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901.
M. A. Akhmet’ev N. I. Zaporozhets A. I. Iakovleva G. N. Aleksandrova V. N. Beniamovsky T. V. Oreshkina Z. N. Gnibidenko Zh. A. Dolya 《Stratigraphy and Geological Correlation》2010,18(6):635-659
The analysis of the main biospheric events that took place in West Siberia and the Arctic region during the Early Paleogene
revealed the paleogeographic and paleobiogeographic unity of marine sedimentation basins and close biogeographic relations
between their separate parts. Most biotic and abiotic events of the first half of the Paleogene in the Arctic region and West
Siberia were synchronous, unidirectional, and interrelated. Shelf settings, sedimentation breaks, and microfaunal assemblages
characteristic of these basins during the Paleogene are compared. The comparative analysis primarily concerned events of the
Paleocene-Eocene thermal maximum (PETM) and beds with Azolla (aquatic fern). The formation of the Eocene Azolla Beds in the Arctic region and West Siberia was asynchronous, although it proceeded in line with a common scenario related
to the development of a system of estuarine-type currents in a sea basin partly isolated from the World Ocean. 相似文献
902.
Peculiarities and variations in the optical spectrum of the post-AGB star V448 Lac = IRAS 22223+4327
Multi-epoch observations with high spectral resolution acquired in 1998–2008 are used to study the time behavior of the spectral-line profiles and velocity fields in the atmosphere and circumstellar shell of the post-AGB star V448 Lac. Asymmetry of the profiles of the strongest absorption lines with lower-level excitation potentials χ low < 1 eV and time variations of these profiles have been detected, most prominently the profiles of the resonance lines of BaII, YII, LaII, SiII. The peculiarities of these profiles can be explained using a superposition of stellar absorption line and shell emission lines. Emission in the (0; 1) 5635 Å Swan system band of the C2 molecule has been detected in the spectrum of V448 Lac for the first time. The core of the Hα line displays radial-velocity variations with an amplitude of ΔV r ≈ 8 km/s. Radial-velocity variations displayed by weak metallic lines with lower amplitudes, ΔV r ≈ 1–2 km/s, may be due to atmospheric pulsations. Differential line shifts, ΔV r = 0–8 km/s have been detected on various dates. The position of the molecular spectrum is stationary in time, indicating a constant expansion velocity of the circumstellar shell, V exp = 15.2 km/s, as derived from the C2 and NaI lines. 相似文献
903.
Günther J. Redhammer Fernando Cámara Matteo Alvaro Fabrizio Nestola Gerold Tippelt Sebastian Prinz Jan Simons Georg Roth Georg Amthauer 《Physics and Chemistry of Minerals》2010,37(10):685-704
A synthetic clinopyroxene with composition LiFe3+Ge2O6, monoclinic s.g. P21/c, a = 9.8792(7), b = 8.8095(5), c = 5.3754(3) Å, β = 108.844(6)°, V = 442.75(16) Å3, has been studied by in situ low- and high-temperature single-crystal X-ray diffraction. The variation of lattice parameters and the intensity of the b-type reflections (h + k = 2n + 1, only present in the P-symmetry) with increasing temperature showed a displacive phase transition from space group P21/c to C2/c at a transition temperature T tr = 789 K, first order in character, with a sudden volume increase of 1.6% and a decrease of β by 1° at the transition. This spontaneous dilatation is reversible, shows a limited hysteresis of ±10°C, and corresponds to the vanishing of the b-type reflections, thus indicating a symmetry increase to space group C2/c. Below T tr an expansion is observed for all the cell parameters, while the β angle remained almost constant; at T > T tr the thermal volume expansion is due to dilatation of the structure in the $(\bar{1}\,0\,1) A synthetic clinopyroxene with composition LiFe3+Ge2O6, monoclinic s.g. P21/c, a = 9.8792(7), b = 8.8095(5), c = 5.3754(3) ?, β = 108.844(6)°, V = 442.75(16) ?3, has been studied by in situ low- and high-temperature single-crystal X-ray diffraction. The variation of lattice parameters
and the intensity of the b-type reflections (h + k = 2n + 1, only present in the P-symmetry) with increasing temperature showed a displacive phase transition from space group P21/c to C2/c at a transition temperature T
tr = 789 K, first order in character, with a sudden volume increase of 1.6% and a decrease of β by 1° at the transition. This spontaneous dilatation is reversible, shows a limited hysteresis of ±10°C, and corresponds
to the vanishing of the b-type reflections, thus indicating a symmetry increase to space group C2/c. Below T
tr an expansion is observed for all the cell parameters, while the β angle remained almost constant; at T > T
tr the thermal volume expansion is due to dilatation of the structure in the ([`1] 0 1)(\bar{1}\,0\,1) plane, mostly along [0 1 0], and pure shear in the (0 1 0) plane due to the decrease of β. From comparison with silicate analogues, the germanate clinopyroxenes are more expansible, while the P21/c expands more than the C2/c phase. The evolution of Q
2 (calculated as the normalized intensity of b-type reflections) with T in the framework of the Landau theory has been done using a standard expression for a first order phase transition. We observe
a jump of Q
02 = 0.538(2) at T
tr, with T
c of 481(7) K, b/a = −2,290 K, and c/a = 3,192 K, and thus far from being tri-critical point. A closely related composition (LiFe3+Si2O6) shows an equivalent phase transition at 228 K, which is very close to the tri-critical point and 561 K cooler. This result
indicates that a change in the composition of tetrahedral sites can have dramatic effects on the P21/c ↔ C2/c displacive phase transition in clinopyroxenes. The major changes observed in the evolution of the crystal structure with
T are observed in the M2 polyhedron, with a volume decrease by ca. 13.3%, compared to ca. 1.3% observed in the M1 polyhedron.
The tetrahedra behave as rigid units with neither a significant change of volume at T > T
tr (<1‰), nor a change of tilting of the basal plane. No change in coordination is observed at T > T
tr in the M2 polyhedron, which remains sixfold coordinated although a strong deformation of this polyhedron is observed. This
deformation is related to a strong change by 51.4° at T
tr of the kinking angle (O3–O3–O3 angle) of the B-chain of tetrahedra, which switches from O-rotated to S-rotated [from 143.3(5)°
to 194.7(6)°]. The A-chain is S-rotated at T < T
tr [206.8(5)° at 703 K] and extends by 12° at the transition. 相似文献
904.
In recent years, spatial variability modeling of soil parameters using random field theory has gained distinct importance in geotechnical analysis. In the present study, commercially available finite difference numerical code FLAC 5.0 is used for modeling the permeability parameter as spatially correlated log-normally distributed random variable and its influence on the steady state seepage flow and on the slope stability analysis are studied. Considering the case of a 5.0 m high cohesive–frictional soil slope of 30°, a range of coefficients of variation (CoV%) from 60 to 90% in the permeability values, and taking different values of correlation distance in the range of 0.5–15 m, parametric studies, using Monte Carlo simulations, are performed to study the following three aspects, i.e., (i) effect of stochastic soil permeability on the statistics of seepage flow in comparison to the analytic (Dupuit′s) solution available for the uniformly constant permeability property; (ii) strain and deformation pattern, and (iii) stability of the given slope assessed in terms of factor of safety (FS). The results obtained in this study are useful to understand the role of permeability variations in slope stability analysis under different slope conditions and material properties. 相似文献
905.
N.N. Kruk A.G. Vladimirov G.A. Babin S.P. Shokalsky N.V. Sennikov S.N. Rudnev N.I. Volkova V.P. Kovach P.A. Serov 《Russian Geology and Geophysics》2010,51(5):431-446
The history of the Vendian–Early Paleozoic formation of protoliths of continental crust in the Gorny Altai segment of the Central Asian fold belt is considered, and their composition, isotopic characteristics, and formation mechanisms are estimated. We have established two stages of crust-forming processes in Gorny Altai: Early and Late Caledonian, with the different structures of formed geoblocks and nature and compositions of crustal protoliths. At the Early Caledonian stage, fragments of oceanic lithosphere of basic composition (MORB, OIT, OIB) (TNd(DM-2st) = 0.65–1.1 Ga) formed, as well as island arcs with andesite-basaltic and andesitic protoliths with low contents of incompatible elements (TNd(DM-2st) = 0.7–0.9 Ga). At the Late Caledonian stage, the redistribution of the substance of these blocks and the external supply of material led to the formation of heterogeneous crust of turbidite basins with an oceanic basement and andesite-dacitic upper-crustal protoliths (TNd(DM-2st) varies from 0.8–0.9 Ga in the framing of the volcanic arc of Altaids to 1.4–1.6 Ga at the boundary of the Altai–Mongolian microcontinent). 相似文献
906.
P.A. Balykin G.V. Polyakov A.E. Izokh Tran Trong Hoa Ngo Thi Phuong Tran Quoc Hung T.E. Petrova 《Russian Geology and Geophysics》2010,51(6):611-624
The Jinping–Song Da rift structure in the Emeishan Large Igneous Province is composed of Permian high- and low-Ti volcanic and volcanoplutonic ultramafic-mafic associations of different compositions and genesis. High-Ti picrites, picrobasalts, basalts, and dolerites are enriched in LREE and depleted in HREE and show low Al2O3/TiO2 ratios (~4), commensurate εNd(T) values (+0.5 to +1.1), and low (Th/Nb)PM ratios similar to those of OIB-enriched mantle source. The established geochemical characteristics evidence that the parental melts of these rocks were generated from garnet lherzolite at the depths of garnet stability (~200 to 400 km). Later, high-Mg low-Ti volcanics (komatiites, komatiitic basalts, and basalts) and associating small peridotite-gabbro massifs and komatiite-basalt dikes were produced as a result of ~20% partial melting of depleted water-poor (≤0.03 wt.% H2O) peridotite substratum from the hottest upper part of mantle plume at relatively shallow depths (100–120 km). The LREE-depleted komatiites and komatiitic basalts are characterized by low (Ce/Yb)CH values, 187Re/188Os = 0.05–1.2, 87Sr/86Sr = 0.704–0.706, positive εNd(T) values (+3 to +8), γOs = –0.5 to +0.9, and strong negative anomalies of Ba, K, and Sr on the spidergrams. The scarcer LREE-enriched komatiites, komatiitic basalts, and basalts vary greatly in chemical composition and values of εNd(t) (+6.4 to –10.2), 87Sr/86Sr (0.706–0.712), and γOs (+14.8 to +56), which is due to the different degrees of crustal contamination of parental magmas. The Rb-Sr isotopic age of basaltic komatiite is 257 ± 24 Ma. The Re-Os age determined by analysis of 12 komatiite samples is 270 ± 21 Ma. These data agree with the age of flood basalts of the Emeishan Large Igneous Province. The komatiite-basalt complex of the Song Da rift is still the only Phanerozoic PGE-Cu-Ni-complex of this composition. The geochemistry of accompanying Cu-Ni-PGE-ores confirms their relationship with komatiite-basaltic magmatism. 相似文献
907.
The Laverton region, located in the eastern Yilgarn Craton (EYC) Western Australia, is second only to the Kalgoorlie region for gold endowment. The integration of high-density, potential-field data, regional- and camp-scale seismic reflection data, regional- and mine-scale structural analysis, and geochronologically-constrained stratigraphy, provided new insights into the 4D architecture and tectonic evolution of Laverton region. 相似文献
908.
909.
在回顾变质矿物共生组合和变质反应图解分析法的基础上,论述了录求变质矿物组合之间、同一组合内矿物之间的平衡变质反应的代数方法,即矩阵高斯变换,线性回归分析、矩阵奇值分解。 相似文献
910.
黄铁矿表面及其与Au(HS)2^—溶液作用的STM研究 总被引:5,自引:0,他引:5
本文用STM研究了黄铁矿和方铅矿表面的原子结构、纳米级微形貌、电子态分布及其吸附态的特点。STM电流图象揭示了表面缺陷与表面电子态之间的对应关系,硫化和的表面的化学反应活性可能是表现缺陷引起的局域导电性增强有关。STM观察进一步表明黄铁矿和方铅矿对金的硫氢配合物的吸附作用优先发生于扭折位和台阶边缘等高能部位,反映出吸附态的分布也是与表面电子态分布相对应的。这样就从微观领域考证了硫化物表面对化学活性 相似文献