Relationship of Avalonian and Cadomian terranes to Grenville and Pan-African events

Suturing of the supercontinent Rodinia in the Grenville event (˜ 1000 Ma) was followed by rifting in the late Proterozoic (˜ 800-700 Ma), reorganization to Gondwana in the Pan-African (˜ 700-500 Ma) and further accretion to develop Pangea at the end of the Paleozoic. One of the Rodinian rifts followed part of the Grenville suture, it produced the margin of eastern North America and southern Baltica and the contrasting margin of west Gondwana in present South America. The Paleozoic accretionary wedge against the Grenville-age margin of North America and Baltica contains Avalonian/Cadomian terranes that exhibit Pan-African erogenic events ± sediments apparently developed while the terranes were in or near Gondwana. These terranes carry lower-Paleozoic fauna (Acado-Baltic) that are not indigenous to North America and Baltica.U---Pb zircon ages range from 1500-1000 Ma in Grenville terranes and from 800–500 Ma with minor inheritance in Avalonian terranes; they are generally much older in Cadomian terranes, implying very little resetting during Pan-African events. T_DM ages are generally 2000–1200 Ma in Grenville terranes, 1300–600 Ma in Avalonian terranes and 2000–1200 in Cadomian terranes. These summary data show that: (1) the Grenville orogenic event produced almost no juvenile crust; (2) the Avalonian terranes of North America contain crust that evolved primarily in the late Proterozoic, possibly as a mixture of juvenile Pan-African material and Grenville or slightly older material; (3) the Cadomian terranes of Europe consist of old (middle-Proterozoic to Archean) crust with minor juvenile Pan-African material. The Avalonian terranes apparently evolved near, and partly on, the Grenville-age crust now in South America during the intense orogeny associated with rotation of Gondwana away from North America. The Cadomian terranes of Europe, however, appear to be fragments of other parts of Gondwana, probably West Africa.     

Simulation studies of processes associated with stimulated electromagnetic emission (SEE) in the ionosphere

Results of numerical simulation studies of processes associated with Stimulated Electromagnetic Emission (SEE) produced during ionospheric heating experiments are presented. A one-dimensional magnetized electrostatic Particle-In-Cell (PIC) simulation model with uniform plasma density is used to investigate electrostatic wave generation in the region where the pump frequency ω₀ approximately equals the upper hybrid frequency ω_uh. In particular, the simulation plasma is driven with a uniform oscillating electric field to represent the long wavelength pump wave and power spectra of the electrostatic waves produced are taken. The pump wave frequency and amplitude are varied to consider the effects on the simulation power spectrum. The upper hybrid frequency in the model is varied through harmonics of the electron cyclotron frequency Ω_ce to consider the effects of stepping the pump frequency through cyclotron harmonics. The power spectrum from the simulation plasma is richly structured. The resulting power spectra show sidebands upshifted and downshifted from the pump frequency by multiples of the lower hybrid frequency ω_lh. The structure of the spectrum is highly sensitive to the proximity of the upper hybrid frequency to the cyclotron harmonic frequencies.     

Effect of scallop shells and sediment grain size on phytoplankton flux to the bed

A flume study was made of bed skin friction and phytoplankton (Thalassiosira weissf ogii) deposition about a sea scallop (Placopecten magellanicus) mimic on a coarse (mean grain dia. =1200 μm), medium (615 μm) and fine (170 μm) quarry sand. Bed skin friction immediately upstream, and at one shell diameter downstream of the mimic was 1.2–2.4 times higher than ambient values (8.1 × 10⁻² Pa). Directly downstream of the mimic there was a region of near-zero skin friction. Bed diatom density was correlated with changes in skin friction; after 21 h, cell densities were 36–87% greater in the regions of high skin friction upstream and downstream of scallop than in control experiments. The pattern of bed diatom density about the scallop was similar in the coarse and medium sands, but deposition to the fine bed was not affected by the mimic. Diatom density was significantly correlated with grain diameter; deposition in the coarse bed was 2.3 times higher than in the medium sand, and 7.4 times higher than in the fine sand. A field experiment confirmed that the coarse sand was a greater sink of phytoplankton pigment than the fine sand. Previous studies and scaling arguments suggest that the differences in bed diatom density were controlled by the magnitude of interfacial solute fluxes. Regions of high skin friction about the mimic increased the porewater exchange, resulting in greater concentrations of diatoms retained within the bed. Similarly, the more permeable coarse sand would have a greater rate of porewater exchange than the fine sand, explaining the higher bed diatom density. Differences in the predicted volume of interstitial void space as a function of grain size closely matched the observed differences in bed diatom density. Results suggest that alteration of boundary layer flows by centimetre scale topography such as scallops, increases the flux of particulate organic matter toward the bed, but whether it is retained within the bed, and thus made available to the benthos is dependent on the sediment granularity.     

Qualitätsanforderungen an Oberflächengewässer: Zielvorgaben,Qualitätsziele und chemische Gewässergüteklassifizierung

Quality Requirements for Fresh Waters: Water Quality Targets, Water Quality Objectives, and Chemical Water Quality Classification In the Federal Republic of Germany, water quality requirements for the protection of inland surface waters against hazardous substances are formulated on the basis of a quality targets derivation concept developed jointly by the Federal Government and the Federal States. The quality requirements were termed “water quality targets” in order to make it clear that the values derived are orientational values rather than legally binding limit values. The international comparison of quality requirements for surface waters shows that, on the whole, the national quality targets ensure a high level of protection. According to present scientific knowledge, impairments of uses, such as supply of drinking water, or risks to aquatic communities need not to be expected if the quality targets are complied with. A comparison of water quality data with the water quality targets makes it possible, on the one hand, to identify those substances whose inputs must be further reduced; on the other hand, it also shows that, for a number of substances, there is no need at present for concern over their adversely water quality. A further differentiation of the aquatic hazard potential of pollutants allows a water quality classification system to be developed on the basis of the quality targets derivation concept. The basic elements of this water quality classification system are presented, and its application is explained by way of examples.     

Abbau von Monochlornitrobenzolen durch Pseudomonas acidovorans CA50

Degradation of Monochloronitrobenzenes by Pseudomonas acidovorans CA50 Pseudomonas acidovorans strain CA50 was used for degradation experiments with monochloronitrobenzenes in aerobic batch culture. The monochloronitrobenzenes were reduced to the corresponding monochloroanilines. The reduction only occurred with an additional carbon and nitrogen source. Chlorocatechols were found to be present. 3-Chlorocatechol accumulated in the presence of 2-chloroaniline, whereas 4-chlorocatechol was an intermediate metabolite of 3- and 4-chloroaniline. Contrary to the degradation of monochloronitrobenzenes, Pseudomonas acidovorans strain CA50 used the monochloroanilines as a sole source of carbon, energy, and nitrogen for growth. The oxidation of monochloroanilines was not repressed by the additional substrates. 2-Chloronitrobenzene was degraded with the lowest rate because of the low turnover of the intermediate metabolite 2-chloroaniline. 3-Chloronitrobenzene was completely degraded also in a mixture. A complete degradation of 4-chloronitrobenzene was achieved only when it was the sole chloronitrobenzene. The results suggest that a dechlorination and mineralization of monochlornitrobenzenes is possible, but for a final proof, further investigations will be necessary.     

任意圆弧形凸起地形中隧洞对入射平面SH波的影响

借助辅助函数的思想， 采用波函数展开法给出了圆弧形凸起地形中隧洞对入射平面SH波影响问题的一个解析解．数值结果表明，凸起地形中隧洞的存在以及隧洞大小，对凸起地形表面运动，以及凸起地形中的隧洞的动应力集中均具有显著影响．      

A Simple Parameterisation for Flux Footprint Predictions

Flux footprint functions estimate the location and relative importance of passive scalar sources influencing flux measurements at a given receptor height. These footprint estimates strongly vary in size, depending on receptor height, atmospheric stability, and surface roughness. Reliable footprint calculations from, e.g., Lagrangian stochastic models or large-eddy simulations are computationally expensive and cannot readily be computed for long-term observational programs. To facilitate more accessible footprint estimates, a scaling procedure is introduced for flux footprint functions over a range of stratifications from convective to stable, and receptor heights ranging from near the surface to the middle of the boundary layer. It is shown that, when applying this scaling procedure, footprint estimates collapse to an ensemble of similar curves. A simple parameterisation for the scaled footprint estimates is presented. This parameterisation accounts for the influence of the roughness length on the footprint and allows for a quick but precise algebraic footprint estimation.     

Estimated N2O and CO2 Emissions as Influenced by Agricultural Practices in Canada

The Denitrification-Decompostion (DNDC) model was used to estimate the impact of change in management practices on N₂O emissions in seven major soil regions in Canada, for the period 1970 to 2029. Conversion of cultivated land to permanent grassland would result in the greatest reduction in N₂O emissions, particularly in eastern Canada wherethe model estimated about 60% less N₂O emissions for thisconversion. About 33% less N₂O emissions were predicted for a changefrom conventional tillage to no-tillage in western Canada, however, a slight increase in N₂O emissions was predicted for eastern Canada. GreaterN₂O emissions in eastern Canada associated with the adoption of no-tillage were attributed to higher soil moisture causing denitrification, whereas the lower emissions in western Canada were attributed to less decomposition of soil organic matter in no-till versus conventional tilled soil. Elimination of summer fallow in a crop rotation resulted in a 9% decrease in N₂O emissions, with substantial emissions occurringduring the wetter fallow years when N had accumulated. Increasing N-fertilizer application rates by 50% increased average emissions by 32%,while a 50% decrease of N-fertilizer application decreased emissions by16%. In general, a small increase in N₂O emissions was predicted when N-fertilizer was applied in the fall rather than in the spring. Previous research on CO₂ emissions with the CENTURY model (Smith et al.,2001) allowed the quantification of the combined change in N₂O andCO₂ emissions in CO₂ equivalents for a wide range of managementpractices in the seven major soil regions in Canada. The management practices that have the greatest potential to reduce the combined N₂O andCO₂ emissions are conversion from conventional tillage to permanent grassland, reduced tillage, and reduction of summer fallow. The estimated net greenhouse gas (GHG) emission reduction when changing from cultivated land to permanent grassland ranged from 0.97 (Brown Chernozem) to 4.24 MgCO₂ equiv. ha^–1 y^–1 (BlackChernozem) for the seven soil regions examined. When changing from conventional tillage to no-tillage the net GHG emission reduction ranged from 0.33 (Brown Chernozem) to 0.80 Mg CO₂ equiv. ha^–1 y^–1 (Dark GrayLuvisol). Elimination of fallow in the crop rotation lead to an estimated net GHG emission reduction of 0.43 (Brown Chernozem) to 0.80 Mg CO₂ equiv.ha^–1 y^–1 (Dark Brown Chernozem). The addition of 50% more or 50% less N-fertilizer both resulted in slight increases in combined CO₂ and N₂O emissions. There was a tradeoff in GHG flux with greaterN₂O emissions and a comparable increase in carbon storage when 50% more N-fertilizer was added. The results from this work indicate that conversion of cultivated land to grassland, the conversion from conventional tillage to no-tillage, and the reduction of summerallow in crop rotations could substantially increase C sequestration and decrease net GHG emissions. Based on these results a simple scaling-up scenario to derive the possible impacts on Canada's Kyoto commitment has been calculated.     

The ACPI Climate Change Simulations

The Parallel Climate Model (PCM) has been used in the Accelerated ClimatePrediction Initiative (ACPI) Program to simulate the global climateresponse to projected CO₂, sulfate, and other greenhouse gasforcingunder a business-as-usual emissions scenario during the 21st century. In these runs, the oceans were initialized to 1995 conditions by a group from the Scripps Institution of Oceanography and other institutions. An ensemble of three model runs was then carried out to the year 2099 using the projected forcing. Atmospheric data fromthese runs were saved at 6-hourly intervals (hourly for certain criticalfields) to support the ACPI objective of accurately modeling hydrologicalcycles over the western U.S. It is shown that the initialization to1995 conditions partly removes the un-forced oceanic temperature and salinity drifts that occurred in the standard 20th century integration. The ACPI runs show a global surface temperature increase of 3–8 °C over northern high-latitudes by the end of the 21st century, and 1–2 °C over the oceans. This is generally within ±0.1°Cof model runs without the 1995 ocean initialization. The exception is in theAntarctic circumpolar ocean where surface air temperature is cooler in theACPI run; however the ensemble scatter is large in this region. Althoughthe difference in climate at the end of the 21st century is minimalbetween the ACPI runs and traditionally spun up runs, it might be largerfor CGCMs with higher climate sensitivity or larger ocean drifts. Ourresults suggest that the effect of small errors in the oceans (such asthose associated with climate drifts) on CGCM-simulated climate changesfor the next 50–100 years may be negligible.