Late Holocene changes in ultraviolet radiation penetration recorded in an East Antarctic lake

Late Holocene changes in the ultraviolet radiation (UVR) penetration in a lake in the Larsemann Hills (East Antarctica) were reconstructed using sediment core proxies based on fossil pigments (scytonemins and its derivatives) and siliceous microfossils. The influence of changes in lake depth on the UVR proxy was excluded by applying a correction, based on the non-linear relation between modern scytonemin concentrations and lake depth in a regional reference data set, and the record of past lake depths inferred using a diatom based transfer function in the sediment core. Results showed four well-defined maxima in the UVR proxy during the last 1600–1800 years, centred around 1820–1780, 1580–1490, 790–580 and 680–440 AD. Several mechanisms may account for these observed changes in UVR penetration, including past variability in cloud cover, atmospheric turbidity, ozone column depth, snow cover on the lake ice, DOM concentrations and lake-ice thickness and transparency resulting from temperature fluctuations. Although some gaps remain in our knowledge of scytonemin production in relation to the limnology of Antarctic lakes, the results highlight the importance and potential of the sediments in these highly transparent water bodies as archives of changes in past UVR receipt at the Earth’s surface.     

Conduit-vent structures and related proximal deposits in the Las Cañadas caldera, Tenerife, Canary Islands

The Las Cañadas caldera wall and the outer slopes of the caldera provide three-dimensional exposures of numerous proximal-welded fallout deposits and have been mapped in detail. As a result, some parts of the Ucanca and Guajara Formations of the stratigraphy of Martí et al. (1994) have been divided into members that correspond to individual eruptions. Mapping has also revealed the occurrence of conduit-vent structures associated with proximal-welded fallout deposits. Conduit-vent structures consist of an upper flaring area and a lower narrow conduit. Conduit-vent geometry and dimensions include cylindrical plugs and eruptive fissures steeply dipping towards the caldera depression and elongated vents. The flaring area can be rather asymmetric and is usually filled by down-vent rheomorphic flow of the proximal fallout deposit. The lower conduits are filled by lava plug, agglutination of juveniles onto conduit walls and dyke intrusion with eventual dome extrusion. The eruption dynamics of welded fallout deposits and magma fragmentation within the conduit are consistent with an evolution from explosive to effusive. In this context conduit flow regimes evolve from turbulent to annular flow in which the conduit is progressively choked, and laminar flow leading to the final conduit closure.     

A Comparison between WCS and OPeNDAP for Making Model Results and Data Products Available through the Internet

Numerical models produce output with a large number of variables, grid cells and time steps. The same applies to algorithms that produce gridded datasets from sparse or abundant raw data. Further use of the resulting data products has been challenging, especially for dissemination outside the institute of origin. Due to the gradually increasing size of data products, simply downloading copies of them is becoming impossible. A gradual transition from traditional download methods to web services is therefore observed. Web services allow for on‐the‐fly access to subsets of data that were hitherto considered as indivisible granules. Here we compare the most mature candidates to serve gridded data through the web: the Open‐source Project for a Network Data Access Protocol (OPeNDAP) and Web Coverage Service (WCS) protocols. In the framework of the new Dutch National Model and Data Centre (NMDC.eu) a distributed data storage has been created by coupling OPeNDAP servers. A WCS service layer is provided for the same data. This allows us to compare OPeNDAP and WCS. Using several use cases, we compare the usability, performance and features of the two protocols.     

Yearly and seasonal variations of low albedo surfaces on Mars in the OMEGA/MEx dataset: Constraints on aerosols properties and dust deposits

The time variations of spectral properties of dark martian surface features are investigated using the OMEGA near-IR dataset. The analyzed period covers two Mars years, spanning from early 2004 to early 2008 (includes the 2007 global dust event). Radiative transfer modeling indicates that the apparent albedo variations of low to mid-latitude dark regions are consistent with those produced by the varying optical depth of atmospheric dust as measured simultaneously from the ground by the Mars Exploration Rovers. We observe only a few significant albedo changes that can be attributed to surface phenomena. They are small-scaled and located at the boundaries between bright and dark regions. We then investigate the variations of the mean particle size of aerosols using the evolution of the observed dark region spectra between 1 and 2.5 μm. Overall, we find that the observed changes in the spectral slope are consistent with a mean particle size of aerosols varying with time between 1 and 2 μm. Observations with different solar zenith angles make it possible to characterize the aerosol layer at different altitudes, revealing a decrease of the particle size of aerosols as altitude increases.     

Molecular modelling of rare earth element complexation in subduction zone fluids

Complexation of (trace) elements in fluids plays a critical role in determining element mobility in subduction zones, but to date, the atomic-scale processes controlling elemental solubilities are poorly understood. As a first step towards computer simulation of element complexation in subduction zone fluids, a thermodynamic cycle was developed to investigate the hydration environment and energetics of lanthanide complexes using density functional theory. The first solvation shell is explicitly defined and the remaining part of the aqueous fluid is modelled using a polarisable continuum model, which allows extrapolation to a broad pressure and temperature range.We illustrate our method by comparing solvation of lanthanide series elements in H₂O in the presence of fluoride or chloride for conditions relevant to subduction zones. The energetics of lanthanide- and lanthanide-fluoride/chloride hydration complexes were determined computationally. Calculated hydration free energies for trivalent lanthanides with explicit eight- and nine-fold coordinated first hydration shells show good agreement with literature data at room pressure and temperature. The hydration free energy is more negative for smaller complexes (heavy lanthanides) relative to larger complexes (light lanthanides), with the difference between La and Lu in water amounting to 361 kJ mol⁻¹. The hydration free energy of all lanthanide ions becomes less negative with increasing pressure (p) and temperature (T) up to 2.5 GPa and 1000 K (typical conditions in the upper part of subducting slabs). The free energy difference between light- and heavy-lanthanides remains essentially unchanged at elevated (p, T) conditions. There are minor geometrical differences in local hydration environment between light lanthanide-chloride (La-Nd) and heavy lanthanide-chloride (Pm-Lu) hydrated complexes, without a distinguishable energy difference. Complexation with fluoride is energetically more favourable than with chloride by 206 ± 4 kJ mol⁻¹ across the entire lanthanide series. The association of fluoride-water and chloride-water fragments with lanthanide-water complexes is energetically more favourable for aqueous lanthanide complexes surrounded by fewer first hydration shell water molecules.The methods developed in this study, in conjunction with simulation of the energetics of trace element incorporation into minerals, open the possibility to use molecular modelling to constrain elemental behaviour in subduction zones.     

Splash detachment of sand particles under varying contact stress field of wind-driven raindrop impact

The effects of wind-driven rain (WDR) on sand detachment were studied under various raindrop obliquities. Results suggested a significant reduction in compressive stress on sand surfaces for a two-dimensional experimental set-up in a wind tunnel. During experiments, sand particles in splash cups were exposed to both wind-free rain (WFR) and WDR driven by horizontal winds of 6.4, 8.9 and 12.8 m s⁻¹ and rainfall intensities of 50, 60, 75 and 90-mm h⁻¹ to assess the sand detachment rate (D, in g m⁻² s⁻¹). The effects of sand moisture state (dry and wet) on the detachment of different-sized particles (0.20–0.50 and 0.50–2.00 mm, respectively) were also tested. Factorial analysis of variance showed that shear and compressive stress components evaluated by horizontal and vertical kinetic energy flux terms (KE_x and KE_y, respectively, in J m⁻² s⁻¹) along with their vector sum (KE_r, in J m⁻² s⁻¹) explained the variation in D. Neither sand size nor sand moisture was statistically significant alone although binary interactions of KE_r, KE_x and KE_y with the sand size and three-way interaction of KE_x, sand size and moisture were statistically significant. These results can be explained by size-dependent variation in sand compressibility and surface friction related to the total stress field developed by a given partition of shear and compressive stresses of wind-driven oblique raindrops (KE_x/KE_y). Further analysis of the variation of the unit sand detachment rate (D_u = D/KE_r = g J⁻¹) with rain inclination (α, in degrees) better revealed the effect of WDR obliquity on D_u that further changed with sand size class and moisture state. Finally, the difference in the resulting stress field differentiable by the oblique raindrop trajectories of the experiment over sand surface significantly affected the non-cohesive particle detachment rates, to some extent interacted with size-dependent compressibility and interface shear strength of sand grains.     

Comparison of Meteoroid Flux Models for Near Earth Space

Over the last decade several new models for the sporadic interplanetary meteoroid flux have been developed. These include the Divine-Staubach and the Dikarev model. They typically cover mass ranges from 10⁻¹⁸ g to 1 g and are applicable for model specific Sun distance ranges between 0.1 AU and 20 AU Near 1 AU averaged fluxes (over direction and velocities) for all these models are tuned to the well established interplanetary model by Grün et al. However, in many respects these models differ considerably. Examples are the velocity and directional distributions and the assumed meteoroid sources. In this paper flux predictions by the various models to Earth orbiting spacecraft are compared. Main differences are presented and analysed. The persisting differences even for near Earth space can be seen as surprising in view of the numerous ground based (optical and radar) and in situ (captured Inter Stellar Dust Particles, in situ detectors and analysis of retrieved hardware) measurements and simulations.     

Das Präkambrium Finnlands

Ohne ZusammenfassungDer vorliegende Aufsatz berichtet über die wissenschaftlichen Ergebnisse der Tagung der Internationalen Vereinigung zum Studium des Präkambriums in Helsingfors im Juli 1931, hinzugefügt sind einige ergänzende Betrachtungen zum Rappakiwiproblem.     

Impact of reservoir operation and climate change on the hydrological regime of the Sesan and Srepok Rivers in the Lower Mekong Basin

The transboundary Sesan and Srepok sub-basins (2S) are the “hot-spot” areas for reservoir development in the Lower Mekong region, with 12 reservoirs built in the Vietnam territory. This study examines the impacts of reservoir operations in Vietnam and projected climate change on the downstream hydrologic regime of the 2S Rivers by jointly applying the Soil Water Assessment Tool (SWAT) and Water Evaluation and Planning (WEAP) models. Different scenarios of reservoir operation are considered and simulated to assess their impact on annual, seasonal, and monthly flow regimes under maximum hydropower capacity generation with and without taking into account the minimum flow requirement downstream near the Vietnam border with Cambodia. The precipitation and temperature projections from the high-resolution regional climate model HadGEM3-RA under two Representative Concentration Pathways, 4.5 and 8.5, of HadGEM2-AO are used as future climate change scenarios for the impact assessment. The study results show that reservoir operation leads to an increase in the dry season stream flows and a decrease in the wet season stream flows. The monthly flow regime exhibits considerable changes for both the Sesan and Srepok Rivers but with different magnitudes and patterns of increase and decrease. Climate change is likely to induce considerable changes in stream flows, though these changes are comparatively lower than those caused by reservoir operation. Climate change is likely to have both counterbalancing and reinforcing effects over the impact of reservoir operation, reducing changes during dry season but increasing changes in most of the other months.     

Spatial Pair-Copula Modeling of Grade in Ore Bodies: A Case Study

A real-world mining application of pair-copulas is presented to model the spatial distribution of metal grade in an ore body. Inaccurate estimation of metal grade in an ore reserve can lead to failure of a mining project. Conventional kriged models are the most commonly used models for estimating grade and other spatial variables. However, kriged models use the variogram or covariance function, which produces a single average value to represent the spatial dependence for a given distance. Kriged models also assume linear spatial dependence. In the application, spatial pair-copulas are used to appropriately model the non-linear spatial dependence present in the data. The spatial pair-copula model is adopted over other copula-based spatial models since it is better able to capture complex spatial dependence structures. The performance of the pair-copula model is shown to be favorable compared to a conventional lognormal kriged model.