Wind Flow Over Complex Terrain: A Historical Perspective and the Prospect for Large-Eddy Modelling

The development of our understanding of turbulent flow overcomplex terrain is described. Despite considerable advances, there are still gaps in our knowledge. Large-eddy simulation of such flows is now becoming possible. This may stimulate further advances but it is computationally very demanding. The application of this technique to flow over hills is discussed.     

Solar Models with Dynamic Screening and Early Mass Loss Tested by Helioseismic,Astrophysical, and Planetary Constraints

The faint young Sun paradox remains an open question. Presented here is one possible solution to this apparent inconsistency, a more massive early Sun. Based on the conditions on early Earth and Mars, a luminosity constraint is set as a function of mass. We examine helioseismic constraints of these alternative mass-losing models. Additionally, we explore a dynamic electron screening correction in an effort to improve helioseismic agreement in the core of the early mass-losing model.     

Turbulent Form Drag On Anisotropic Three-Dimensional Orography

Results are presented from a large number of numerical simulations performed to investigate the dependence of the turbulentform drag on three-dimensional ellipsoidal hills upon aspect ratio and wind direction. For isolatedisotropic hills the results are, as expected, found to beindependent of wind direction. However directionaldependence rapidly becomes important as the ridges are elongated,and the results quickly converge onto those obtained in the limitingcase of two-dimensional ridges. Based on the numerical results,a simple parametrization of the drag is proposed.     

Intellectuals in the Public: Uniting a Divided Baltimore

The University of Baltimore offered a community-based course following the Baltimore unrest in 2015. The course, which we called Divided Baltimore, engaged scores of students and community members together in a weekly forum of presentations and hard discussion. It focused on how Baltimore became segregated, how segregation affects all Baltimoreans, and what we could do about it. I discuss how the course worked, what we learned, and how we were able to pull off the course in short order. The key to what we accomplished was having built community partnerships around structural racism and racial equity in Baltimore over a period of several years before 2015. The lesson is that we can all do this—all be intellectuals in the public—if first we invest the time, our talents, and our intellectual energy in community engagement.     

Brown trout (Salmo trutta) removal by rotenone alters zooplankton and phytoplankton community composition in a shallow mesotrophic reservoir

Brown trout (Salmo trutta) are known to have effects on multiple trophic levels in New Zealand streams, but their impacts on lower trophic levels are less well understood within lentic systems. We examined the effects of brown trout removal using rotenone on zooplankton and phytoplankton community composition in the Upper Karori Reservoir, New Zealand. Significant shifts were observed in zooplankton and phytoplankton composition following removal of brown trout from the reservoir. Shifts in zooplankton community composition did not occur immediately following trout removal (February), but instead followed the likely timing of galaxiid spawning (July). The removal of brown trout likely resulted in reduced predation pressure on galaxiids. A major change occurred in the zooplankton community with the dominance shifting from larger crustaceans to smaller rotifers, indicating an increased predation pressure from the larval native galaxiid. A delayed response in zooplankton community composition change indicates rotenone was not the direct cause of this. A major shift in phytoplankton community composition occurred immediately following trout removal. This was not consistent with the trophic cascade hypothesis of reduced grazing pressure from larger zooplankton due to increased galaxiid predation as a result of brown trout removal.     

Freshwater bryozoans of New Zealand: A preliminary survey

Five bryozoan species were encountered in a 15‐day survey of freshwater habitats in New Zealand. Listed in order of decreasing frequency these were: Fredericella sultana, Plumatella repens, P. emarginata, Paludicella articulata, and one plumatellid species not previously described. Micro‐structural features of the floatoblast annulus separate the P. repens specimens into two distinct varieties, named here P. repens typica and P. repens rugosa. Paludicella, reported almost 100 years ago from the City of Dunedin waterworks, was still found only in a single reservoir of that city. Species distribution did not correlate significantly with water temperature, current velocity, pH, or total dissolved solids. Two additional species believed to occur in New Zealand, Fredericella australiensis and Plumatella fungosa, were not seen in this brief survey. An identification key is provided for New Zealand bryozoans.     

Activities and volatilities of trace components in silicate melts: a novel use of metal–silicate partitioning data

Ian Carmichael spent 45 years thinking about and working on the activities of components in silicate melts and their use to estimate physicochemical conditions at eruption and in the source regions of igneous rocks. These interests, principally in major components such as SiO₂, led us to think about possible ways of determining the complementary activity coefficients of trace components in silicate melts. While investigating the conditions of accretion and differentiation of the Earth, a number of authors have determined the partitioning of trace elements such as Co, Ni, Mo and W between liquid Fe metal and liquid silicate. These data have the potential to provide activity information for a large number of trace components in silicate melts. In order to turn the partitioning measurements into activities, however, we need to know the activity coefficient of FeO, γ_FeO in the silicate. We obtained γ_FeO as a function of melt composition by fitting a simple model to 83 experimental data for which the authors had measured the FeO content of the silicate melt in equilibrium with metal (Fe-bearing alloy) at known f_O2. The compositional dependence of γ_FeO is weak, but, when calculated in the system Diopside–Anorthite–Forsterite, it decreases towards the Forsterite apex. A similar approach for Ni, for which twice as many data are available, leads to similar composition dependence of activity coefficient and confirms the suggestion that γ_NiO/γ_FeO is almost constant over a wide range of silicate melt composition. The activity coefficients for FeO were used in conjunction with measured Mo and W partitioning between Fe-rich metal and silicate melt to estimate activity coefficients for trace MoO₂ and WO₃ dissolved in silicate melt. When combined with data on Mo- and W-saturated silicate melts a strong dependence of activity coefficient is observed. Calculated in the system Diopside–Anorthite–Forsterite, both MoO₂ and WO₃ exhibit similar behaviour to FeO and NiO in that activity coefficients decrease as Forsterite content increases. The effect is much larger for Mo and W, however, γ_MoO2 and γ_WO3 varying by factors of 20 and nearly 100, respectively, in this system. In order to illustrate the potential applications of the metal–silicate partitioning approach to determine the activity coefficients of volatile elements, we used it to determine activity coefficients of PbO, CuO_0.5 and InO_1.5 in a silica-saturated melt at 1,650 °C. We find values of 0.22, 3.5 and 0.02, respectively, indicating a strong dependence on cation charge. The value for CuO_0.5 is in excellent agreement with experimental data of Holzheid and Lodders (Geochim Cosmochim Acta 65:1933–1951, 2001), which shows that the method is viable. When combined with thermodynamic data on the gas species, we find that Pb is the most volatile of the 3 elements under ‘normal’ terrestrial conditions of oxygen fugacity but that In should become the most volatile under strongly reducing conditions such as those of the solar nebula. The oxygen fugacity dependence of volatility has implications for the high relative abundance of In in silicate Earth. We conclude that metal–silicate partitioning experiments are a viable means for determining activities of trace components in silicate melts and are particularly useful if the metal of the element is unstable or volatile at igneous temperatures.     

Estimating Organic-Rich Shale Fractal Dimensions from Gas Adsorption Isotherms: Combining Different Methods Leads to More Reliable Values and Insight

Fabric and roughness of the pore-size distributions in organic-rich shales determine their fluid flow and storage capabilities. Accurate estimation of the pore-surface fractal dimension (D) provides valuable insight to these qualities in shales. Low-pressure gas adsorption isotherms are widely used for determining D, typically applying the Frenkel–Halsey–Hill (FHH) method. Other D estimation methods, proposed by Neimark (NM) and Wang and Li (WL), are theoretically consistent and mathematically related to the FHH model but yield distinctive D values for many shales. This study evaluates the mathematical relationships between the FHH, NM and WL fractal determination methods, and with the aid of twenty-six published adsorption isotherms from shales around the world, compares their similarities and differences. Uncertainties exist in establishing best-fit lines to curved data trends in the FHH and NM methods, and in fitting power curves to data trends in the NM and WL methods. The FHH and WL D values are found to be more consistent for whole isotherm and isotherm segment analysis than the NM D values, which are systematically higher. The reasons for this are explained in terms of their graphical relationships. This leads to a novel 10-step protocol for a more thorough determination of shale D values that incorporates all three methods and involves graphical analysis that clearly exposes the uncertainties associated with the values determined. Applying this protocol should derive reliable D values to compare with key shale properties such as surface area, surface volume, thermal maturity and organic richness in future research.