Methods of Analyzing Quinones in Water and their Application in Studying the Effects of Hydrophytes on Phenols. Part 2: Polarographic Methods of Quinone Analysis

After an outline of the possibilities and difficulties connected with the polarographic determination of aqueous quinone solutions, a specified oscillo-polarographic method of investigation is described. By the examples of solutions of pure substances as well as of the industrial waters of a pulp mill (up to 2.3 mg/1 total quinone) the conditions for applying the technique developed art' explained. The relative error of this method does not exceed 3%     

Application of the numerical manifold method for stress wave propagation across rock masses

In this paper, the numerical manifold method (NMM) is extended to study wave propagation across rock masses. First, improvements to the system equations, contact treatment, and boundary conditions of the NMM are performed, where new system equations are derived based on the Newmark assumption of the space–time relationship, the edge‐to‐edge contact treatment is further developed for the NMM to handle stress wave propagation across discontinuities, and the viscous non‐reflection boundary condition is derived based on the energy minimisation principle. After the modification, numerical comparisons between the original and improved NMM are presented. The results show that the original system equations result in artificial numerical damping, which can be overcome by the Newmark system equations. Meanwhile, the original contact scheme suffers some calculation problems when modelling stress wave propagation across a discontinuity, which can be solved by the proposed edge‐to‐edge contact scheme. Subsequently, the influence of the mesh size and time step on the improved NMM for stress wave propagation is studied. Finally, 2D wave propagation is modelled, and the model's results are in good agreement with the analytical solution. Copyright © 2013 John Wiley & Sons, Ltd.     

Response of vegetation pattern to different landform and water-table depth in Hailiutu River basin,Northwestern China

The spatial distribution of vegetation pattern and vegetation cover fraction (VCF) was quantified with remote sensing data in the Hailiutu River basin, a semiarid area in North China. The moderate resolution imaging spectroradiometer normalized different vegetation index (NDVI) values for 4 years from 2008 to 2011 and field observation data were used to assess the impact of climate factors, landform and depth to water table on vegetation distribution at large scale. In the VCF map, 74 % of the study area is covered with low and low–medium density vegetation, 24 % of the catchment is occupied by medium–high and high-density vegetation, and 2 % of area is bare soil. The relationship between NDVI and climate factors indicated that NDVI is correlated with relative humidity and precipitation. In the river catchment, NDVI increases gradually from landform of sand dune, eolian sand soil to river valley; 92.4 % of low NDVI from 0.15 to 0.3 is mostly distributed in sand dunes and the vegetation type is shrubs. Crops, shrubs and some dry willows dominate in eolian sand soil and 82.5 % of the NDVI varies between 0.2 and 0.35. In the river valley, 70.4 % of NDVI ranges between 0.25 and 0.4, and grass, dry willow and some crops are the main plants. Shrubs development of Korshinsk peashrub and Salix psammophila are dependent on groundwater by analyzing NDVI response to groundwater depth. However, NDVI of Artemisia desertorum had little sensitivity to groundwater.     

Geochemistry of Flood Basalts of the Toranmal Section, Northern Deccan Traps, India: Implications for Regional Deccan Stratigraphy

Tholeiitic lavas forming a flood basalt sequence of 870 m thicknessat Toranmal in the northern Deccan Traps have a large rangein isotopic ratios [     

Influences of mulching durations on soil erosion and nutrient losses in a peanut (Arachis hypogaea)-cultivated land

Plastic film mulching is widely employed to improve crop yields. Mulching for the entire crop growth period is a widespread practice. However, a shorter plastic film mulching duration is suggested for obtaining larger grain yield recently. To quantify the effects of plastic film mulching durations on soil erosion and nutrient losses, a three-treatment experiment with three replicates was constructed in field. The designed treatments were control (M0, non-mulched treatment), mulching from sowing to the end of the peanut pod-setting stage (M1) and pod-filling stage (M2). Plastic film mulching significantly increased the mean runoff and sediment yield. With film mulching, the mean runoff and soil losses among M1 and M2 treatments had no significant difference, and significantly larger than that in M0 treatment. After mulching removing, there were no significant differences between the mean runoff and soil losses of M0 and M1 treatments. Compared with the M2 treatment, the M0 treatment had significantly reduced mean runoff and soil losses of all the events. Non-mulching increased the total nitrogen (TN) and total phosphorus (TP) losses. The M0 treatment had the highest TN (23.0 mg m^?2) and TP (3.02 mg m^?2) losses in the three treatments. The M2 treatment significantly reduced the TN and TP losses. In conclusion, mulching from sowing to the end of pod-setting stage was suggested as the appropriate choice for the largest yield and less soil erosion. But, some soil conservation measurements should be taken in furrow areas to effectively reduce soil erosion, under the condition of film mulching.     

Palaeomagnetic results from the ca. 1130 Ma Borgmassivet intrusions in the Ahlmannryggen region of Dronning Maud Land, Antarctica, and tectonic implications

Detailed palaeomagnetic and rock magnetic analyses provide improved palaeomagnetic results from 23 sites in the Borgmassivet intrusions in the Ahlmannryggen region of Dronning Maud Land, East Antarctica. These intrusions are of similar age to their host, the ca. 1130 Ma Ritscherflya Supergroup (RSG). A mean direction of D=235.4°, I=−7.6° with k=45.9 and α₉₅=4.5° was obtained from this study. When combined with previously reported results from 11 sites in the same region, including sites from the Ritscherflya Supergroup, it gives an overall mean direction for 34 sites from the igneous suite with D=236.5°, I=−3.6°, k=27.9 and α₉₅=4.8°. Isothermal remanent magnetization (IRM) experiments on several specimens suggest magnetite or titanomagnetite as the primary remanence carrier, while high temperature magnetic susceptibility experiments indicate the presence of single domain particles. These observations, together with field evidence and the high coercivities and unblocking temperatures, support a primary origin for the observed characteristic remanence. The Borgmassivet palaeomagnetic pole lies at 54.5°E, 8.3°N with A₉₅=3.3°. If Antarctica is moved to its Gondwanan position adjacent to southeast Africa, the Borgmassivet pole (BM) coincides with that of the African well-established, well-dated (1100 Ma) Umkondo Large Igneous Province pole, supporting the hypothesis that the Grunehogna craton of Dronning Maud Land was part of the Kalahari craton of southern Africa at ca. 1100 Ma.     

Effects of key components of <Emphasis Type="Italic">S. triqueter</Emphasis> root exudates on fractions and bioavailability of pyrene–lead co-contaminated soils

The key components of S. triqueter root exudates involved 4-oxo-pentanoic acid, succinic acid, glutaric acid, phthalate acid, citric acid, vanillic acid, myristic acid, pentadecanoic acid, decanoic acid, 14-methyl-pentadecanoic acid, hexadecanoic acid, octadecanoic acid and oleic acid, and the content of the water-soluble organic acids (citric acid, succinic acid and glutaric acid) significantly increased in pyrene and lead co-contaminated rhizosphere soil. These three water-soluble organic acids including citric acid, succinic acid and glutaric acid were detected as the specific root exudates of S. triqueter under stress of pollutants for pyrene and lead, so they were chosen as the research objects, and they were added into the bioremediation systems of pyrene and lead co-contaminated wetland soils. Compared with the control, the treatments added the three organic acids always improved the quantity of the bioavailable fraction of pyrene and lead in wetland soils and greatly influenced other chemical states of pyrene and lead fractions in the test concentration range. Under the 50 g kg^?1 of organic acids concentration, the amount of the bioavailable fraction of pyrene and lead increased 41.0 and 872.7 % by citric acid, respectively. The enhancement of bioavailability of pyrene and lead in the wetland soil by adding organic acids generally decreased in the following order: citric acid > succinic acid > glutaric acid. Enhancing effects of organic acids on the bioavailability improvement of pyrene and lead is remarkable.     

Local responses in 2D assemblies of elliptical rods when subjected to biaxial shearing

Acta Geotechnica - This study explored the characteristics of local responses in 2D assemblies of elliptical particles when subjected to shearing. A biaxial shearing system was designed for this...