A model for the three-dimensional evolution of continental rift basins,north-east Africa

Large areas of north-east Africa were dominated by regional extension in the Late Phanerozoic. Widespread rifting occurred in the Late Jurassic, with regional extension culminating in the Cretaceous and resulting in the greatest areal extent and degree of interconnection of the west, central and north African rift systems. Basin reactivation continued in the Paleocene and Eocene and new rifts probably formed in the Red Sea and western Kenya. In the Oligocene and Early Miocene, rifts in Kenya, Ethiopia and the Red Sea linked and expanded to form the new east African rift system.This complex history of rifting resulted in failed rift basins with low to high strain geometries, a range of associated volcanism and varying degrees of interaction with older structures. One system, the Red Sea rift, has partially attained active seafloor spreading. From a comparison of these basins, a general model of three-dimensional rift evolution is proposed. Asymmetrical crustal geometries dominated the early phases of these basins, accompanied by low angle normal faulting that has been observed at least locally in outcrop. As rifting progressed, the original fault and basin forms were modified to produce larger, more through-going structures. Some basins were abandoned, others experienced reversals in regional dip and, in general, extension and subsidence became focused along narrower zones near the rift axes. The final transition to oceanic spreading was accomplished in the Red Sea by a change to high angle, planar normal faulting and diffuse dike injection, followed by the organization of an axial magma chamber.     

Inversion of reflection seismograms by differential semblance analysis: algorithm structure and synthetic examples1

Seismograms predicted from acoustic or elastic earth models depend very non-linearly on the long wavelength components of velocity. This sensitive dependence demands the use of special variational principles in waveform-based inversion algorithms. The differential semblance variational principle is well-suited to velocity inversion by gradient methods, since its objective function is smooth and convex over a large range of velocity models. An extension of the adjoint state technique yields an accurate estimate of the differential semblance gradient. Non-linear conjugate gradient iteration is quite successful in locating the global differential semblance minimum, which is near the ordinary least-squares global minimum when coherent data noise is small. Several examples, based on the 2D primaries-only acoustic model, illustrate features of the method and its performance.     

The “susceptibility factor” in the atmospheric response to periodic forcing

Evidence is presented of a periodic component in the inter-annual variability of precipitation and pressure data for India during June, the month of the onset of the Indian southwest monsoon. Two frequencies that explain a statistically significant percent of the variance in these data sets are the same as the two that explain most of the variance of the average monthly lunar tidal potential for June. Not only are the frequencies the same but they are also in phase which strongly suggests that lunar tides in the atmosphere do, in fact, produce an element of climatic variability. The amplitude of the atmospheric response to this periodic forcing was not constant in time but was found to be related to the long term change in northern hemispheric surface temperature. This susceptibility of the atmosphere to an external forcing results in a nonlinear relationship between forcing and response. As a result, nonlinear regression had to be used in order to adequately define the magnitude of the response at a given frequency. The ramifications of this nonlinear response are discussed. The nonlinear interaction of the northern hemisphere temperature and the 18.6 year lunar nodal cycle results in a modulation of the frequency which appears in a linear spectral analysis near 22 years. Thus, the 22-year cycle often found in meteorological data sets may instead be the result of the modulated nodal cycle.     

Partitioning of platinum-group elements and Au in the Fe−Ni−Cu−S system: experiments on the fractional crystallization of sulfide melt

Partitioning of platinum-group elements (PGE) between sulfide liquid and monosulfide solid solution (mss) has been investigated by crystallizingmss from Fe–Ni–Cu sulfide liquid at 1,000–1,040° C, using bulk compositions and PGE contents typical of magmatic sulfides associated with mafic and ultramafic systems. Products were analyzedin situ for PGE and Au using SIMS. Sulfide liquid compositions were more Ni- and Cu-rich than coexistingmss. Liquid/mss partition coefficients are: Os-0.23±0.04, Ir-0.28±0.11, Ru-0.24±0.05, Rh-0.33±0.06, Pt-4.8±0.7, Pd-4.8±1.9, Au-11.4. Partitioning of PGE is independent of PGE concentration and Ni content in the composition range investigated. Additionally, Henry's law appears to be obeyed up to minor-element contents in the sulfide liquid andmss. Osmium, Ir, Ru, and Rh are compatible elements in the anhydrous Fe–Ni–Cu–S system, whereas Pt, Pd and Au are incompatible elements. These affinities correspond to the partitions of PGE between massive and Cu-rich magmatic sulfides. However, the detailed precious-metal compositions of the Cu-rich sulfides of mafic rock systems, disseminated ores of komatiites and Cu-rich assemblage of droplet ore from the Noril'sk-Talnakh deposits are not consistent with those expected for pristine fractionated sulfide liquids.     

Genetic modelling for banded iron-formation of the Hamersley Group, Pilbara Craton, Western Australia

The banded iron-formation (BIF) of the Hamersley Group, Pilbara Craton, Western Australia, particularly from the well studied Dales Gorge Member, is unique in its lateral stratigraphic and petrological continuity throughout an area exceeding 60,000 km², enabling reasonable estimates for the annual input of components to the depository. In the model of this paper, varying supply of materials for the medley of mesoband types, particularly of iron and silica in the oxide BIF, can be accommodated by the interaction of two major oceanic supply systems: (1) surface currents and (2) convective upwelling from mid-oceanic ridge (MOR) or hot-spot activity, both modified by varied input of pyrochastic material. (1) The surface currents were saturated in silica and carried minimal iron due to photic precipitation, but were periodically recharged by storm mixing. Precipitation from them gave rise to the banded chert-rich horizons, including the varves, whose regular and finely laminated iron/silica distribution resulted from seasonal meteorological influences. (2) Precipitation from convection driven upwelling of high iron solution from MOR or hot-spot activity periodically overwhelmed the delicate seasonal patterns of (1) to produce the iron-dominated mesobands. A wide range of intermediate mesoband types resulted where the deep water supply was modified by varied MOR activity, or by partial blocking of upwelling waters by surface currents (such as by the present El Niño). During these periods of oxide-dominated BIF, silica was deposited from saturated solution mainly by evaporative concentration, and iron by oxidation due to photolysis and photosynthetically produced oxygen.Superimposed on these supply differences was the varying effect of fine aluminous ash from dominantly northern distal volcanic sources, changing the meteorological and depositional conditions. Occasional input of extremely fi ash during BIF precipitation produced mesoband (cm) scale variations involving increased carbonate-silicate precipitation. Sustained volcanic periods resulted in S-macroband deposition (chert-carbonate-silicate BIF, with shale), gradually returning to the dominant hematite-magnetite-chert BIF as the volcanic input waned. During volcanic periods, the normally high capacity of sunlight to precipitate ferric iron directly by photolytic oxidation of ferrous iron, and by photosynthetic production of oxygen, was modified by turbidity in the atmosphere (aerosols and dust) and in the water (colloids from reactive ash). S Surface-precipitated ferric hydroxyoxide redissolved in the presence of decaying organic matter in the subphotic zone, augmenting the iron content of the zone. Precursor ferrous carbonates and silicates were precipitated when the iron concentration of this sub-photic zone exceeded their respective solubilities. During volcanism, the increased availability of nutrients, particularly phosphorus, to surface waters increased the organic contribution despite lower light values, leading to an almost total absence of ferric iron oxides in the S macrobands (i.e. no magnetite or hematite). Cooling of warm, silica-saturated sea-water during these periods of “olcanic winter” increased the ratio of precipitation of silica to iron, which, however, was still controlled by seasonal conditions. Intermediate concentrations of organic matter, insufficient to totally convert the ferric compounds either during precipitation or diagenesis, resulted in overgrowths of magnetite on hematite, and eventually in the substantial conversion of hematite to magnetite, where higher temperatures were achieved during low-grade regional metamorphism.Changes in sea-level to explain facies changes in BIF are not required in this model, but are not excluded. The preferred conditions are for a very low oxygen to anoxic atmosphere, a much higher level of MOR activity than at present, the presence of photosynthetic plankton, the absence of si silica-secreting organisms, and a deep sea-water temperature higher than 20°C. However, none of these conditions is essential to the model.A narrow carbonate bank is postulated for part of the Fortescue River Valley area during Marra Mamba Iron Formation times (basal Hamersley Group), with BIF precipitation on either side. The reef is postulated to have grown northward becoming a major shallow-water carbonate platform on the Pilbara continent during upper Marra Mamba Iron Formation and Wittenoom Dolomite times, but ceased to play an important role in subsequent periods.     

The heat capacity of hydrous cordierite above 295 K

The heat capacity of synthetic hydrous cordierite (Mg₂Al₄Si₅O₁₈·nH₂O) has been determined by differential scanning calorimetry (DSC) from 295 to 425 K as a function of H₂O content. Six samples with H₂O contents ranging from 0 to 0.82 per formula unit were examined. The partial molar heat capacity of H₂O in cordierite over the measured temperature interval is independent of composition and temperature within experimental uncertainty and is equal to 43.3 ±0.8 J/mol/ K. This value exceeds the molar heat capacity of gaseous H₂O by 9.7 J/mol/K, but is significantly smaller than the heat capacity of H₂O in several zeolites and liquid H₂O. A statistical-mechanical model of the heat capacity of adsorbed gas species (Barrer 1978) is used to extrapolate the heat capacity of hydrous cordierite to temperatures greater than 425 K. In this model, the heat capacity of hydrous cordierite (Crd·nH₂O) is represented as follows: Cp(Crd · nH₂O) = Cp(Crd)+ n{Cp(H₂O, gas)+ R(gas constant)} (1) An examination of calorimetric data for hydrous beryl, analcime, mordenite, and clinoptilolite (Hemingway et al. 1986; Johnson et al. 1982, 1991, 1992) demonstrates the general applicability of the statistical-mechanical model for the extrapolation of heat capacity data of zeolitic minerals. The heat capacity data for cordierite are combined with the data of Carey and Navrotsky (1992) to obtain the molar enthalpy of formation and enthalpy of hydration of hydrous cordierite as a function of temperature.     

The reconstruction of eighteenth century temperature records through the use of content analysis

The reconstruction of a temperature record for eighteenth century eastern Massachusetts is discussed. In addition to instrumental records diaries were analyzed in order to produce temperature indices. Reliability tests demonstrate that the methodology used is capable of replicating results regardless of changes in coders or intraregional variability in language. Validity tests, comparing diary reconstructions with instrumental records for the same period, produced positive results. A compilation of all climate related data shows the decades of the 1720's, 1750's, and 1760's were cool, while the 1770's and 1790's were warm.     

Rhyodacites,andesites, ferro-basalts and ocean tholeiites from the galapagos spreading center

Volcanic rocks, dredged from depths greater than 1000 m on the Galapagos spreading center, show extreme chemical diversity, including rhyodacites, andesite, ferro-basalts, and low-K oceanic tholeiite. All samples have fresh glassy margins. The ferro-basalts contain up to 18.5% total iron as FeO and up to 3.75% TiO₂, while the oceanic tholeiites are as low as 0.02% K₂O. The ferro-basalts correlate with the previously proposed zone of high magnetic anomaly amplitudes which flank the Galapagos hot spot, and are consistent with a genesis by shallow fractional crystallization.     

Co2+ as a chemical analogue for Fe2+ in high-temperature experiments in basaltic systems

High-temperature experiments on ferromagnesian compositions have been hampered by the rapid absorption of up to 95% of the original iron by platinum and 40% by silver-palladium capsules. Molybdenum or iron capsule materials can decrease or alleviate iron loss, but restrict oxygen fugacities to values near the iron-wustite buffer. Because Co²⁺ is stable at f_O2 =HM and because the solubility of Co in platinum in this range of f_O2 is ～0.05% at temperatures to 1350°C, its use as an analogue for Fe²⁺ is possible. In addition, experiments simulating various Fe²⁺ ratios can be easily performed by choosing appropriate Co²⁺/Fe³⁺ ratios. The cobalt phases produced possess brilliant and distinctive colors which are valuable aids in optical identification of minute phases. The cobalt analogue hypothesis was tested with atmospheric pressure experiments in air on the cobalt analogue of the 1921 Kilauea basalt at three simulated Fe²⁺/Fe³⁺ ratios. The results were compared with those of R.E.T. Hill (1969) for the natural 1921 basalt. The phase relations were the same, with the cobalt system stability fields systematically shifted by about +50°C. Microprobe analysis of olivines and the coexisting glasses indicate that the distribution of Co²⁺ between olivine and melt is independent of temperature and liquid composition. Although the analogue liquid composition differs from the equilibrium composition of the natural system, it may be corrected be employing distribution coefficients (K_D = 0.61 for the Co system; K_D = 0.33 for the Fe system) to closely approximate what the natural system would yield if iron loss did not occur.