Structure and dynamics of the Bok globule B335

CO maps of the Bok globule B335 are presented and used to derive its density profile, mass distribution, and rotational velocity structure. It is found that the cloud is in nearly hydrostatic equilibrium with a density profile that varies roughly as r^?1 in the core and r^?3 in the envelope. The observed rotation is unimportant in the force balance at the present stage of evolution.     

Subaqueous pyroclastic flows and ignimbrites: an assessment

An assessment of the literature on subaqueous pyroclastic flows and their deposits shows that the term pyroclastic flow is frequently used loosely to describe primary, hot gas-rich pyroclastic flows, mass-flows which resulted from the transformation of gassupported flows into water-supported ones, and secondary mass-flows carrying redeposited pyroclastic debris. Based on subaerial pyroclastic flows, the term pyroclastic flow should be restricted to demonstrably hot, gas-rich mass-flows of pyroclastic debris. Using this definition, very few examples of subaqueous pyroclastic deposits with evidence for hot emplacement and of having been wholly submerged have been described. In the majority of these cases, the evidence for a hot state of emplacement and for the subaqueous nature of the host depositional environment is inadequate. The only unequivocal cases of hot pyroclastic flow deposits with adequate supporting evidence are the Ordovician nearshore, shallow marine ignimbrites of Ireland and Wales, and Miocene ignimbrites of southwest Japan, resulting from the passage of subaerially erupted pyroclastic flows into shallow water. Other possible examples are near-vent dense clast deposits in the Donzurobo Formation of Japan, possible submarine intra-caldera ponded ignimbrite successions in California and Wales, and near-vent pumiceous deposits of Ramsay Island, Wales. All other purported cases are either clearly the result of water-supported mass-flow transportation and deposition (debris avalanches, debris flows, turbidity currents), or lack adequate supporting evidence regarding the heat state or the palaeoenvironment. Only the shallow marine ignimbrites of Ireland and Wales show adequate evidence of welding, but even these could have been nearly wholly exposed above sea-level when welding occurred. We conclude that when pyroclastic flows enter water they are generally disrupted explosively and/or ingest water and transform into water-supported mass-flows, and we suggest the various scenarios in which this occurs. There is no evidence to suggest that welding in wholly subaqueous environments is common.     

On the practice of estimating fractal dimension

Coastlines epitomize deterministic fractals and fractal (Hausdorff-Besicovitch) dimensions; a divider [compass] method can be used to calculate fractal dimensions for these features. Noise models are used to develop another notion of fractals, a stochastic one. Spectral and variogram methods are used to estimate fractal dimensions for stochastic fractals. When estimating fractal dimension, the objective of the analysis must be consistent with the method chosen for fractal dimension calculation. Spectal and variogram methods yield fractal dimensions which indicate the similarity of the feature under study to noise (e.g., Brownian noise). A divider measurement method yields a fractal dimension which is a measure of complexity of shape.     

SHRIMP zircon dating and Sm/Nd isotopic investigations of Neoproterozoic granitoids, Eastern Desert, Egypt

There is an increasing evidence for the involvement of pre-Neoproterozoic zircons in the Arabian–Nubian Shield, a Neoproterozoic crustal tract that is generally regarded to be juvenile. The source and significance of these xenocrystic zircons are not clear. In an effort to better understand this problem, older and younger granitoids from the Egyptian basement complex were analyzed for chemical composition, SHRIMP U–Pb zircon ages, and Sm–Nd isotopic compositions. Geochemically, the older granitoids are metaluminous and exhibit characteristics of I-type granites and most likely formed in a convergent margin (arc) tectonic environment. On the other hand, the younger granites are peraluminous and exhibit the characteristics of A-type granites; these are post-collisional granites. The U–Pb SHRIMP dating of zircons revealed the ages of magmatic crystallization as well as the presence of slightly older, presumably inherited zircon grains. The age determined for the older granodiorite is 652.5 ± 2.6 Ma, whereas the younger granitoids are 595–605 Ma. Xenocrystic zircons are found in most of the younger granitoid samples; the xenocrystic grains are all Neoproterozoic, but fall into three age ranges that correspond to the ages of other Eastern Desert igneous rocks, viz. 710–690, 675–650 and 635–610 Ma. The analyzed granitoids have (+3.8 to +6.5) and crystallization ages, which confirm previous indications that the Arabian–Nubian Shield is juvenile Neoproterozoic crust. These results nevertheless indicate that older Neoproterozoic crust contributed to the formation of especially the younger granite magmas.     

Quick-look assessments to identify optimal CO2 EOR storage sites

A newly developed, multistage quick-look methodology allows for the efficient screening of an unmanageably large number of reservoirs to generate a workable set of sites that closely match the requirements for optimal CO₂ enhanced oil recovery (EOR) storage. The objective of the study is to quickly identify miscible CO₂ EOR candidates in areas that contain thousands of reservoirs and to estimate additional oil recovery and sequestration capacities of selected top options through dimensionless modeling and reservoir characterization. Quick-look assessments indicate that the CO₂ EOR resource potential along the US Gulf Coast is 4.7 billion barrels, and CO₂ sequestration capacity is 2.6 billion metric tons. In the first stage, oil reservoirs are screened and ranked in terms of technical and practical feasibility for miscible CO₂ EOR. The second stage provides quick estimates of CO₂ EOR potential and sequestration capacities. In the third stage, a dimensionless group model is applied to a selected set of sites to improve the estimates of oil recovery and storage potential using appropriate inputs for rock and fluid properties, disregarding reservoir architecture and sweep design. The fourth stage validates and refines the results by simulating flow in a model that describes the internal architecture and fluid distribution in the reservoir. The stated approach both saves time and allows more resources to be applied to the best candidate sites.     

Li-Sr-Nd isotope signatures of the plume and cratonic lithospheric mantle beneath the margin of the rifted Tanzanian craton (Labait)

Lithium concentrations and isotopic compositions of olivine and ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd of coexisting clinopyroxene from peridotite xenoliths from the Quaternary Labait volcano, Tanzania, document the influence of rift-related metasomatism on the ancient cratonic mantle. Olivines show negative correlations between Fo content and both δ⁷Li and Li concentrations. Olivines in iron-rich peridotites (Fo_85–87) have high Li concentrations (3.2–4.8 ppm) and heavy δ⁷Li (+5.2 to +6.6). In contrast, olivines in ancient, refractory peridotites have lower Li concentrations (∼2 ppm) and relatively light δ⁷Li (+2.6 to +3.5). This reflects mixing between ancient, refractory cratonic lithosphere and asthenosphere-derived rift magmas. A uniquely fertile, deformed, high-temperature garnet lherzolite, interpreted to be from the base of the lithosphere, has a ⁸⁷Sr/⁸⁶Sr of 0.7029 and ¹⁴³Nd/¹⁴⁴Nd of 0.51286, similar to HIMU oceanic basalts. It provides the best estimate of the Sr–Nd isotope composition of the upwelling mantle (i.e., plume, sensu lato) underlying this portion of the East African Rift, and is slightly less radiogenic compared to previous estimates of the plume that were based on rift basalts. Although elevated δ⁷Li are not exclusive to HIMU source regions, the data collectively indicate that the plume beneath Labait has HIMU characteristics in Sr, Nd and Li isotope composition. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Exurbia from the bottom-up: Confronting empirical challenges to characterizing a complex system

We describe empirical results from a multi-disciplinary project that support modeling complex processes of land-use and land-cover change in exurban parts of Southeastern Michigan. Based on two different conceptual models, one describing the evolution of urban form as a consequence of residential preferences and the other describing land-cover changes in an exurban township as a consequence of residential preferences, local policies, and a diversity of development types, we describe a variety of empirical data collected to support the mechanisms that we encoded in computational agent-based models. We used multiple methods, including social surveys, remote sensing, and statistical analysis of spatial data, to collect data that could be used to validate the structure of our models, calibrate their specific parameters, and evaluate their output. The data were used to investigate this system in the context of several themes from complexity science, including have (a) macro-level patterns; (b) autonomous decision making entities (i.e., agents); (c) heterogeneity among those entities; (d) social and spatial interactions that operate across multiple scales and (e) nonlinear feedback mechanisms. The results point to the importance of collecting data on agents and their interactions when producing agent-based models, the general validity of our conceptual models, and some changes that we needed to make to these models following data analysis. The calibrated models have been and are being used to evaluate landscape dynamics and the effects of various policy interventions on urban land-cover patterns.     

Ionospheric conditions

A general analysis of ionospheric conditions has been made in the light of possible ionic reactions occurring in the upper atmosphere. Data obtained on various parameters, such as ionic production and recombination, show that precise knowledge of the spectral distribution of solar radiation is needed and that other experimental determinations on dissociative recombinations are required.

The ionic complexity of the ionosphere is underlined by describing how the atomic ions O⁺ and N⁺ react with N₂, O₂ and NO molecules. The behavior of the molecular ions N⁺₂, O⁺₂and NO⁺depends on a group of simultaneous processes involving charge transfers and ionatom interchanges which are more important than dissociative recombinations. The altitude distribution of ions is exemplified by discussing the relative importance of various loss coefficients in the D-, E- and F-regions. It is seen that molecular nitrogen ions are subject to important charge transfer processes, that nitric oxide ions are always final products destroyed only by dissociative recombination. Additionally, the entire production of atomic oxygen ions is related to the photoionization of molecular nitrogen. Some information is also given on possible anomalies in the ratio of O⁺₂ and NO⁺ densities in the lower ionosphere. From the lack of sufficient experimental information on ionic processes it is shown that a precise analysis of ionospheric behavior remains highly speculative.