Hollandite–strontiomelane solid solutions coexisting with kanonaite and braunite in late quartz veins of the Stavelot Massif, Ardennes, Belgium

In a newly found type of quartz vein cross-cutting the famous "viridine"-bearing phyllites at Le Coreux, hollandite, ideally BaMn₈O₁₆, was discovered for the first time at this locality and in Belgium. Because the crystals contain up to 60 mol% of the Sr end member, this is also the second occurrence of strontiomelane. The coexisting "viridine" (= kanonaite) contains the highest amount (88 mol%) of the ideal end member MnAlSiO₅ ever found worldwide. The hollandite-type minerals are intimately intergrown with braunite containing appreciable Ca and Mg. Ba-bearing muscovite, Fe-poor excess-Al clinochlore (not quite trioctahedral), and albite are the remaining accessory minerals in the dominant quartz matrix. Microprobe analyses of all phases show rather extreme element fractionations: nearly all K is located in muscovite and none in the hollandite phase despite the existence of the end member KMn₈O₁₆ (cryptomelane). Similarly, nearly all Na is in albite and not in hollandite (no NaMn₈O₁₆=manjiroite component). Nearly all Mn resides in the two oxide phases and in kanonaite. Mg is strongly fractionated into chlorite. The small amounts of Fe and Ti present are predominantly partitioned into the hollandite phase, which also accommodates most of the Ba and Sr. Indeed, the hollandite phase is stabilized by the latter two elements relative to other Mn oxides. Kanonaite is stabilized by Al. Although no requisite sites are available in its crystal structure, braunite always contains small amounts of Ba and Sr. However, the Sr/(Sr+Ba) ratios in braunite are spurious and unrelated to those of the directly adjoining hollandite phases The conditions of formation of these veins may be well below 300 °C at low pressures (1-2 kbar), in agreement with the experimental results that the maximum Mn contents in kanonaite increase with falling temperatures.     

Computer simulation of crystal structures

It is impossible to calculate from first principles the details of crystal structures. However, it is possible to rely on information which is certain, namely on interatomic distances, and calculate the details of a crystal structure based on these. Individual distances between atoms can be predicted accurately if one considers the coordination numbers of anions and cations, the extended electrostatic valence rule, and the effects of shared edges between different coordination polyhedra. The predicted interatomic distances are used as observations in a distance least squares refinement in which the positional parameters and the cell edges are adjusted until the calculated interatomic distances correspond as closely as possible to the predicted distances. The topology of the simulated structure has to be known or assumed. Appropriate weighting can facilitate proper modelling. Applications include: a) solution of pseudosymmetric structures; b) preliminary refinement of trial structures; c) geometric refinement without X-ray intensities; d) comparison of hypothetical structures with observed polymorphs of the same compositions; e) simulation of temperature dependence of structures; f) simulation of pressure dependence; g) calculation of structures isomorphous to known structures; h) calculation of thermal ellipsoids; i) calculation of local environments deviating from the overall symmetry of a structure; j) testing of hypotheses about the behavior of structures at varying conditions.     

Climate Shifts during the Last Century

Fluctuations of the land surface areas covered by Koeppen climates are analysed for the 1901 to 1995 period using trends and outliers as indicators of climate shift. Only the extreme climate zones of the global Tropics and of the Tundra (with the highly correlated northern hemisphere temperature) realise statistically significant shifts and outliers. There are nosignificant trends and outliers in the fluctuating ocean-atmosphere patterns (Pacific Decadal and North Atlantic Oscillations) and the highly correlated intermediate climate zones (dry, subtropical and boreal) of the surrounding continents.     

Simulating midday all-slope surface temperatures along a climatic-latitudinal transect during cloudless summer conditions

Two physically-models of solar radiation transmission and of a steady-state slope energy budget have been coupled. Using climatic observational inputs, averaged in 10-deg latitude bands, a systematic examination was made of changing surface temperatures and differences between surface and air temperatures as functions of varying slope angles (0 to 90 deg) and orientations (south-, west-, and north-facing). Along a latitudinal transect of the east coast of the Americas (northern hemisphere), two contrasting landscapes were examined: barren and grassy. No simple relationship was discovered among the factors regarding shortwave and longwave radiative absorption, components of the energy budget, and surface temperature trends, yet the response of temperatures on a latitudinal basis was systematic and orderly. Characteristically, a great diversity existed among surface temperatures of different slopes and orientations at any particular latitude. Such diversity was accentuated in the higher latitudes. The findings were assumed general enough to encompass most of the possible contrasts encountered in a real-world north-south transect.Dr. O'Rourke is currently a Visiting Scholar at UCLA from Litton Systems, Inc., Data Systems Division.