The influence of sea waves on the wind profile

From wind profile and wave measurements performed during the JONSWAP II experiment, relations between the dimensionless profile slope and the significant wave height are derived. It is shown that the wind profile is distorted by the waves especially in the vicinity of the water surface. The wave influence on the profile seems to be restricted to heights below about three wave heights. Above this level, the dimensionless profile slope is an approximately constant value corresponding to a drag coefficient of about 1.15 × 10^–3.     

The tritium and carbon-14 profiles at the Geosecs I (1969) and GOGO I (1971) North Pacific stations

Tritium and¹⁴C data of the “GOGO I” station at 28.5°N, 121.6°W in November 1971 are reported. The tritium decline between 150 and 350 m depth is as pronounced as was observed on a previous occupation of the same position, station “Geosecs I” in September 1969, and the tritium concentrations below 200 m are unchanged.¹⁴C data from the depth range of tritium decline are corrected for fallout¹⁴C contribution. The correcting procedure requires simultaneous measurements of¹⁴C, ΣCO₂, and tritium. It is concluded that the natural absolute¹⁴C concentration attains a maximum near 400 m depth, of 7.5% excess over that of surface water.     

Tectonic implications of new U–Pb zircon ages of the Ladakh batholith,Indus suture zone,northwest Himalaya,India

We determined U–Pb ages on zircons from Ladakh granitoid samples of three previously undated plutons and deduced four distinct age groups between c. 67 and c. 45 Ma (66.6 ± 2.1, 57.6 ± 1.4, 53.4 ± 1.8, 52.50 ± 0.53 and 45.27 ± 0.56 Ma). This suggests that the Ladakh batholith grew by addition of at least four distinct subduction‐related magma pulses at c. 67, 58, 53 and 45 Ma, thus indicating that the belt was continuously active throughout the Palaeocene and the Middle Eocene (Lutetian). The 45.27 ± 0.56 Ma pluton at Daah‐Hanu is the last major calcalkaline arc magmatic pulse in the Ladakh batholith. Thereafter, the subduction‐related major plutonism gradually waned. The earlier estimate for the youngest pluton within the Ladakh batholith is 49.8 ± 0.8 Ma for the Leh pluton ( J. Geol., 2000, 108 , 303 ).     

Water source characterization through spatiotemporal patterns of major,minor and trace element stream concentrations in a complex,mesoscale German catchment

The link between spatiotemporal patterns of stream water chemistry and catchment characteristics for the mesoscale Dill catchment (692 km²) in Germany is explored to assess the catchment scale controls on water quality and to characterize water sources. In order to record the spatiotemporal pattern, ‘snapshot sampling’ was applied during low, mean and high flow, including 73 nested sites throughout the catchment. Water samples were analysed for the elements Li, B, Na, Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Mo, Ba, Pb and U using inductively‐coupled‐plasma mass spectrometry, and for electric conductivity and pH. Principle component analysis and hierarchical cluster analysis were used to find typical element associations and to group water samples according to their hydrochemical fingerprints. This revealed regional hydrochemical patterns of water quality which were subsequently related to catchment attributes to draw conclusions about the controls on stream chemistry. It was found that various lithologic signals and anthropogenic point source inputs controlled the base flow hydrochemistry. During increased flows, stream waters were diluted causing additional hydrochemical variability in response to heterogeneous precipitation inputs and differences in aquifer storage capacities. The hydrochemical patterns further displayed in‐stream mixing of waters. This implied, that stream waters could be apportioned to the identified water sources throughout the catchment. The basin‐wide hydrochemical variability has the potential to outrange the tracer signatures typically inferred in studies at the hillslope scale and is able to strongly influence the complexity of the catchment output. Both have to be considered for further catchment scale tracer and modelling work. Despite the likelihood of non‐conservative behaviour, the minor and trace elements enhanced the rather qualitative discrimination of the various groundwater types, as the major cations were strongly masked by point source inputs. Copyright © 2007 John Wiley & Sons, Ltd.     

Diet of Haplognathia ruberrima (Gnathostomulida) in a Caribbean marine mangrove

Haplognathia ruberrima is a cosmopolitan gnathostomulid species found in sulfur bacterial mats in mangroves in Guadeloupe (French West Indies). Haplognathia ruberrima presents a δ¹³C value lower than all measured meiofaunal grazers and lower than the available measured food sources of this environment. This low δ¹³C value can not be due to specific ingestion of ¹³C‐depleted methanogenic bacteria because abundances of those bacteria are reduced in surficial and deep sediments as revealed by δ¹³C of bacterial fatty acid. According to scanning electron microscope observations, no bacterial ectosymbionts were observed at the surface of the gnathostomulids, and transmission electron microscope views revealed the absence of bacterial endosymbionts. Energy‐dispersive X‐ray spectroscopy analysis detected low levels of sulfur (0.32%±0.8) in biological tissues of H. ruberrima, confirming the absence of thioautotrophic bacterial symbionts in these animals. Consequently, the low δ¹³C value of H. ruberrima can not be due to the presence of sulfur‐oxidizing symbionts but more probably to the selective and exclusive consumption of free‐living, sulfur‐oxidizing bacteria.     

Hotspot distribution, gravity, mantle tomography: evidence for plumes

Thermal convection is the motor of Earth dynamics and therefore is the link between plate motions, hotspots, seismic velocity variations in the mantle, and anomalies of the gravity field. Small scale mantle anomalies, such as plumes, do, however, generally escape detection by tomographic methods. It is attempted to approach the problem of detection in a somewhat statistical manner. Correlations are sought between spherical harmonic expansions of the fields under study: the hotspot distribution, mantle velocity variations, gravity, heat flow. Using spherical harmonic representations of global fields implies integration and averaging over the whole globe. Thus, although relationships may remain masked in the space domain by a multitude of effects, tendencies may become visible in the spectra or in appropriate averages.The main results are the following: There is a significant long wavelength (n=2,3) negative correlation between the hotspot density and the P-wave velocity variation in the lower mantle. Positive hotspot density of degree 2 to 9 generally correlates with low seismic velocity in all depths of the upper mantle and with positive gravity. This fits well with plume-type convection. These results are also confirmed regionally for a number of individual mid-ocean ridges and hotspots. The hotspot density and the free air anomalies are distinctly positive above regions of low velocity extending to great depth. The effect is not distinct at ridges with shallow velocity anomalies. In a general way, we suggest that the antipodal upwellings (Pacific, Africa) are divided by downwelling currents around the shrinking Pacific. Plate boundaries can easily move away from their past connections with the deeper mantle. Small scale plume currents seem to be depicted in the hotspot expansion. © 1999 Elsevier Science Ltd. All rights reserved.     

The Kabanga Ni sulfide deposit, Tanzania: I. Geology, petrography, silicate rock geochemistry, and sulfur and oxygen isotopes

The Kabanga Ni sulfide deposit represents one of the most significant Ni sulfide discoveries of the last two decades, with current indicated mineral resources of 23.23 Mt at 2.64% Ni and inferred mineral resources of 28.5 Mt at 2.7% Ni (Nov. 2008). The sulfides are hosted by a suite of ∼1.4 Ga ultramafic–mafic, sill-like, and chonolithic intrusions that form part of the approximately 500 km long Kabanga–Musongati–Kapalagulu igneous belt in Tanzania and Burundi. The igneous bodies are up to about 1 km thick and 4 km long. They crystallized from several compositionally distinct magma pulses emplaced into sulfide-bearing pelitic schists. The first magma was a siliceous high-magnesium basalt (approximately 13.3% MgO) that formed a network of fine-grained acicular-textured gabbronoritic and orthopyroxenitic sills (Mg# opx 78–88, An plag 45–88). The magma was highly enriched in incompatible trace elements (LILE, LREE) and had pronounced negative Nb and Ta anomalies and heavy O isotopic signatures (δ¹⁸O +6 to +8). These compositional features are consistent with about 20% contamination of primitive picrite with the sulfidic pelitic schists. Subsequent magma pulses were more magnesian (approximately 14–15% MgO) and less contaminated (e.g., δ¹⁸O +5.1 to +6.6). They injected into the earlier sills, resulting in the formation of medium-grained harzburgites, olivine orthopyroxenites and orthopyroxenites (Fo 83–89, Mg# _opx 86–89), and magmatic breccias consisting of gabbronorite–orthopyroxenite fragments within an olivine-rich matrix. All intrusions in the Kabanga area contain abundant sulfides (pyrrhotite, pentlandite, and minor chalcopyrite and pyrite). In the lower portions and the immediate footwall of two of the intrusions, namely Kabanga North and Kabanga Main, there occur numerous layers, lenses, and veins of massive Ni sulfides reaching a thickness of several meters. The largest amount of high grade, massive sulfide occurs in the smallest intrusion (Kabanga North). The sulfides have heavy S isotopic signatures (δ³⁴S wr = +10 to +24) that broadly overlap with those of the country rock sulfides, consistent with significant assimilation of external sulfur from the Karagwe–Ankolean sedimentary sequence. However, based partly on the relatively homogenous distribution of disseminated sulfides in many of the intrusive rocks, we propose that the Kabanga magmas reached sulfide saturation prior to final emplacement, in staging chambers or feeder conduits, followed by entrainment of the sulfides during continued magma ascent. Oxygen isotope data indicate that the mode of sulfide assimilation changed with time. The heavy δ¹⁸O ratios of the early magmas are consistent with ingestion of the sedimentary country rocks in bulk. The relatively light δ¹⁸O ratios of the later magmas indicate less bulk assimilation of the country rocks, but in addition the magmas selectively assimilated additional S, possibly through devolatization of the country rocks or through cannibalization of magmatic sulfides deposited in the conduits by preceding magma surges. The intrusions were tilted at ca. 1.37 Ga, during the Kibaran orogeny and associated synkinematic granite plutonism. This caused solid-state mobilization of ductile sulfides into shear zones, notably along the base of the intrusions where sulfide-hornfels breccias and lenses and layers of massive sulfides may reach a thickness of >10 m and can extend for several 10 s to >100 m away from the intrusions. These horizons represent an important exploration target for additional nickel sulfide deposits.     

Modelling of paleo-saltwater intrusion in the northern part of the Nubian Aquifer System, Northeast Africa

A numerical groundwater model of the Nubian Aquifer System was established to prove the influence of rising seawater levels on the groundwater salinity in northern Egypt over the last 140,000 years. In addition, the impact of a groundwater recharge scenario for these 140,000 years, involving climatic change, on the saltwater/freshwater interface was investigated. Saltwater intrusion induced by rising water levels of the Mediterranean Sea led to salinisation from the Mediterranean Sea to the Qattara depression. This modeling approach was supported by a density-driven model setup and calculation. The modelled saltwater/freshwater interfaces partially fitted the observed ones, especially in the southern half of the Qattara depression. In other parts of the northern Nubian Aquifer System, the ingression of salt water was modelled adequately, but in the west, small regions of the measured interface were not. The development in the Qattara depression (Egypt) and Sirte basin (Libya) were investigated in more detail. The different behaviour in the Sirte basin may be due to high evapotranspiration rates in some former periods, salt solutions from the pre-Quaternary layers or saltwater infiltration from sabkha-like recent salt-bearing sediments.     

Zircon Hf isotope perspective on the origin of granitic rocks from eastern Bavaria, SW Bohemian Massif

The petrogenetic potential of in situ laser ablation Hf isotope data from melt precipitated zircons was explored through the analyses of about 700 individual crystals derived from about 20 different granitic intrusions covering the Variscan basement segment of eastern Bavaria, SE Germany. In combination with geochemical features, four major suites of granitic rocks can be distinguished: (1) NE Bavarian redwitzites (52–57 wt% SiO₂, intrusion ages around 323 Ma) have chondritic εHf(t) values (+0.8 to –0.4). The redwitzites are hybrid rocks and the Hf data are permissive of mixing of a mantle progenitor and crustal melts. (2) Various intermediate rock types (dioritic dyke, granodiorite, palite, 59–63 wt% SiO₂, 334–320 Ma) from the Bavarian Forest yield negative εHf(t) values between –3.4 and –5.1. These values which apparently contradict a mantle contribution fingerprint an enriched (metasomatized) mantle component that was mixed with crustal material. (3) Voluminous, major crust forming granites sensu stricto (67–75 wt% SiO₂, 328–298 Ma) are characterized by a range in εHf(t) values from –0.5 to –5.6. Different crustal sources and/or modification of crustal melts by various input of juvenile material can explain this variation. (4) Post-plutonic (c. 299 Ma) porphyritic dykes of dacitic composition (64–67 wt% SiO₂) from the southern Bavarian Forest have chondritic εHf(t) values (+0.6 to –1.1) and display large intergrain Hf isotope variation. The dykes form a separate petrogenetic group and the Hf data suggest that the zircons crystallized when a pristine mantle-derived parental melt was modified by infiltration of crustal material. The zircon Hf data form a largely coherent positive array with the whole-rock Nd data and both systems yield similar two-stage depleted mantle model ages (1.1–1.7 Ga).