Ammonium excretion by benthic invertebrates and sediment-water nitrogen flux in the Gulf of Mexico near the Mississippi River outflow

Benthic macroinvertebrate biomass and ammonium excretion rates were measured at four stations in the Gulf of Mexico near the Mississippi River mouth. Calculated areal excretion rates were then compared to sediment-water nitrogen fluxes measured in benthic bottom lander chambers at similar stations to estimate the potential importance of macroinvertebrate excretion to sediment nitrogen mineralization. Excretion rates for individual crustaceans (amphipods and decapods) was 2–21 nmoles NH₄ ⁺ (mg dry weight)^?1 h^?1. The mean excretion rates for the polychaetes, Paraprionaspio pinnata [6–12 nmoles NH₄ ⁺ (mg dry weight)^?1h^?1] and Magelona sp. [27–53 nmoles NH₄ ⁺ (mg dry weight)^?1h^?1], were comparable or higher than previous measurements for similar size benthic or pelagic invertebrates incubated at the same temperature (22±1°C). Although the relatively high rates of excretion by these selective feeders may have been partially caused by experimental handling effects (e.g., removal from sediment substrates), they probably reflected the availability of nitrogen-rich food supplies in the Mississippi River plume. When the measured weight-specific rates were extrapolated to total areal biomass, areal macroinvertebrate excretion estimates ranged from 7 μmole NH₄ ⁺ m^?2h^?1 at a 40-m deep station near the river mouth to 18 μmole NH₄ ⁺ m^?2h^?1 at a shallower (28-m deep) station further from the river mouth. The net flux of ammonium and nitrate from the sediments to the water measured in bottom lander chambers in the same region were 15–53 μmole NH₄ ⁺ m^?2h^?1 and ?25–21 μmole NO₃ ^? m^?2h^?1. These results suggest that excretion of NH₄ ⁺ by macroinvertebrates could be a potentially important component of benthic nitrogen regeneration in the Mississippi River plume-Gulf shelf region.     

Computations and estimates of rate coefficients for hydrocarbon reactions of interest to the atmospheres of the outer solar system

The rate coefficients, including Arrhenius parameters, have been computed for a number of chemical reactions involving hydrocarbon species for which experimental data are not available and which are important in planetary atmospheric models. The techniques used to calculate the kinetic parameters include the Troe and semiempirical bond energy-bond order (BEBO) or bond strength-bond length (BSBL) methods.     

Evaluation of two direct immunoassays for rapid detection of petroleum products on marine birds

To reduce rehabilitation time and improve survival, a practical, objective test is needed to determine if marine birds are contaminated with oil before they enter captivity. The RaPID Assays and EnviroGard immunoassays for detection of polycyclic aromatic hydrocarbons (PAHs) in soil were evaluated for their ability to detect petroleum on feather samples from 30 intermediate fuel oil contaminated and 30 uncontaminated common murres (Uria aalge). Sensitivity, specificity, positive and negative predictive value, precision, and time required to run each assay were determined. The RaPID Assays was 96.7% sensitive and specific, while the EnviroGard assay was 93.3% sensitive, and 90.0% specific. Sensitivity decreased at higher dilutions for both assays. Intra-replicate variation was less than 20%. Our evaluation showed that these immunoassays are rapid and cost-effective methods for detecting oil-contamination on the plumage of seabirds, with the EnviroGard assay being more practical in most oil spill response situations due to ease of use and rapidity of results.     

The caldera-forming eruption of Volcán Ceboruco, Mexico

3 of magma erupted, ∼95% of which was deposited as fall layers. During most of the deposition of P1, eruptive intensity (mass flux) was almost constant at 4–8×10⁷ kg s⁻¹, producing a Plinian column 25–30 km in height. Size grading at the top of P1 indicates, however, that mass flux waned dramatically, and possibly that there was a brief pause in the eruption. During the post-P1 phase of the eruption, a much smaller volume of magma erupted, although mass flux varied by more than an order of magnitude. We suggest that caldera collapse began at the end of the P1 phase of the eruption, because along with the large differences in mass flux behavior between P1 and post-P1 layers, there were also dramatic changes in lithic content (P1 contains ∼8% lithics; post-P1 layers contain 30–60%) and magma composition (P1 is 98% rhyodacite; post-P1 layers are 60–90% rhyodacite). However, the total volume of magma erupted during the Jala pumice event is close to that estimated for the caldera. These observations appear to conflict with models which envision that, after an eruption is initiated by overpressure in the magma chamber, caldera collapse begins when the reservoir becomes underpressurized as a result of the removal of magma. The conflict arises because firstly, the P1 layer makes up too large a proportion (∼75%) of the total volume erupted to correspond to an overpressurized phase, and secondly, the caldera volume exceeds the post-P1 volume of magma by at least a factor of three. The mismatches between model and observations could be reconciled if collapse began near the beginning of the eruption, but no record of such early collapse is evident in the tephra sequence. The apparent inability to place the Jala pumice eruptive sequence into existing models of caldera collapse, which were constructed to explain the formation of calderas much greater in volume than that at Ceboruco, may indicate that differences in caldera mechanics exist that depend on size or that a more general model for caldera formation is needed. Received: 18 November 1998 / Accepted: 23 October 1999     

Experimental constraints on pre-eruptive water contents and changing magma storage prior to explosive eruptions of Mount St Helens volcano

Compositionally diverse dacitic magmas have erupted from Mount St Helens over the last 4000 years. Phase assemblages and their compositions in these dacites provide information about the composition of the pre-eruptive melt, the phases in equilibrium with that melt and the magmatic temperature. From this information pre-eruptive pressures and water fugacities of many of the dacites have been inferred. This was done by conducting hydrothermal experiments at 850°C and a range of pressures and water fugacities and combining the results with those from experiments at temperatures of 780 and 920°C, to cover the likely range in equilibration conditions of the dacites. Natural phase assemblages and compositions were compared with the experimental results to infer the most likely conditions for the magmas prior to eruption. Water contents disolved in the melts of the dacites were then estimated from the inferred conditions. Water contents in the dacites have varied greatly, from 3.7 to 6.5 wt.%, in the last 4000 years. Between 4000 and about 3000 years ago the dacites tended to be water saturated and contained 5.5 to 6.5 wt.% water. Since then, however, the dacites have been significantly water-undersaturated and contained less than 5.0 wt.% water. These dacites have tended to be hotter and more mafic, and andesitic and basaltic magmas have erupted. These changes can be explained by variable amounts of mixing between felsic dacite and basalt, to produce hotter, drier and more mafic dacites and andesites. The magma storage region of the dacitic magmas has also varied significantly during the 4000 years, with shifts to shallower levels in the crust occurring within very short time periods, possibly even two years. These shifts may be related to fracturing of overlying roof rock as a result of magma with-drawal during larger volume eruptions.     

Collection of intact sediment cores with overlying water to study nitrogen- and oxygen-dynamics in regions with seasonal hypoxia

Settled particles of fresh, labile organic matter may be a significant source of oxygen demand and nutrient regeneration in seasonally-hypoxic regions caused by nutrient inputs into stratified coastal zones. Studying the dynamics of this material requires sediment sampling methods that include flocculent organic materials and overlying water (OLW) at or above the sediment–water interface (SWI). A new coring device (“HYPOX” corer) was evaluated for examining nitrogen- (N) and oxygen-dynamics at the SWI and OLW in the northern Gulf of Mexico (NGOMEX). The HYPOX corer consists of a “Coring Head” with a check-valve, a weighted “Drive Unit,” and a “Lander,” constructed from inexpensive components. The corer collected undisturbed sediment cores and OLW from sediments at NGOMEX sampling sites with underlying substrates ranging from sand to dense clay. The HYPOX corer could be deployed in weather conditions similar to those needed for a multi-bottle rosette water-sampling system with 20 L bottles. As an example of corer applicability to NGOMEX issues, NH₄⁺ cycling rates were examined at hypoxic and control sites by isotope dilution experiments. The objective was to determine if N-dynamics in OLW were different from those in the water column. “Ammonium demand,” as reflected by potential NH₄⁺ uptake rates, was higher in OLW than in waters collected from a meter or more above the bottom at both sites, but the pattern was more pronounced at the hypoxia site. By contrast, NH₄⁺ regeneration rates were low in all samples. These preliminary results suggest that heterotrophic activity and oxygen consumption in OLW in the hypoxic region may be regulated by the availability of NH₄⁺, or other reduced N compounds, rather than by the lack of sufficient labile organic carbon.     

Land cover effects on runoff patterns in eastern Piedmont (USA) watersheds

Physiography and land cover determine the hydrologic response of watersheds to climatic events. However, vast differences in climate regimes and variation of landscape attributes among watersheds (including size) have prevented the establishment of general relationships between land cover and runoff patterns across broad scales. This paper addresses these difficulties by using power spectral analysis to characterize area‐normalized runoff patterns and then compare these patterns with landscape features among watersheds within the same physiographic region. We assembled long‐term precipitation and runoff data for 87 watersheds (first to seventh order) within the eastern Piedmont (USA) that contained a wide variety of land cover types, collected environmental data for each watershed, and compared the datasets using a variety of statistical measures. The effect of land cover on runoff patterns was confirmed. Urban‐dominated watersheds were flashier and had less hydrologic memory compared with forest‐dominated watersheds, whereas watersheds with high wetland coverage had greater hydrologic memory. We also detected a 10–15% urban threshold above which urban coverage became the dominant control on runoff patterns. When spectral properties of runoff were compared across stream orders, a threshold after the third order was detected at which watershed processes became dominant over precipitation regime in determining runoff patterns. Finally, we present a matrix that characterizes the hydrologic signatures of rivers based on precipitation versus landscape effects and low‐frequency versus high‐frequency events. The concepts and methods presented can be generally applied to all river systems to characterize multiscale patterns of watershed runoff. Copyright © 2013 John Wiley & Sons, Ltd.     

Storage and interaction of compositionally heterogeneous magmas from the 1986 eruption of Augustine Volcano, Alaska

Compositional heterogeneity (56–64 wt% SiO₂ whole-rock) in samples of tephra and lava from the 1986 eruption of Augustine Volcano, Alaska, raises questions about the physical nature of magma storage and interaction beneath this young and frequently active volcano. To determine conditions of magma storage and evolutionary histories of compositionally distinct magmas, we investigate physical and chemical characteristics of andesitic and dacitic magmas feeding the 1986 eruption. We calculate equilibrium temperatures and oxygen fugacities from Fe-Ti oxide compositions and find a continuous range in temperature from 877 to 947°C and high oxygen fugacities (ΔNNO=1–2) for all magmas. Melt inclusions in pyroxene phenocrysts analyzed by Fourier-transform infrared spectroscopy and electron probe microanalysis are dacitic to rhyolitic and have water contents ranging from <1 to ∼7 wt%. Matrix glass compositions are rhyolitic and remarkably similar (∼75.9–76.6 wt% SiO₂) in all samples. All samples have ∼25% phenocrysts, but lower-silica samples have much higher microlite contents than higher-silica samples. Continuous ranges in temperature and whole-rock composition, as well as linear trends in Harker diagrams and disequilibrium mineral textures, indicate that the 1986 magmas are the product of mixing between dacitic magma and a hotter, more mafic magma. The dacitic endmember is probably residual magma from the previous (1976) eruption of Augustine, and we interpret the mafic endmember to have been intruded from depth. Mixing appears to have continued as magmas ascended towards the vent. We suggest that the physical structure of the magma storage system beneath Augustine contributed to the sustained compositional heterogeneity of this eruption, which is best explained by magma storage and interaction in a vertically extensive system of interconnected dikes rather than a single coherent magma chamber and/or conduit. The typically short repose period (∼10 years) between Augustine's recent eruptive pulses may also inhibit homogenization, as short repose periods and chemically heterogeneous magmas are observed at several volcanoes in the Cook Inlet region of Alaska.     

Light scattering constants for a water cloud

Summary The study of radiative transfer in clouds and fog requires a knowledge of basic radiation constants. For this purpose the volume extinction, scattering, and absorption coefficients, the maximum absorption coefficients for composite spectral lines, and the coefficients used to expand the phase function into a series of Legendre polynomials for analytic representation of the phase function are provided in tabular and graphical format. The analysis for cloud droplets is based upon the rigorous electromagnetic theory. All Mie computations are carried out in an exact manner avoiding any approximations. Absorption line constants as computed here are based upon the investigations ofElsasser withCulbertson [5]³) andWyatt, Stull, andPlass [18]. Tabulations are made on the basis of fifty spectral intervals covering the entire solar and infrared spectra. Polarization effects are disregarded in this study.     

Discussion on the atmospheric radiation tables byElsasser andCulbertson

Summary The radiation tables byElsasser andCulbertson [1]²) are based upon an integrated form of the radiative transfer equation. Unfortunately, a term dealing with the temperature dependency of the transmission function is left out. This leads to an inconsistency of their analysis. It is the aim of this paper to correct and to modifyElsasser's graphical-numerical procedure such as to make his treatment internally consistent.