

本文论述了跨越断层埋地管线地震反应研究工作概况,包括理论研究和实验研究的进展,并介绍了不同情况下采用的研究方法和建立的相应的研究模型,通过对数据结果进行整理分析,得出跨越断层埋地管线地震反应规律。同时,本文还对埋地管线研究中的一些重要参数对研究结果的影响作了详尽的阐述,提出了需进一步研究的问题和今后可能的研究发展方向。