Composition,Structure, and Conditions of Formation of Fluorine-Bearing Sodalite: Experimental Evidence

Fluoro-sodalite was synthesized for the first time at temperatures of 400–800°C and H₂O pressures of 1–2 kbar in the Si–Al–Na–H–O–F system. X-ray diffraction and infrared spectroscopic investigations showed that fluorine is incorporated in the sodalite structure as anionic octahedral groups, [AlF₆]^3–, the number of which can vary from 0 to 1. Correspondingly, the end-members of the F-sodalite series are Na₇(H₂O)₈[Si₅Al₇O₂₄] and Na₈(AlF₆)(H₂O)₄[Si₇Al₅O₂₄]. Depending on the composition of the system, F-sodalite associates at 500–650°C with nepheline, albite, cryolite, and villiaumite, which are joined by analcime below 500°C and aluminosilicate melt above 650°C. Fluorine-bearing sulfate–chlorine-sodalite was found for the first time in a pegmatite sample from the Lovozero massif. The highest fraction of the fluorine end-member in natural sodalite is 0.2. The incorporation of F into the sodalite structure requires much more energy compared with Cl^– and SO ₄ ^2- , because it is accompanied by a structural rearrangement and a transition from tetrahedral Al to octahedral Al.     

Raman spectrum of natural and synthetic stishovite

Raman spectra of natural and synthetic samples of stishovite have been measured with a micro-optical spectrometer system. These spectra have a pattern that is characteristic of rutile-structured oxides. The spectrum of synthetic stishovite is characterized by well-resolved bands at 231, 589, 753, and 967 cm^?1, which are assigned as theB _1g,E _g,A _1g, andB _2g fundamentals, respectively, of the first-order Raman spectrum of the ideal, ordered structure. Natural stishovite obtained from Meteor Crater, Arizona has a first-order Raman spectrum that is fully consistent with that of the synthetic material. The observed spectrum of the natural sample, however, is weaker and has bands in addition to those identified as fundamentals in the spectrum of the synthetic material. A broad band at ～475 cm^?1 may be indicative of glass or contaminants derived from the extraction procedure. Alternatively, this band may arise from multiphonon scattering that is enhanced by poor crystallinity or structural disorder in the natural shocked sample.     

Distribution of some ions and minor gaseous components by concentrations in the atmospheric surface layer of some regions in Eastern Siberia and the Far East

We consider the resemblance between the ion composition of the fraction of soluble aerosols and gaseous admixtures in the atmospheric surface layer at the high-level Mondy station (East Sayan), those in the Listvyanka settlement south of Lake Baikal, in the city of Irkutsk, and at the Primorskaya station near the city of Ussuriysk (Primorskii krai). We use measurement data on the concentrations of the following ions: HCO ₃ ^? , SO ₄ ^2? , NO ₃ ^? , Cl^?, H⁺, Na⁺, K⁺, Mg²⁺, Ca²⁺ in the soluble fraction of aerosols and gases HNO₃, HCl, NH₃, and SO₂ in air samples over a 10-year period conducted in the mode of online monitoring. We found the lognormal form of distributions of concentrations of each of the abovementioned components according to the number of samples. A versatile scheme of the distribution of mean geometric concentrations of atmospheric components was proposed for all four groups.     

Three-dimensional hybrid modelling of soil-structure interaction

A three-dimensional hybrid model for the analysis of soil-structure interaction under dynamic conditions is developed which takes advantage of the desirable features of the finite element and substructure methods and which minimizes their undesirable features. The modelling is achieved by partitioning the total soil-structure system into a near-field and a far-field with a hemispherical interface. The near-field, which consists of the structure to be analysed and a finite region of soil around it, is modelled by finite elements. The semi-infinite far-field is modelled by distributed impedance functions at the interface which are determined by system identification methods. Numerical results indicate that the proposed model makes possible realistic and economical assessment of three-dimensional soil-structure interaction for both surface and embedded structures.     

Drag force on a circular cylinder in unseparated laminar high Reynolds number nonlinear random oscillatory flow

The stochastic properties of the drag force maxima on a circular cylinder subjected to nonlinear random waves are investigated. Unseparated laminar high Reynolds number flow is considered. A simplified approach based on second order Stokes waves is presented, including the sum-frequency effect only. It is demonstrated how a drag force formula valid for regular linear waves can be used to find the cumulative distribution function of individual drag force maxima for nonlinear irregular waves. Here the [Wang, 1968] drag force coefficient is used.     

Detailed spectroscopic investigation of Herbig-Haro object RNO 43N

Byurakan Astrophysical Observatory. Translated from Astrofizika, Vol. 36, No. 1, pp. 5–13, January–February, 1993.     

The depth distribution of hydrogen in lunar materials

A technique employing the resonant nuclear reaction ¹H(¹⁹F, αγ) ¹⁶O has been used to measure hydrogen concentration versus depth in selected coarse fine fragments from the Apollo 11 and Apollo 15 missions, and in glass coated surface chips from two Apollo 15 rocks. The highly variable hydrogen content in the coarse fine fragments is concentrated mainly in a layer extending from the surface to a depth of 2000 ± 500A?. The hydrogen content of the surface region of the Apollo 15 rock chips is comparable to that of the coarse fine samples, but is concentrated mainly within a few hundred angstroms of the surface. The hydrogen depth distribution in a piece of platinum foil from the Apollo 16 Lunar surface Cosmic Ray Experiment was also measured in an attempt to place a limit on the flux of 10–40 keV protons associated with a solar flare event.     

Growth of filamentous fungi in a surface-sealed woody substratum buried in salt-marsh sediments

Balsa wood panels were sealed to prevent oxygen diffusion from aerobic zones and buried in a North Carolina salt marsh to determine whether filamentous fungi could invade them despite the resulting anoxia. Results were similar to those of a previous study which had employed unsealed panels and suggest that fungi involved either are facultative microaerophiles or capable of translocating sufficient oxygen through their hyphae to permit growth into oxygen-deficient soil strata.