Mamaku Ignimbrite: a caldera-forming ignimbrite erupted from a compositionally zoned magma chamber in Taupo Volcanic Zone, New Zealand

Mamaku Ignimbrite was deposited during the formation of Rotorua Caldera, Taupo Volcanic Zone, New Zealand, 220–230 ka. Its outflow sheet forms a fan north, northwest and southwest of Rotorua, capping the Mamaku–Kaimai Plateau. Mamaku Ignimbrite can be divided into a partly phreatomagmatic basal sequence, and a main sequence which comprises lower, middle, and upper ignimbrite. The internal stratigraphy indicates that it was emplaced progressively from a pyroclastic density current of varying energy that became less particulate away from source. Gradational contacts between lower, middle, and upper ignimbrite are consistent with it being deposited during one eruptive event from the same source. Variations in lithic clast content and coexistence of different pumice types through the ignimbrite sequence indicate that caldera collapse occurred throughout the eruption, but particularly when middle Mamaku Ignimbrite was deposited and in the final stages of deposition of upper Mamaku Ignimbrite. Maximum lithic data and the location of lithic lag breccias in upper Mamaku Ignimbrite confirm Rotorua Caldera as the source. At least 120 m of geothermally altered intra-caldera Mamaku Ignimbrite occurs inside Rotorua Caldera. Pumice clasts in the Mamaku Ignimbrite are dacite to high-silica rhyolite and can be chemically divided into three types: high–silica rhyolite (type 1), rhyolite (type 2), and dacite (type 3). All are petrogenetically related and types 1 and 2 may be derived by up to 20% crystal fractionation from the type 3 dacite. All three types probably resided in a single, gradationally zoned magma chamber. Andesitic juvenile fragments are found only in upper Mamaku Ignimbrite and inferred to represent a discrete magma that was injected into the silicic chamber and is considered to have accumulated as a sill at the base of the magma chamber. The contrast in density between the andesitic and silicic magmas did not allow eruption of the andesitic fragments during the deposition of lower and middle Mamaku Ignimbrite. The advanced stage of caldera collapse, late in the main eruptive phase, created withdrawal dynamics that allowed andesitic magma to reach the surface as fragments within upper Mamaku Ignimbrite.     

Geographies of knowledge, practices of globalization: learning from the oil exploration and production industry

In this paper we initiate a dialogue between work on the geographies of globalization and knowledge economies, areas of inquiry that have tended to develop in isolation. We argue for a critical harnessing of these two bodies of work to (1) understand how and where different types of knowledge are acquired, produced and mobilized by firms as they seek to 'go global', (2) map the multi-scalar geographies of knowledge that enable practices of globalization and (3) examine the ways in which networks of knowledge structure emerging geographies of production. We demonstrate the potential of this move using oil exploration and production as an example.     

The nature, origin and physicochemical controls of hydrothermal Mo-Bi mineralization in the Cadillac deposit, Quebec, Canada

Mo-Bi mineralization occurs in subvertical and subhorizontal quartz-muscovite-± K-feldspar veins surrounded by early albitic and later K-feldspathic alteration halos in monzogranite of the Archean Preissac pluton, Abitibi region, Québec, Canada. Molybdenite is intergrown with muscovite in the veins or associated with K-feldspar in the alteration halos. Mineralized veins contain five main types of fluid inclusions: aqueous liquid and liquid-vapor inclusions, aqueous carbonic liquid-liquid-vapor inclusions, carbonic liquid and vapor inclusions, halite-bearing aqueous liquid and liquid-vapor inclusions, trapped mineral-bearing aqueous liquid and liquid-vapor inclusions. The carbonic solid in frozen carbonic and aqueous-carbonic inclusions melts in most cases at −56.7 ± 0.1 °C indicating that the carbonic fluid consists largely of CO₂. All aqueous inclusion types and the aqueous phase in carbonic inclusions have low initial melting temperatures (≥70 °C), requiring the presence of salts other than NaCl. Leachate analyses show that the bulk fluid contains variable proportions of Na, K, Ca, Cl, and traces of Mg and Li. The following solids were identified in the fluid inclusions by SEM-EDS analysis: halite, calcite, muscovite, millerite (NiS), barite and antarcticite (CaCl₂ · 6H₂O). All are interpreted to be trapped phases except halite which is a daughter mineral, and antarcticite which formed during sample preparation (freezing). Aqueous inclusions homogenize to liquid at temperatures between 75 °C and 400 °C; the mode is 375 °C. Aqueous-carbonic inclusions homogenize to liquid or vapor between 210 °C and 400 °C. Halite-bearing aqueous inclusions homogenize by halite dissolution at approximately 170 °C. Aqueous inclusions containing trapped solids exhibit liquid-vapor homogenization at temperatures similar to those of halite-bearing aqueous inclusions. Temperatures of vein formation, based on oxygen isotopic fractionation between quartz and muscovite, range from 342 °C to 584 °C. The corresponding oxygen isotope composition of the aqueous fluid in equilibrium with these minerals ranges from 1.2 to 5.5 per mil with a mean of 3.9 per mil, suggesting that the liquid had a significant meteoric component. Isochores for aqueous fluid inclusions intersect the modal isotopic isotherm of 425 °C at pressures between 590 and 1900 bar. A model is proposed in which molybdenite was deposited owing to decreasing temperature and/or pressure from CO₂-bearing, moderate to high salinity fluids of mixed magmatic-meteoric origin that were in equilibrium with K-feldspar and muscovite. These fluids resulted from the degassing of a monzogranitic magma and evolved through interaction with volcanic (komatiitic) and sedimentary country rocks. Received: 6 February 1997 / Accepted: 28 January 1998     

Evaluation of Hydrologically Relevant PCM Climate Variables and Large-Scale Variability over the Continental U.S.

The ability of the Parallel Climate Model (PCM) to reproduce the mean and variability of hydrologically relevant climate variables was evaluated by comparing PCM historical climate runs with observations over temporal scales from sub-daily to annual. The domain was the continental U.S, and the model spatial resolution was T42 (about 2.8 degrees latitude by longitude). The climate variables evaluated include precipitation, surface air temperature, net surface solar radiation, soil moisture, and snow water equivalent. The results show that PCM has a winter dry bias in the Pacific Northwest and a summer wet bias in the central plains. The diurnal precipitation variation in summer is much stronger than observed, with an afternoon maximum in summer precipitation over much of the U.S. interior, in contrast with an observed nocturnal maximum in parts of the interior. PCM has a cold bias in annual mean temperature over most of the U.S., with deviations as large as ?8 K. The PCM daily temperature range is lower than observed, especiallyin the central U.S. PCM generally overestimates the net solar radiation over most of the U.S, although the diurnal cycle is simulated well in spring, summer and winter. In autumn PCM has a pronounced noontime peak in solar radiation that differs by 5–10% from observations. PCM'ssimulated soil moisture is less variable than that of a sophisticated land-surface hydrology model, especially in the interior of the country. PCM simulates the wetter conditions over the southeastern U.S. and California during warm (El Niño) events, but shifts the drier conditions in the PacificNorthwest northward and underestimates their magnitude. The temperature response to the North Pacific Oscillation is generally captured by PCM, but the amplitude of this response is overestimated by a factor of about two.     

Timing of volcanic, plutonic and geothermal activity at Ngatamariki, New Zealand

Four ⁴⁰Ar/³⁹Ar dates on mineral separates from fresh and hydrothermally altered volcanic and plutonic rocks from the Ngatamariki geothermal field indicate that andesitic volcanism took place in the eastern portion of the Taupo Volcanic Zone (TVZ) prior to 1.2 Ma and probably considerably earlier. These data significantly extend the onset and duration of andesitic volcanism in the east-central TVZ over previous estimates. Intrusive activity is represented at Ngatamariki by a dioritic pluton, the only such pluton yet recognized in the entire TVZ. Hornblende from the pluton yields a crystallization age of near 550 ka. Hydrothermal alteration spatially associated with the pluton produced sericite of a similar age. Overlying and postdating the most intense hydrothermal alteration zone is the Whakamaru Ignimbrite (or its equivalent) which was emplaced at 330 ka. Two distinct geothermal systems may have been active at nearly the same site from 550 ka to present. The most intense activity occurred before 330 ka and was associated with emplacement of the Ngatamariki diorite. This was followed by the less intense system that is currently active. The geothermal regime at Ngatamariki has, therefore, probably been active intermittently for at least 550 ka.     

Early 20th-century uplift of the northern Peninsular ranges province of southern California

Repeated leveling in the northern Peninsular Ranges province identifies an early 20thcentury episode of crustal upwarping in southern California. The episodic vertical movement is broadly bracketed between 1897 and 1934, and the main deformation is bracketed within 1906–1914 and involved regional up-to-the-northeast tilting of the Santa Ana block of as much as 4 · 10⁻⁶ rad and elevation changes exceeding 0.4 m in the Perris block and parts of the San Jacinto block, Transverse Ranges, and the Mohave block. Primary tide station records containing occasional entries since 1853 at San Pedro and San Diego show no evidence of episodic crustal movement, suggesting that the uplifted area hinged along coastal fault zones forming the west boundary of the Santa Ana block.Physiographic features and recent studies of Quaternary marine terraces by others show that this episode of regional tilting and uplift is a part of the continuing tectonic process in southern California. A crude, questionable coincidence exists between the uplift episode and a period of increased seismicity (1890–1923) in the northern Peninsular Ranges characterized by a number of moderate-size (M > 6) earthquakes on NW-trending strike-slip faults. However, releveling data are too sparse to associate the uplift development clearly with any one event.