Defining the Potential of Nanoscale Re‐Os Isotope Systematics Using Atom Probe Microscopy

Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm³). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS ¹⁸⁷Os/¹⁸⁹Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM ¹⁸⁷Os/¹⁸⁹Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.     

Exurbia from the bottom-up: Confronting empirical challenges to characterizing a complex system

We describe empirical results from a multi-disciplinary project that support modeling complex processes of land-use and land-cover change in exurban parts of Southeastern Michigan. Based on two different conceptual models, one describing the evolution of urban form as a consequence of residential preferences and the other describing land-cover changes in an exurban township as a consequence of residential preferences, local policies, and a diversity of development types, we describe a variety of empirical data collected to support the mechanisms that we encoded in computational agent-based models. We used multiple methods, including social surveys, remote sensing, and statistical analysis of spatial data, to collect data that could be used to validate the structure of our models, calibrate their specific parameters, and evaluate their output. The data were used to investigate this system in the context of several themes from complexity science, including have (a) macro-level patterns; (b) autonomous decision making entities (i.e., agents); (c) heterogeneity among those entities; (d) social and spatial interactions that operate across multiple scales and (e) nonlinear feedback mechanisms. The results point to the importance of collecting data on agents and their interactions when producing agent-based models, the general validity of our conceptual models, and some changes that we needed to make to these models following data analysis. The calibrated models have been and are being used to evaluate landscape dynamics and the effects of various policy interventions on urban land-cover patterns.     

Concentrations,physico-chemical states and mean residence times of 210Pb and 210Po in marine and estuarine waters

The concentrations and physico-chemical states of ²¹⁰Pb have been measured in Bikini Atoll and Washington State coastal waters, and ²¹⁰Po in Washington coastal waters. Lead-210 concentrations of 113–133 dpm · m^?3 were found in surface water collections near Bikini Atoll and 29–153 dpm · m^?3 in Bikini Lagoon. The concentrations of ²¹⁰Pb in near Bikini and in Washington State waters increased with depth in the upper 150m at a rate of 0.35–0.45dpm·m^?3 · m^?1. In the North Equatorial Current waters near Bikini Atoll ²¹⁰Pb was found associated predominantly with the soluble (colloidal) fraction, but in Washington coastal waters ²¹⁰Pb and ²¹⁰Po were found associated with the paniculate (> 0.3 μm) fraction. The mean residence times of ²¹⁰Pb, calculated from the atmospheric input to marine waters from precipitation and the concentrations measured in surface water, were consistent with the physico-chemical states of ²¹⁰Pb found in samples collected in deep ocean and coastal waters. Approximate values of the mean residence times were calculated, for the upper 50 m, to be as follows: 58 days in the Strait of Juan de Fuca, 128 days at the 5-mile (8 km) station off Cape Flattery (Washington), 163 days at the 12-mile (19 km) station off Cape Flattery, and 2.6 yr near Bikini Atoll. It appears that ²¹⁰Pb and ²¹⁰Po can be used to trace particle removal rates in the upper layers of marine waters.     

Initial results and progress of the Mississippi delta sediment pore water pressure experiment

Abstract

This report describes the instrumentation, initial results, and progress of an experiment designed to measure and monitor submarine sediment pore water and hydrostatic pressures in a selected area of the Mississippi Delta. The experiment also is intended to monitor significant pressure perturbations during active storm periods. Initial analysis of the data revealed excess pore water pressures in the silty clay sediment at selected depths below the mudline. Continuous monitoring of the pore water and hydrostatic pressures was expected to reveal important information regarding sediment pore water pressure variations as a function of the geological processes active in the Mississippi Delta.     

Developing coastal adaptation to climate change in the New York City infrastructure-shed: process, approach, tools, and strategies

While current rates of sea level rise and associated coastal flooding in the New York City region appear to be manageable by stakeholders responsible for communications, energy, transportation, and water infrastructure, projections for sea level rise and associated flooding in the future, especially those associated with rapid icemelt of the Greenland and West Antarctic Icesheets, may be outside the range of current capacity because extreme events might cause flooding beyond today??s planning and preparedness regimes. This paper describes the comprehensive process, approach, and tools for adaptation developed by the New York City Panel on Climate Change (NPCC) in conjunction with the region??s stakeholders who manage its critical infrastructure, much of which lies near the coast. It presents the adaptation framework and the sea-level rise and storm projections related to coastal risks developed through the stakeholder process. Climate change adaptation planning in New York City is characterized by a multi-jurisdictional stakeholder?Cscientist process, state-of-the-art scientific projections and mapping, and development of adaptation strategies based on a risk-management approach.     

Structure and dynamics of the Bok globule B335

CO maps of the Bok globule B335 are presented and used to derive its density profile, mass distribution, and rotational velocity structure. It is found that the cloud is in nearly hydrostatic equilibrium with a density profile that varies roughly as r^?1 in the core and r^?3 in the envelope. The observed rotation is unimportant in the force balance at the present stage of evolution.     

Late Wisconsinan glaciation models of northern Maine and adjacent Canada

Surficial stratigraphic units of Aroostook County, Maine, have been mapped and formal stratigraphic names for these units are proposed. Evidence exists for at least two distinct glacial phases which are represented by three tills. Two of these tills were deposited penecontemporaneously either as the result of coalescing ice sheets or as the result of the thermal regime existing within a single ice sheet. The oldest till is named the St. Francis and is correlated with the Chaudière Till of southeastern Quebec. The other tills are named the Mars Hill and Van Buren tills, respectively, and are correlated with the Lennoxville till of southeastern Quebec. Interbedded stratified sediments associated with the St. Francis till are correlated with the Gayhurst Formation. Stratified sediments associated with Van Buren and Mars Hill tills are correlated with post Lennoxville sediments of Quebec. Granite-gneiss erratics of Canadian Shield provenance in the Van Buren till indicate advance of the Laurentide ice into northern Maine during late Wisconsinan time. Moraines in southern Aroostook County with associated outwash and eskers record general recession from coastal Maine. Recession occurred after the formation of the Pineo Ridge moraine in Maine and the St. Antonin-Highland Front moraine complex in Quebec. The Caribou-Winterville moraine complex in northern Maine marks the boundary between the penecontemporaneously deposited Van Buren and Mars Hill surface tills and is correlated with the Grand Falls moraine at Grand Falls, New Brunswick.     

Crustal structure of the Ruby Mountains and southern Carlin Trend region, Nevada, from magnetotelluric data

We have collected about 150 magnetotelluric (MT) soundings in northeastern Nevada in the region of the Ruby Mountains metamorphic core complex uplift and southern Carlin mineral trend, in an effort to illuminate controls on core complex evolution and deposition of world-class gold deposits. The region has experienced a broad range of tectonic events including several periods of compressional and extensional deformation, which have contributed to the total expression of electrical resistivity. Most of the soundings reside in three east–west profiles across increasing degrees of core uplift to the north (Bald Mountain, Harrison Pass, and Secret Pass latitudes). One short cross-line was also taken to assess an east–west structure to the north of the northern profile. Model resistivity cross-sections were derived from the MT data using a 2-D inversion algorithm, which damps departures of model parameters from an a priori structure. Geological interpretation of the resistivity combines previous seismic, potential field and isotope models, structural and petrological models for regional compression and extension, and detailed structural/stratigraphic interpretations incorporating drilling for petroleum and mineral exploration. To first order, the resistivity structure is one of a moderately conductive, Phanerozoic sedimentary section fundamentally disrupted by intrusion and uplift of resistive crystalline rocks. Late Devonian and early Mississippian shales of the Pilot and Chainman Formations together form an important conductive marker sequence in the stratigraphy and show pronounced increases in conductance (conductivity–thickness product) from east to west. These increases are attributed to graphitization caused by Elko–Sevier era compressional shear deformation and possibly by intrusive heating. The resistive crystalline central massifs adjoin the host stratigraphy across crustal-scale, steeply dipping fault zones. The zones provide pathways to the lower crust for heterogeneous, upper crustal induced, electric current flow. Resistive core complex crust appears steeply bounded under the middle of the neighboring grabens and not to deepen at a shallow angle to arbitrary distances to the west. The numerous crustal breaks imaged with MT may contribute to the low effective elastic thickness (T_e) estimated regionally for the Great Basin and exemplify the mid-crustal, steeply dipping slip zones in which major earthquakes nucleate. An east–west oriented conductor in the crystalline upper crust spans the East Humboldt Range and northern Ruby Mountains. The conductor may be related to nearby graphitic metasediments, with possible alteration by middle Tertiary magmatism. Lower crustal resistivity everywhere under the profiles is low and appears quasi one-dimensional. It is consistent with a low rock porosity (<1 vol.%) containing hypersaline brines and possible water-undersaturated crustal melts, residual to the mostly Miocene regional extension. The resistivity expression of the southern Carlin Trend (CT) in the Pinon Range is not a simple lineament but rather a family of structures attributed to Eocene intrusion, stratal deformation, and alteration/graphitization. Substantial reactivation or overprinting by core complex uplift or Basin–Range extensional events seems likely. We concur with others that the Carlin Trend may result in part from overlap of the large Eocene Northeast Nevada Volcanic Field with Precambrian–Paleozoic deep-water clastic source rocks thickening abruptly to the west of the Pinon Range, and projecting to the north–northwest.     

Spatio-temporal variability of small copepods (especially Oithona plumifera) in shallow nearshore waters off the south coast of South Africa

Although small copepods are one of the main dietary sources for many commercially important fish, their role in the pelagic trophic dynamics has traditionally been underestimated due to the methodology commonly used in plankton sampling. Temporal variation in abundance of adults and nauplii of small copepods (particularly Oithona plumifera) in nearshore waters on the south coast of South Africa was investigated fortnightly over 14 months at site (km) and location (100 m) scales. Sampling was within <500 m of the shore, where depth was ca. 10 m, using vertical hauls of an 80-μm mesh plankton net from 1 m above the seabed to the surface. Twenty-seven adult copepod taxa were recorded, but Oithona spp. was consistently the most abundant. Taxon richness was 7–19 on each sampling occasion. There was strong temporal variation (Oithona varied between 0 and 2300 m⁻³), but much of this was short-term variability (e.g. between consecutive sampling sessions), with no seasonality or other long-term discernable patterns. There were periods of consistently low numbers, but very high numbers often followed samples with low abundances. Nor was there spatial structure at the location scale, though numbers differed between sites. Despite considerable variability at the location scale within sites, Kenton consistently showed higher densities than High Rocks. Separate analyses, with Bonferroni adjustment, showed that this difference was significant on eight out of 21 occasions for Oithona, six for other pelagic copepods and three for nauplii. This suggests that hydrodynamics favour aggregation of plankton at Kenton. A high degree of short-term variability, with a tendency for aggregation of small zooplankton at certain sites has implications for both pelagic processes and food-web links between the benthic and pelagic environments.