Effect of Fe on garnet–melt trace element partitioning: experiments in FCMAS and quantification of crystal-chemical controls in natural systems

Garnet–melt trace element partitioning experiments were performed in the system FeO–CaO–MgO–Al₂O₃–SiO₂ (FCMAS) at 3 GPa and 1540°C, aimed specifically at studying the effect of garnet Fe²⁺ content on partition coefficients (D^Grt/Melt). D^Grt/Melt, measured by SIMS, for trivalent elements entering the garnet X-site show a small but significant dependence on garnet almandine content. This dependence is rationalised using the lattice strain model of Blundy and Wood [Blundy, J.D., Wood, B.J., 1994. Prediction of crystal–melt partition coefficients from elastic moduli. Nature 372, 452–454], which describes partitioning of an element i with radius r_i and valency Z in terms of three parameters: the effective radius of the site r₀(Z), the strain-free partition coefficient D₀(Z) for a cation with radius r₀(Z), and the apparent compressibility of the garnet X-site given by its Young's modulus E_X(Z). Combination of these results with data in Fe-free systems [Van Westrenen, W., Blundy, J.D., Wood, B.J., 1999. Crystal-chemical controls on trace element partitioning between garnet and anhydrous silicate melt. Am. Mineral. 84, 838–847] and crystal structure data for spessartine, andradite, and uvarovite, leads to the following equations for r₀(3+) and E_X(3+) as a function of garnet composition (X) and pressure (P):

r₀(3+) [Å]=0.930X_Py+0.993X_Gr+0.916X_Alm+0.946X_Spes+1.05(X_And+X_Uv)−0.005(P [GPa]−3.0)(±0.005 Å)

E_X(3+) [GPa]=3.5×10¹²(1.38+r₀(3+) [Å])^−26.7(±30 GPa)

Accuracy of these equations is shown by application to the existing garnet–melt partitioning database, covering a wide range of P and T conditions (1.8 GPa<P<5.0 GPa; 975°C<T<1640°C). D^Grt/Melt for all 3+ elements entering the X-site (REE, Sc and Y) are predicted to within 10–40% at given P, T, and X, when D^Grt/Melt for just one of these elements is known. In the absence of such knowledge, relative element fractionation (e.g. D_Sm^Grt/Melt/D_Nd^Grt/Melt) can be predicted. As an example, we predict that during partial melting of garnet peridotite, group A eclogite, and garnet pyroxenite, r₀(3+) for garnets ranges from 0.939±0.005 to 0.953±0.009 Å. These values are consistently smaller than the ionic radius of the heaviest REE, Lu. The above equations quantify the crystal-chemical controls on garnet–melt partitioning for the REE, Y and Sc. As such, they represent a major advance en route to predicting D^Grt/Melt for these elements as a function of P, T and X.     

黑河实验区地表净辐射区域分布及季节变化

利用卫星遥感信息和地面观测资料，分析研究黑河实验区地表净辐射的区域分布及季节变化特征。结果表明，卫星遥感结合地面观测，首先可以得到较为精确的地表反射率和地表温度分布，进而得到较为合理的地表净辐射的区域分布和季节变化特征。     

Impact of India–Asia collision on SE Asia: The record in Borneo

Borneo occupies a central position in the Sundaland promontory of SE Asia. It has a complex Cenozoic geological history of sedimentation and deformation which began at about the same time that India is commonly suggested to have started to collide with Asia. Some tectonic reconstructions of east and SE Asia interpret a large SE Asian block with Borneo at its centre which has been rotated clockwise and displaced southwards along major strike–slip faults during the Cenozoic due to the indentation of Asia by India. However, the geological history of Borneo is not consistent with the island simply forming part of a large block extruded from Asia. The large clockwise rotations and displacements predicted by the indentor model for Borneo are incompatible with palaeomagnetic evidence and there is no evidence that the major strike–slip faults of the Asian mainland reach Borneo. Seismic tomography shows there is a deep high velocity anomaly in the lower mantle beneath SE Asia interpreted as subducted lithosphere but it can be explained just as well by alternative tectonic models as by the indentor model. Very great thicknesses of Cenozoic sediments are present in Borneo and circum-Borneo basins, and large amounts of sediment were transported to the Crocker turbidite fan of north Borneo from the Eocene to the Early Miocene, but all evidence indicates that these sediments were derived from local sources and not from distant sources in Asia elevated by India–Asia collision. The Cenozoic geological history of Borneo records subduction of the proto-South China Sea and Miocene collision after this ocean lithosphere was eliminated, and a variety of effects resulting from long-term subduction beneath SE Asia. There is little to indicate that India–Asia collision has influenced the Cenozoic geological record in Borneo.     

Quantifying deformation in North Borneo with GPS

The existence of intra-plate deformation of the Sundaland platelet along its eastern edge in North Borneo, South-East Asia, makes it an interesting area that still is relatively understudied. In addition, the motion of the coastal area of North-West Borneo is directed toward a frontal fold-and-thrust belt and has been fueling a long debate on the possible geophysical sources behind it. At present this fold-and-thrust belt is not generating significant seismic activity and may also not be entirely active due to a decreasing shelfal extension from south to north. Two sets of Global Positioning System (GPS) data have been used in this study; the first covering a time period from 1999 until 2004 (ending just before the Giant Sumatra–Andaman earthquake) to determine the continuous Sundaland tectonic plate motion, and the second from 2009 until 2011 to investigate the current deformations of North Borneo. Both absolute and relative positioning methods were carried out to investigate horizontal and vertical displacements. Analysis of the GPS results indicates a clear trend of extension along coastal regions of Sarawak and Brunei in North Borneo. On the contrary strain rate tensors in Sabah reveal that only insignificant and inconsistent extension and compression occurs throughout North-West Borneo. Moreover, station velocities and rotation rate tensors on the northern part of North Borneo suggest a clockwise (micro-block) rotation. The first analysis of vertical displacements recorded by GPS in North-West Borneo points to low subsidence rates along the western coastal regions of Sabah and inconsistent trends between the Crocker and Trusmadi mountain ranges. These results have not been able to either confirm or reject the hypothesis that gravity sliding is the main driving force behind the local motions in North Borneo. The ongoing Sundaland–Philippine Sea plate convergence may also still play an active role in the present-day deformation (crustal shortening) in North Borneo and the possible clockwise rotation of the northern part of North Borneo as a micro-block. However, more observations need to be collected to determine if the northern part of North Borneo indeed is (slowly) moving independently.     

MERIS and the red-edge position

The Medium Resolution Imaging Spectrometer (MERIS) is a payload component of Envisat-1. MERIS will be operated over land with a standard 15 band setting acquiring images with a 300 m spatial resolution. The red-edge position (REP) is a promising variable for deriving foliar chlorophyll concentration, which plays an important role in ecosystem processes. The objectives of this paper are: (1) to study which factors effect the REP of vegetation, (2) to study whether this REP can be derived from the MERIS standard band setting and (3) to show what REP represents at the scale of MERIS data. Two different data sets were explored for simulating the REP using MERIS bands: (1) simulated data using reflectance models and (2) airborne reflectance spectra of an agricultural area obtained by the airborne visible-infrared imaging spectrometer (AVIRIS). A “linear method”, assuming a straight slope of the reflectance spectrum around the midpoint of the slope, was a robust method for determining the REP and the MERIS bands at 665, 708.75, 753.75 and 778.75 nm could be used for applying the “linear method” for REP estimation. Results of the translation to the scale of MERIS data were very promising for applying MERIS at, for instance, the ecosystem level.     

Dissolved organic carbon in the freshwater tidal reaches of the Schelde estuary

To unravel the factors that regulate DOC dynamics in the freshwater tidal reaches of the Schelde estuary, DOC concentration and biodegradability were monitored in the upper Schelde estuary and its major tributaries. Although the Schelde estuary possesses a densely populated and industrialized catchment, our data suggest that the bulk of DOC in the freshwater tidal reaches is not derived from waste water. This was concluded from the low biodegradability of DOC (on average 9%), DOC concentrations that are close to the mean for European rivers (4.61 mg l⁻¹) and the absence of an inverse relationship between DOC and discharge. Most DOC originating from waste water being discharged in tributaries of the estuary appears to be remineralised before these tributaries reach the main estuary. Although dense phytoplankton blooms were observed in the upper estuary during summer (up to 700 μg chl a l⁻¹), these blooms did not appear to produce large quantities of DOC in the freshwater tidal reaches as DOC concentrations were low when phytoplankton biomass was high. The fact that DOC concentrations were high in winter and decreased in summer suggests a predominantly terrestrial source of DOC in the freshwater tidal reaches of the Schelde estuary.     

Formal definition and dating of the GSSP (Global Stratotype Section and Point) for the base of the Holocene using the Greenland NGRIP ice core,and selected auxiliary records

The Greenland ice core from NorthGRIP (NGRIP) contains a proxy climate record across the Pleistocene–Holocene boundary of unprecedented clarity and resolution. Analysis of an array of physical and chemical parameters within the ice enables the base of the Holocene, as reflected in the first signs of climatic warming at the end of the Younger Dryas/Greenland Stadial 1 cold phase, to be located with a high degree of precision. This climatic event is most clearly reflected in an abrupt shift in deuterium excess values, accompanied by more gradual changes in δ¹⁸O, dust concentration, a range of chemical species, and annual layer thickness. A timescale based on multi‐parameter annual layer counting provides an age of 11 700 calendar yr b2 k (before AD 2000) for the base of the Holocene, with a maximum counting error of 99 yr. A proposal that an archived core from this unique sequence should constitute the Global Stratotype Section and Point (GSSP) for the base of the Holocene Series/Epoch (Quaternary System/Period) has been ratified by the International Union of Geological Sciences. Five auxiliary stratotypes for the Pleistocene–Holocene boundary have also been recognised. Copyright © 2008 John Wiley & Sons, Ltd.     

Pleistocene Rhine–Thames landscapes: geological background for hominin occupation of the southern North Sea region

This paper links research questions in Quaternary geology with those in Palaeolithic archaeology. A detailed geological reconstruction of The Netherlands' south‐west offshore area provides a stratigraphical context for archaeological and palaeontological finds. Progressive environmental developments have left a strong imprint on the area's Palaeolithic record. We highlight aspects of landscape evolution and related taphonomical changes, visualized in maps for critical periods of the Pleistocene in the wider southern North Sea region. The Middle Pleistocene record is divided into two palaeogeographical stages: the pre‐Anglian/Elsterian stage, during which a wide land bridge existed between England and Belgium even during marine highstands; and the Anglian/Elsterian to Saalian interglacial, with a narrower land bridge, lowered by proglacial erosion but not yet fully eroded. The Late Pleistocene landscape was very different, with the land bridge fully dissected by an axial Rhine–Thames valley, eroded deep enough to fully connect the English Channel and the North Sea during periods of highstand. This tripartite staging implies great differences in (i) possible migration routes of herds of herbivores as well as hominins preying upon them, (ii) the erosion base of axial and tributary rivers causing an increase in the availability of flint raw materials and (iii) conditions for loess accumulation in northern France and Belgium and the resulting preservation of Middle Palaeolithic sites. Copyright © 2011 John Wiley & Sons, Ltd.     

The nature of hydroxyl groups in aluminosilicate glasses: Quantifying Si-OH and Al-OH abundances along the SiO2-NaAlSiO4 join by H, Al-H and Si-H NMR spectroscopy

The combined results of ²⁷Al-¹H and ¹H-²⁹Si-¹H cross polarization NMR experiments for hydrous glasses (containing 0.5-2 wt% water) along the SiO₂-NaAlSiO₄ join confirm that the dissolution mechanism of water in aluminosilicate glasses is fundamentally the same as for Al-free systems, i.e. the dissolved water ruptures oxygen bridges and creates Si-OH and Al-OH groups, in addition to forming molecular water (H₂O_mol). The fraction of Al-OH increases non-linearly as the Al content increases with up to half of the OH groups as Al-OH for compositions close to NaAlSiO₄. The relative abundances of the different species are controlled by the degree of Al-avoidance and the relative tendency of hydrolysis of the different types of oxygen bridges, Si-O-Si, Si-O-Al and Al-O-Al. A set of homogeneous reactions is derived to model the measured Al-OH/Si-OH speciation, and the obtained equilibrium constants are in agreement with literature data on the degree of Al-avoidance. With these equilibrium constants, the abundance of the different oxygen species, i.e. Si-O-Si, Si-O-Al, Al-O-Al, Si-OH, Al-OH and H₂O_mol, can be predicted for the entire range of water and Al contents.