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排序方式: 共有290条查询结果,搜索用时 15 毫秒
91.
92.
A preliminary methods comparison for measurement of dissolved organic nitrogen in seawater 总被引:2,自引:0,他引:2
Jonathan H. Sharp Kathrine R. Rinker Karen B. Savidge Jeffrey Abell Jean Yves Benaim Deborah Bronk David J. Burdige Gustave Cauwet Wenhao Chen Marylo D. Doval Dennis Hansell Charles Hopkinson Gerhard Kattner Nancy Kaumeyer Karen J. McGlathery Jeffrey Merriam Nick Morley Klaus Nagel Hiroshi Ogawa Carol Pollard Mireille Pujo-Pay Patrick Raimbault Raymond Sambrotto Sybil Seitzinger Georgina Spyres Frank Tirendi Ted W. Walsh C. S. Wong 《Marine Chemistry》2002,78(4)
Routine determination of dissolved organic nitrogen (DON) is performed in numerous laboratories around the world using one of three families of methods: UV oxidation (UV), persulfate oxidation (PO), or high temperature combustion (HTC). Essentially all routine methods measure total dissolved nitrogen (TDN) and calculate DON by subtracting the dissolved inorganic nitrogen (DIN). While there is currently no strong suggestion that any of these methods is inadequate, there are continuing suspicions of slight inaccuracy by UV methods.This is a report of a broad community methods comparison where 29 sets (7 UV, 13 PO, and 9 HTC) of TDN analyses were performed on five samples with varying TDN and DIN concentrations. Analyses were done in a “blind” procedure with results sent to the first author. With editing out one set of extreme outliers (representing 5 out of 145 ampoules analyzed), the community comparability for analyzing the TDN samples was in the 8–28% range (coefficient of variation representing one standard deviation for the five individual samples by 28 analyses). When DIN concentrations were subtracted uniformly (single DIN value for each sample), the comparability was obviously worse (19–46% cv). This comparison represents a larger and more diverse set of analyses, but the overall comparability is only marginally better than that of the Seattle workshop of a decade ago. Grouping methods, little difference was seen other than inconclusive evidence that the UV methods gave TDN values for several of the samples higher than HTC methods. Since there was much scatter for each of the groups of methods and for all analyses when grouped, it is thought that more uniformity in procedures is probably needed. An important unplanned observation is that variability in DIN analyses (used in determining the final analyte in most UV and PO methods) is essentially as large as the variability in the TDN analyses.This exercise should not be viewed as a qualification exercise for the analysts, but should instead be considered a broad preliminary test of the comparison of the families of methods being used in various laboratories around the world. Based on many independent analyses here, none of the routinely used methods appears to be grossly inaccurate, thus, most routine TDN analyses being reported in the literature are apparently accurate. However, it is not reassuring that the ability of the international community to determine DON in deep oceanic waters continues to be poor. It is suggested that as an outgrowth of this paper, analysts using UV and PO methods experiment and look more carefully at the completeness of DIN conversion to the final analyte and also at the accuracy of their analysis of the final analyte. HTC methods appear to be relatively easy and convenient and have potential for routine adoption. Several of the authors of this paper are currently working together on an interlaboratory comparison on HTC methodology. 相似文献
93.
1936年4月1日广西灵山县平山镇东南罗阳山附近发生M6(3/4)地震,该地震是华南大陆自有地震记载以来发生的最大地震。本研究收集整理了灵山M6(3/4)地震的地质资料、活动断层探测最新成果等,选取适当的研究区域,利用随机振动有限断层模型计算区域内网格点的峰值加速度(PGA)及峰值速度(PGV)等参数,并且加入浅层横波速度结构Vs30对地震动参数的影响,最终得到此次地震的地震动分布并分析了地震动特征。本研究将模拟结果与野外调查烈度数据和地震动衰减关系进行对比,结果显示模拟结果与调查烈度值和衰减关系在整体衰减特征、极震区的分布等方面均符合较好,模拟结果可为该地区未来地震危害性评估提供依据。本研究所使用的方法流程亦可应用于本地区地震烈度速报,为震后应急救援及决策指挥提供帮助。 相似文献
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余震触发机制的Dieterich解析模型被广泛应用于区域地震活动性的定量分析以及依赖时间的概率地震预测模型的建立等方面.基于滑移速率和状态相依赖的摩擦定律和弹簧-滑块模型,从Dieterich断层滑移速率方程出发,给出了静态应力扰动下触发地震的时钟提前或推后的近似解,从而明确地阐明了触发地震的产生机制与断层的演化过程密切相关,并与传统位错模型下库仑应力扰动时间提前或推后量作了比较.采用对数线性拟合方法求得了汶川Mw7.9主震后余震序列持续时间,符合Dieterich理论结果.以汶川余震序列为例,给出了两种不同的应力扰动模式在该余震序列中的应用.结果表明,经典Dieterich扰动解无法给出主震发生后即时余震数量的异常增加,而考虑主震前后剪应力速率变化的Dieterich分段解则可反映出余震发生率及个数随时间的演化特征. 相似文献
97.
The first dinosaur tracksite from Xinjiang, NW China (Middle Jurassic Sanjianfang Formation, Turpan Basin) a preliminary report 总被引:1,自引:0,他引:1
A new dinosaur tracksite was discovered in a steeply inclined sandstone layer of the Middle Jurassic Sanjianfang Formation in the Shanshan area of the Turpan Basin. The site is the first record of dinosaur footprints from Xinjiang Province in northwestern China. More than 150 tridactyl theropod dinosaur footprints are preserved as positive hyporeliefs on the lower bedding plane of a fine-grained sandstone body. Most of the footprints are isolated and appear to be randomly distributed. Some show well defined phalangeal pads, heels and rarely indistinct impressions of the distal part of the metatarsus. Two distinct morphotypes are present: a larger type with relatively broad pads shows similarities to Changpeipus and Megalosauripus, and a slightly smaller, slender and gracile type which is similar to Grallator, Eubrontes and Anchisauripus. In both morphotypes, digit III is the longest with a length between 11.4 and 33.6 cm. A single imprint shows prominent scratches, probably formed during slipping of the track maker. 相似文献
98.
基于指数函数的有界性、函数曲线形状和构造土体动力本构模型的一般原则,把函数Y=e^x在(-∞,0]区间上的图像进行翻转、平移、放缩,从而构造出土体的动力本构模型的骨架曲线。在卸载和反向加载时,采用与骨架曲线相同的函数形式,并以前一次卸载开始点作为起点,以土体的极限应力水平作为渐近线,构造出土体动力本构模型的滞回曲线。在此基础上构造出适用于非对称循环荷载的指数形式土体动力本构模型(UE模型)。并用共振柱实验的结果检验了模型的有效性。UE模型具有四个特点:第一,适用于非对称循环荷载;第二,记忆量小;第三,卸载再加载滞回曲线自动满足Masing准则;第四,模型参数少,物理意义明确,可用常规试验确定。 相似文献
99.
The study presents the results of U-Pb dating of zircons and whole-rock geochemical analyses of syenogranite in Angeer Yinwula area, China, with the aim of determining its formation time, petrogenesis and regional setting. Zircon U-Pb data obtained by LA-ICP-MS indicate that the syenogranite formed in the Early Cretaceous(136.1±0.9 Ma). Geochemically, the rock is characterized by high SiO_2(76.63%--77.58%) and Na_2O+K_2O(8.00%--8.32%), low MgO(0.02%--0.04%) and TFe_2O_3(0.51%--0.84%), and is enriched in LREEs and LILEs, depleted in HREEs and HFSEs. It belongs to high-K calc-alkaline, metaluminous-weakly peraluminous, exhibiting an affinity to I-type granite. All these characteristics implied that the syenogranite in this region derived from crust-mantle mixed source. Overall, the regional geology, geochronology and geochemical features suggest that the formation of the syenogranite was related to the subduction of the Paleo-Pacific Ocean. 相似文献
100.
分别选用两景Radarsat-2和TerraSAR-X数据,应用子带干涉技术获取夏威夷火山国家公园及其附近区域的沉降量,并将其与偏移跟踪技术结果进行对比,证明了子带干涉技术的地表形变监测能力,且分辨率越高、带宽越宽的TerraSAR-X数据得到的监测精度越高。用两景PALSAR数据,应用子带干涉技术获得唐洞煤矿地表方位向位移,与同期GPS监测数据进行对比,进一步验证了子带干涉技术的形变监测能力。 相似文献