A mineral inclusion, carbon isotope, nitrogen content, nitrogen aggregation state and morphological study of 576 microdiamonds from the DO27, A154, A21, A418, DO18, DD17 and Ranch Lake kimberlites at Lac de Gras, Slave Craton, was conducted. Mineral inclusion data show the diamonds are largely eclogitic (64%), followed by peridotitic (25%) and ultradeep (11%). The paragenetic abundances are similar to macrodiamonds from the DO27 kimberlite (Davies, R.M., Griffin, W.L., O'Reilly, S.Y., 1999. Diamonds from the deep: pipe DO27, Slave craton, Canada. In: Gurney, J.J., Gurney, J.L., Pascoe, M.D., Richardson, S.H. (Eds.), The J. B. Dawson Vol., Proc. 7th Internat. Kimberlite Conf., Red Roof Designs, Cape Town, pp. 148–155) but differ to diamonds from nearby kimberlites at Ekati (e.g., Lithos (2004); Tappert, R., Stachel, T., Harris, J.W., Brey, G.P., 2004. Mineral Inclusions in Diamonds from the Panda Kimberlite, S. P., Canada. 8th International Kimberlite Conference, extended abstracts) and Snap Lake to the south (Dokl. Earth Sci. 380 (7) (2001) 806), that are dominated by peridotitic stones.
Eclogitic diamonds with variable inclusion compositions and temperatures of formation (1040–1300 °C) crystallised at variable lithospheric depths sometimes in changing chemical environments. A large range to very 13C-depleted C-isotope compositions (δ13C=−35.8‰ to −2.2‰) and an NMORB bulk composition, calculated from trace elements in garnet and clinopyroxene inclusions, are consistent with an origin from subducted oceanic crust and sediments. Carbon isotopes in the peridotitic diamonds have mantle compositions (δ13C mode −4.0‰). Mineral inclusion compositions are largely harzburgitic. Variable temperatures of formation (garnet TNi=800–1300 °C) suggest the peridotitic diamonds originate from the shallow ultra-depleted and deeper less depleted layers of the central Slave lithosphere. Carbon isotopes (δ13C av.=−5.1‰) and mineral inclusions in the ultradeep diamonds suggest they formed in peridotitic mantle (670 km). The diamonds may have been entrained in a plume and subcreted to the base of the central Slave lithosphere.
Poorly aggregated nitrogen (IaA without platelets) in a large number of eclogitic (67%) and peridotitic (32%) diamonds, with similar nitrogen contents, indicates the diamonds were stored in the mantle at low temperatures (1060–<1100 °C) following crystallisation in the Archean. Type IaA diamonds have largely cubo-octahedral growth forms, and Type II and Type IaAB diamonds, with higher nitrogen aggregation states, mostly have octahedral morphologies. However, no correlation between these groups and their mineral inclusion compositions, C-isotopes, and N-contents rules out the possibility of unique source origins and suggests eclogitic and peridotitic diamonds experienced variable mantle thermal states. Variation in mineral inclusion chemistries in single diamonds, possible overgrowths of 13C-depleted eclogitic diamond on diamonds with peridotitic and ultradeep inclusions, and Type I ultradeep diamond with low N-aggregation is consistent with diamond growth over time in changing chemical environments. 相似文献
The "Taihua Group" is a collective term for a series of old terranes scattered along the southern margin of the North China Craton. The timing of formation and thermal overprinting of the Taihua Group have long been contentious, and its relationship with the Qinling orogenic belt has been unclear. In this study, new data from integrated in-situ U–Pb dating and Hf isotope analysis of zircons from an amphibolite (from the Xiong’ershan terrane) and a biotite gneiss (from the Lantian-Xiaoqinling terrane) indicate that the Upper Taihua Group formed during the Paleoproterozoic (2.3–2.5 Ga) and thus was originally part of the southern edge of North China Craton, detached during the Mesozoic Qinling orogeny and displaced about 100 km north from its original location. This suggests that the Taihua Group became part of the tectonic terrane associated with the Qinling orogeny and now forms part of the overthrust basement section of the Qinling belt. Before the Qinling orogeny, the Taihua Group was metamorphosed at 2.1 Ga. The initial Hf-isotope compositions of zircons, together with positive εNd(t) values for the whole-rocks, imply that the original magmas were derived from a juvenile source with some assimilation of an Archean crustal component. 相似文献
Thermodynamic calculations and Gibbs free energy minimization computer experiments strongly support the hypothesis that kerogen maturation and oil generation are inevitable consequences of oxidation/reduction disproportionation reactions caused by prograde metamorphism of hydrocarbon source rocks with increasing depth of burial.These experiments indicate that oxygen and hydrogen are conserved in the process.Accordingly, if water is stable and present in the source rock at temperatures ?25 but ?100 °C along a typical US Gulf Coast geotherm, immature (reduced) kerogen with a given atomic hydrogen to carbon ratio (H/C) melts incongruently with increasing temperature and depth of burial to produce a metastable equilibrium phase assemblage consisting of naphthenic/biomarker-rich crude oil, a type-II/III kerogen with an atomic hydrogen/carbon ratio (H/C) of ∼1, and water. Hence, this incongruent melting process promotes diagenetic reaction of detritus in the source rock to form authigenic mineral assemblages.However, in the water-absent region of the system CHO (which is extensive), any water initially present or subsequently entering the source rock is consumed by reaction with the most mature kerogen with the lowest H/C it encounters to form CO2 gas and a new kerogen with higher H/C and O/C, both of which are in metastable equilibrium with one another.This hydrolytic disproportionation process progressively increases both the concentration of the solute in the aqueous phase, and the oil generation potential of the source rock; i.e., the new kerogen can then produce more crude oil.Petroleum is generated with increasing temperature and depth of burial of hydrocarbon source rocks in which water is not stable in the system CHO by a series of irreversible disproportionation reactions in which kerogens with higher (H/C)s melt incongruently to produce metastable equilibrium assemblages consisting of crude oil, CO2 gas, and a more mature (oxidized) kerogen with a lower H/C which in turn melts incongruently with further burial to produce more crude oil, CO2 gas, and a kerogen with a lower H/C and so forth.The petroleum generated in the process progresses from heavy naphthenic crude oils at low temperatures to mature petroleum at ∼150 °C. For example, the results of Computer Experiment 27 (see below) indicate that the overall incongruent melting reaction in the water-absent region of the system C-H-O at 150 °C and a depth of ∼4.3 km of an immature type-II/III kerogen with a bulk composition represented by C292H288O12(c) to produce a mature (oxidized) kerogen represented by C128H68O7(c), together with a typical crude oil with an average metastable equilibrium composition corresponding to C8.8H16.9 (C8.8H16.9(l)) and CO2 gas (CO2(g)) can be described by writing
The processes of organic maturation that occur during the permineralization of fossils and the detailed chemistry of the resulting products are incompletely understood. Primary among such processes is the geochemical alteration of biological matter to produce kerogen, such as that which comprises the cell walls of the fossils studied here: essentially unmetamorphosed, Eocene plant axes (specimens of the fossil fern Dennstaedtiopsis aerenchymata cellularly permineralized in cherts of the Clarno Formation of Oregon and the Allenby Formation of British Columbia). The composition and molecular structure of the kerogen that comprises the cell walls of such axes were analyzed using ultraviolet Raman spectroscopy (UV–Raman), solid state 13C nuclear magnetic resonance spectroscopy (13C NMR) and pyrolysis–gas chromatography–mass spectrometry (py–GC–MS).Cellularly well-preserved fern axes from both geologic units exhibit similar overall molecular structure, being composed primarily of networks of aromatic rings and polyene chains that, unlike more mature kerogens, lack large polycyclic aromatic hydrocarbon (PAH) constituents. The cell walls of the Allenby Formation specimens are, however, less altered than those of the Clarno chert, exhibiting more prevalent oxygen-containing and alkyl functional groups and comprising a greater fraction of rock mass.The study represents the first demonstration of the effectiveness (and limitations) of the combined use of UV–Raman, 13C NMR and py–GC–MS for the analysis of the kerogenous cell walls of chert-permineralized vascular plants. 相似文献
Analysis of salinity data from Mobile Bay indicates that stratification-destratification events within this broad, shallow estuary are not uncommon. These events are related to the strength of the winds, through their influence on wave generation and subsequent bottom drag coefficient increases, and to the strength of river discharge. They do not appear to be due to the strength of tidal currents, as has been observed elsewhere. Furthermore, river flow appears to be the dominant control, the winds being important only in the absence of large freshwater discharges. The annual spring freshet can flush most of the salt from the bay. During other times of the year the relative strengths of river discharge and wind stress change the bay from highly stratified to nearly homogeneous and back on a variety of time scales ranging from daily to seasonal. 相似文献
About half of the lunar meteorites in our collections are feldspathic breccias. Acquiring geochronologic information from these breccias is challenging due to their low radioactive-element contents and their often polymict nature. We used high-spatial-resolution (5 μm) NanoSIMS (nanoscale secondary ion mass spectrometry) U-Pb dating technique to date micro-zircons in the lunar feldspathic meteorites Dhofar 1528 and Dhofar 1627. Three NanoSIMS dating spots of two zircon grains from Dhofar 1528 show a discordia with an upper intercept at 4354 ± 76 Ma and a lower intercept at 332 ± 1407 Ma (2σ, MSWD = 0.01, p = 0.91). Three spots of two zircon grains in Dhofar 1627 define a discordia with an upper intercept at 3948 ± 30 Ma and a lower intercept at 691 ± 831 Ma (2σ, MSWD = 0.40, p = 0.53). Both samples likely experienced shock metamorphism caused by impacts. Based on the clastic nature, lack of recrystallization and the consistent U-Pb and Pb-Pb dates of the zircons in Dhofar 1528, the U-Pb date of 4354 Ma is interpreted as the crystallization age of its Mg-suite igneous precursor. Some of the Dhofar 1627 zircons show poikilitic texture, a crystallization from the matrix impact melt, so the U-Pb date of 3948 Ma corresponds to an impact event, likely the Imbrium basin-forming event. These data are the first radiometric ages for these two meteorites and demonstrate that in situ (high spatial resolution) U-Pb dating has potential for extracting geochronological information about igneous activities and impact events from lunar feldspathic and polymict breccias. 相似文献
Although the field of view of the Normal Incidence Spectrometer (NIS) of the Coronal Diagnostic Spectrometer (CDS) is 4×4 arc min, it is possible to observe the full solar disk by forming a mosaic of images taken in succession. This paper describes just such a study which has been used to collect images of the Sun simultaneously in six wavelengths between 304 Ú and 630 Ú, and with a temperature coverage between 5×104 K and 2.5×106 K. A representative sample of the resulting images is presented. These data can be used to explore the origin of solar EUV variability, and examine large-scale solar features. Another use of these data is to calibrate the pointing of the CDS Offset Pointing System (OPS), by comparing them against the SOHO Extreme ultraviolet Imaging Telescope (EIT) full-disk images taken at the same time. Many joint observations are made with CDS and other SOHO instruments, and calibration of the pointing is crucial to the co-pointing of the instruments, and to the analyses of these data. Coalignment is done by fitting to a cross-correlation function, using an IDL procedure which can be applied to any CDS/NIS data set. The accuracy of an individual coalignment can be demonstrated to be in the range 1–2 arc sec. The overall accuracy of the OPS calibration is ±5 arc sec, mainly attributable to measurement error in the actuator positions. An onboard Spartan Intermediate Sun Sensor of the Lockheed design, which was intended to provide greater pointing accuracy, exhibits a time-varying calibration, possibly due to a gradual loss of sensitivity. 相似文献
We searched for a variation with heliographic latitude of the solar limb effect by comparing the relative wavelengths of weak and strong Fraunhofer lines. The blue shifts associated with the limb effect appear 9%±5% larger in the polar radius vector than in an equatorial radius vector at cos = 0.5. This should perhaps be interpreted as an increase with latitude of either solar convection or of convective overshoot. Recent observations of poleward meridional flows of 30m s–1 should be corrected for this limb effect variation. This correction increases this flow velocity to 70 m s–1. A search for a similar variation in plages and in network boundaries had negative results, the variation being +1%±5% and -1%±6% respectively.Now at the Multiple Mirror Telescope Observatory, University of Arizona, Tucson, Ariz. 85721, U.S.A. The MMTO is jointly operated by the University of Arizona and the Smithsonian Institution.The Sacramento Peak Observatory is operated by the Association of Universities for Research in Astronomy, Inc. under contract AST 78-17292 with the National Science Foundation. 相似文献
Abstract— Martian meteorites (MMs) have been launched from an estimated 5–9 sites on Mars within the last 20 Myr. Some 80–89% of these launch sites sampled igneous rock formations from only the last 29% of Martian time. We hypothesize that this imbalance arises not merely from poor statistics, but because the launch processes are dominated by two main phenomena: first, much of the older Martian surface is inefficient in launching rocks during impacts, and second, the volumetrically enormous reservoir of original cumulate crust enhances launch probability for 4.5 Gyr old rocks. There are four lines of evidence for the first point, not all of equal strength. First, impact theory implies that MM launch is favored by surface exposures of near‐surface coherent rock (≤102 m deep), whereas Noachian surfaces generally should have ≥102 m of loose or weakly cemented regolith with high ice content, reducing efficiency of rock launch. Second, similarly, both Mars Exploration Rovers found sedimentary strata, 1–2 orders of magnitude weaker than Martian igneous rocks, favoring low launch efficiency among some fluvial‐derived Hesperian and Noachian rocks. Even if launched, such rocks may be unrecognized as meteorites on Earth. Third, statistics of MM formation age versus cosmic‐ray exposure (CRE) age weakly suggest that older surfaces may need larger, deeper craters to launch rocks. Fourth, in direct confirmation, one of us (N. G. B.) has found that older surfaces need larger craters to produce secondary impact crater fields (cf. Barlow and Block 2004). In a survey of 200 craters, the smallest Noachian, Hesperian, and Amazonian craters with prominent fields of secondaries have diameters of ?45 km, ?19 km, and ?10 km, respectively. Because 40% of Mars is Noachian, and 74% is either Noachian or Hesperian, the subsurface geologic characteristics of the older areas probably affect statistics of recognized MMs and production rates of secondary crater populations, and the MM and secondary crater statistics may give us clues to those properties. 相似文献
This article examines social conditions in a bay experiencing population growth, gear conflict, overfishing, and general resource decline. Sample surveys of fishing households carried out in 1980 and 1993 in nine villages of San Miguel Bay reveal patterns of continuity and change. The key continuity is sustained overall population growth in fishing villages. Among the key forms of change are those which demonstrate a degree of adaptation to resource decline: decreased participation in fishing; greater reliance of fishing households on nonfishing income; increased dependence on remittances of nonhousehold children; increased participation of women in nonhousehold labor; and dramatic growth in the number of fishing organizations involved in resource management. The findings suggest that resource management policies should be patterned after spontaneous adaptations to resource decline. 相似文献