Experimental transport of Si,Al and Mg in hydrothermal solutions: an application to vein mineralization during high-pressure,low-temperature metamorphism in the French Alps

A study of hydrothermal vein mineralization in meta-argillites subjected to high-pressure, low-temperature metamorphism reveals that ferromagnesian (e.g., chlorite) and pure aluminosilicate (e.g., pyrophyllite) mineralization can be correlated with regimes of increasing and decreasing temperature, respectively. An experimental study of the transport of silica, aluminum and magnesium in hydrothermal solutions has been undertaken to simulate variations in the physical conditions during metamorphism and the accompanying mass transport in a closed system. Thermodynamic and kinetic analysis of the experimental results indicates that local equilibrium among aqueous and mineral phases controls the distribution and composition of hydrothermal vein mineralization and that vein mineralogy can be used to infer the sense of variation of pressure and temperature during metamorphism.     

Climatic forcing before,during, and after the 8.2 Kyr B.P. global cooling event

This paper attempts at full characterization of the unique global 8.2 Kyr B.P. cooling event. Significant atmospheric cooling started during 9.5–8.5 Kyr B.P. when the Sun was extremely quiet during three periods of ∼ 50–100 years. The flood of melt water in the N. Atlantic from glacial lakes during the demise of the Laurentide ice sheet, starting at ∼ 8.5 Kyr B.P., adds to the atmospheric cooling. Climatic forcing events occurred at 8.5 Kyr B.P., at 8.2 Kyr B.P. and finally at 8.06 Kyr B.P., leading to concurrent increases or decreases in the atmospheric Δ¹⁴C levels, completely consistent with the climatic forcing proposed here.     

Benthic studies in upper Buzzards Bay,Massachusetts: 2011/12 as compared to 1955

Precise biodiversity mapping that can be compared over decades would greatly inform the discussion of climate change impacts on species richness and shifts in dominant benthic species. Buzzards Bay, Massachusetts, USA, has a long history of field studies documenting benthic community structure. This bioassessment compares 1955 benthic infaunal sampling results with 2011/2012 samples to determine whether there has been a compositional change. I also compared structural components including grain size and near‐bottom temperatures. In addition, benthic temperature rise and fall was logged at 15‐min intervals from May to October of consecutive years. There was an observed difference in the benthic compositional structure, substrate and temperature between the 1955 and 2011/2012 station conditions. The 1955 identification of Buzzards Bay as being nutrient poor and having a reported 20.5 °C benthic temperature maximum has changed. Coastal development has brought increased nutrient inputs, and the 2012 bottom temperature maximum was at least 4 °C greater. These conditions contribute to shifts in benthic species dominance, and the substrate itself has been transformed to shell reefs at the stations where the gastropod Crepidula fornicata proliferated.     

Galaxy concentrations are trimodal

We have analysed the distribution of inclination-corrected galaxy concentrations in the Sloan Digital Sky Survey. We find that unlike most galaxy properties, which are distributed bimodally, the distribution of concentrations is trimodal: it exhibits three distinct peaks. The newly discovered intermediate peak, which consists of early-type spirals and lenticulars, may contain ∼60 per cent of the number density and ∼50 per cent of the luminosity density of  ^0.1 M_r < −17  galaxies in the local universe. These galaxies are generally red and quiescent, although the distribution contains a tail of blue star-forming galaxies and also shows evidence of dust. The intermediate-type galaxies have higher apparent ellipticities than either disc or elliptical galaxies, most likely because some of the face-on intermediate types are misidentified as ellipticals. Their physical half-light radii are smaller than the radii of either the disc or elliptical galaxies, which may be evidence that they form from disc fading. The existence of a distinct peak in parameter space associated with early-type spiral galaxies and lenticulars implies that they have a distinct formation mechanism and are not simply the smooth transition between disc-dominated and spheroid-dominated galaxies.     

Ammonium and phosphate dynamics in a Virginia salt marsh

Experimental chambers were used in a Virginia salt marsh to partition the tidal flux of dissolved nutrients occurring at the marsh surface and in the water column. On five dates from June to October 1989, six replicate chambers in the short Spartina alterniflora zone were monitored over complete tidal cycles. When reservoir water, used to simulate tidal flooding in the chambers, was initially low in dissolved nutrients, the marsh surface was a source of both ammonium and phosphate to the water column. Calculations of the physical processes of diffusion and advection could not account for total nutrient release from the marsh surface. We hypothesize the primary source of nutrients was organic matter mineralization in surface sediments, which released nutrients into the flooding water column. Assimilation (uptake) of phosphate measured in water-column incubation experiments was nearly equal to phosphate released from the marsh surface. Surface release of ammonium, however, was somewhat greater than water-column uptake. In this salt marsh, benthic production and release of ammonium and phosphate is comparable in magnitude to pelagic consumption, thereby yielding only a small “net” transfer of these nutrients to the estuary.     

A direct determination of the oxygen isotope fractionation between quartz and magnetite at 600 and 800°C and 5 kbar

The partitioning of oxygen isotopes between quartz and magnetite was measured at 600 and 800 C and 5 kbar, using an internally heated pressure vessel equipped with a Shaw-membrane. Through adjustment of the hydrogen fugacity the starting material, fayalite, was decomposed to form quartz and magnetite. The isotopic composition difference between the separated quartz and magnetite fraction was measured directly. As the mineral separates were not completely pure, a correction was applied to the measured fractionations. The independence of the measured isotopic composition differences of run length, the initial isotopic composition of the starting materials as well as the isotopic composition difference between them suggests that the fractionations, 1000 In α_Q-M = 7.8 ± 0.4% at 600°C and 1000 In α_Q-M = 6.1 ± 0.2% at 800°C, represent equilibrium values.