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121.
Anthony C. Withers Marc M. Hirschmann 《Contributions to Mineralogy and Petrology》2008,156(5):595-605
Olivine crystals were grown in the presence of a hydrous silicate fluid during multi-anvil experiments at 8 GPa and 1,000–1,600°C.
Experiments were conducted both in a simple system (FeO–MgO–SiO2–H2O) and in a more complex system containing additional elements (CaO–Na2O–Al2O3–Cr2O3–TiO2–FeO–MgO–SiO2–H2O). Silica activity was buffered by the presence of either pyroxene (high a
SiO2) or ferropericlase (low a
SiO2), and was buffered by the presence of Ni + NiO or Fe + FeO, or constrained by the presence of Fe2O3. Raman spectroscopy was used to identify pyroxene polymorphs in the run products. Clinoenstatite was present in the 1,000°C
experiment, and enstatite in experiments at 1,400–1,520°C. The H2O content of olivine was measured using secondary ion mass spectroscopy, and infrared spectroscopy was used to investigate
the nature of hydrous defects. The H2O storage capacity of olivine decreases with increasing temperature at 8 GPa. In contrast to previous experimental results
at ≤2 GPa, no significant effect of varying oxygen fugacity is evident, but H2O storage capacity is enhanced under conditions of low silica activity. No significant growth of low wavenumber (<3,400 cm−1) peaks, generally associated with high at low pressure, was observed in the FTIR spectra of olivine from the high experiments. Our experiments show that previous high pressure H2O storage capacity measurements for olivine synthesized under more oxidizing conditions than the Earth’s mantle are not likely
to be compromised by the of the experiments. However, the considerable effect of temperature on H2O storage capacity in olivine must be taken into account to avoid overestimation of the bulk upper mantle H2O storage capacity. 相似文献
122.
We present the software program THERIA_G, which allows for numerical simulation of garnet growth in a given volume of rock
along any pressure–temperature–time (P–T–t) path. THERIA_G assumes thermodynamic equilibrium between the garnet rim and the rock matrix during growth and accounts for
component fractionation associated with garnet formation as well as for intracrystalline diffusion within garnet. In addition,
THERIA_G keeps track of changes in the equilibrium phase relations, which occur during garnet growth along the specified P–T–t trajectory. This is accomplished by the combination of two major modules: a Gibbs free energy minimization routine is used
to calculate equilibrium phase relations including the volume and composition of successive garnet growth increments as P and T and the effective bulk rock composition change. With the second module intragranular multi-component diffusion is modelled
for spherical garnet geometry. THERIA_G allows to simulate the formation of an entire garnet population, the nucleation and
growth history of which is specified via the garnet crystal size frequency distribution. Garnet growth simulations with THERIA_G
produce compositional profiles for the garnet porphyroblasts of each size class of a population and full information on equilibrium
phase assemblages for any point along the specified P–T–t trajectory. The results of garnet growth simulation can be used to infer the P–T–t path of metamorphism from the chemical zoning of garnet porphyroblasts. With a hypothetical example of garnet growth in a
pelitic rock we demonstrate that it is essential for the interpretation of the chemical zoning of garnet to account for the
combined effects of the thermodynamic conditions of garnet growth, the nucleation history and intracrystalline diffusion.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.
相似文献
F. GaidiesEmail: |
123.
Mauro Lo Cascio Yan Liang Nobumichi Shimizu Paul C. Hess 《Contributions to Mineralogy and Petrology》2008,156(1):87-102
The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing
pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum
capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free,
olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across
the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations
in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and
is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange
between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt
interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is
especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt
partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive
boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume
diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements
in residual minerals reequilibrate with their surrounding melt.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
124.
125.
David M. Hirsch 《Contributions to Mineralogy and Petrology》2008,155(4):401-415
Garnet-bearing schists from the Waterville Formation of south-central Maine provide an opportunity to examine the factors
governing porphyroblast size over a range of metamorphic grade. Three-dimensional sizes and locations for all garnet porphyroblasts
were determined for three samples along the metamorphic field gradient spanning lowest garnet through sillimanite grade, using
high-resolution X-ray computed tomography. Comparison of crystal size distributions to previous data sets obtained by stereological
methods for the same samples reveals significant differences in mode, mean, and shape of the distributions. Quantitative textural
analysis shows that the garnets in each rock crystallized in a diffusion-controlled nucleation and growth regime. In contrast
to the typical observation of a correlation between porphyroblast size and position along a metamorphic field gradient, porphyroblast
size of the lowest-grade specimen is intermediate between the high- and middle-grade specimens’ sizes. Mean porphyroblast
size does not correlate with peak temperatures from garnet-biotite Fe-Mg exchange thermometry, nor is post-crystallization
annealing (Ostwald Ripening) required to produce the observed textures, as was previously proposed for these rocks. Robust
pseudosection calculations fail to reproduce the observed garnet core compositions for two specimens, suggesting that these
calc-pelites experienced metasomatism. For each of these two specimens, Monte Carlo calculations suggest potential pre-metasomatism
bulk compositions that replicate garnet core compositions. Pseudosection analyses allow the estimation of the critical temperatures
for garnet growth: ∼481, ∼477, and ∼485°C for the lowest-garnet-zone, middle-garnet-zone, and sillimanite-zone specimens,
respectively. Porphyroblast size appears to be determined in this case by a combination of the heating rate during garnet
crystallization, the critical temperature for the garnet-forming reaction and the kinetics of nucleation. Numerical simulations
of thermally accelerated, diffusion-controlled nucleation, and growth for the three samples closely match measured crystal
size distributions. These observations and simulations suggest that previous hypotheses linking the garnet size primarily
to the temperature at the onset of porphyroblast nucleation can only partially explain the observed textures. Also important
in determining porphyroblast size are the heating rate and the distribution of favorable nucleation sites. 相似文献
126.
Yan Liang 《Geochimica et cosmochimica acta》2008,72(15):3804-3821
Several lines of evidence suggest that the melt generation and segregation regions of the mantle are heterogeneous, consisting of chemically and lithologically distinct domains of variable size and dimension. Partial melting of such heterogeneous mantle source regions gives rise to a diverse range of basaltic magmas. In order to better assess the role of source heterogeneity during mantle melting, we have undertaken a theoretical study of trace element distribution and fractionation during concurrent melting and melt migration in an upwelling, chemically heterogeneous, two-porosity double lithology melting column. Analytical solutions for the abundance of a trace element in the matrix and channel were obtained under the assumptions that the porosity, melt and solid velocities, and solid-melt partition coefficients are constant and uniform. For simplicity, we neglected diffusion and dispersion in the melt. Chemical source heterogeneities of arbitrary size and shape were integrated into the simple melting models by allowing trace element abundance in the source region to vary as a function of time and space. Concurrent melting and melt migration in an upwelling heterogeneous mantle may be approximated as a quasi-steady state problem in which time-dependent concentration patterns produced by melting of heterogeneous source regions are superimposed on a reference steady-state concentration distribution established by melting of the ambient or background mantle. Chromatographic fractionation is especially important for the matrix melt and solid when chemical heterogeneities are involved during melting and melt migration in the mantle, giving rise to significant phase-shift between two incompatible trace elements in the matrix melt and scattered correlations among incompatible trace elements in residual peridotites. Mixing is the chief mass transfer process in the dunite channel where the chromatographic effect is negligible for most of the incompatible trace elements. The lack of chromatographic fractionation among incompatible trace elements and isotopic ratios in MORB suggests either most MORB are channel melts or mixing in magma conduit and chamber is very efficient such that the phase-shift is averaged out during magma transport and storage processes. Advection brings melt produced by smaller-degree of melting in the deeper part of the melting column to the overlying melting region, increasing the incompatible trace element abundance in the matrix and the channel. This advection-induced self-enrichment is especially important when heterogeneous sources are involved and may account for some of the enriched incompatible trace element patterns observed in residual peridotite that were previously interpreted to be a result of mantle metasomatism. Systematic studies of high-resolution spatially correlated mantle samples may help to constrain the melting history and the size and nature of chemical heterogeneities in the mantle. 相似文献
127.
Kathleen A. Radloff Anya R. Manning Brian Mailloux Yan Zheng M. Moshiur Rahman M. Rezaul Huq Kazi M. Ahmed Alexander van Geen 《Applied Geochemistry》2008
Microbial Fe reduction is widely believed to be the primary mechanism of As release from aquifer sands in Bangladesh, but alternative explanations have been proposed. Long-term incubation studies using natural aquifer material are one way to address such divergent views. This study addresses two issues related to this approach: (1) the need for suitable abiotic controls and (2) the spatial variability of the composition of aquifer sands. Four sterilization techniques were examined using orange-colored Pleistocene sediment from Bangladesh and artificial groundwater over 8 months. Acetate (10 mM) was added to sacrificial vials before sterilization using either (1) 25 kGy of gamma irradiation, (2) three 1-h autoclave cycles, (3) a single addition of an antibiotic mixture at 1× or (4) 10× the typical dose, and (5) a 10 mM addition of azide. The effectiveness of sterilization was evaluated using two indicators of microbial Fe reduction, changes in diffuse spectral reflectance and leachable Fe(II)/Fe ratios, as well as changes in P-extractable As concentrations in the solid phase. A low dose of antibiotics was ineffective after 70 days, whereas autoclaving significantly altered groundwater composition. Gamma irradiation, a high dose of antibiotics, and azide were effective for the duration of the experiment. 相似文献
128.
Quantitative sinkhole hazard assessments in karst areas allow calculation of the potential sinkhole risk and the performance
of cost-benefit analyses. These estimations are of practical interest for planning, engineering, and insurance purposes. The
sinkhole hazard assessments should include two components: the probability of occurrence of sinkholes (sinkholes/km2 year) and the severity of the sinkholes, which mainly refers to the subsidence mechanisms (progressive passive bending or
catastrophic collapse) and the size of the sinkholes at the time of formation; a critical engineering design parameter. This
requires the compilation of an exhaustive database on recent sinkholes, including information on the: (1) location, (2) chronology
(precise date or age range), (3) size, and (4) subsidence mechanisms and rate. This work presents a hazard assessment from
an alluvial evaporite karst area (0.81 km2) located in the periphery of the city of Zaragoza (Ebro River valley, NE Spain). Five sinkholes and four locations with features
attributable to karstic subsidence where identified in an initial investigation phase providing a preliminary probability
of occurrence of 0.14 sinkholes/km2 year (11.34% in annual probability). A trenching program conducted in a subsequent investigation phase allowed us to rule
out the four probable sinkholes, reducing the probability of occurrence to 0.079 sinkholes/km2 year (6.4% in annual probability). The information on the severity indicates that collapse sinkholes 10–15 m in diameter
may occur in the area. A detailed study of the deposits and deformational structures exposed by trenching in one of the sinkholes
allowed us to infer a modern collapse sinkhole approximately 12 m in diameter and with a vertical throw of 8 m. This collapse
structure is superimposed on a subsidence sinkhole around 80 m across that records at least 1.7 m of synsedimentary subsidence.
Trenching, in combination with dating techniques, is proposed as a useful methodology to elucidate the origin of depressions
with uncertain diagnosis and to gather practical information with predictive utility about particular sinkholes in alluvial
karst settings: precise location, subsidence mechanisms and magnitude, and timing and rate of the subsidence episodes. 相似文献
129.
Gregory P. Marchildon Suren Kulshreshtha Elaine Wheaton Dave Sauchyn 《Natural Hazards》2008,45(3):391-411
Agriculture in the southern Great Plains of Canada has been particularly vulnerable to prolonged episodes of drought. Using
climate data and a precipitation minus potential evapotranspiration index, the extent of the region’s exposure to drought
is examined. Between 1914 and 1917, the Dry Belt was particularly vulnerable to drought, whereas after 1928, a much larger
region known as the Palliser Triangle covering most of southern Alberta and Saskatchewan was much more exposed to drought.
These droughts provoked major institutional adaptation, in particular the establishment of the Special Areas Board by the
Government of Alberta, and the creation of the Prairie Farm Rehabilitation Administration by the Government of Canada. Both
organizations have proved to be relatively permanent public adaptations to the natural hazard of drought in the region. Moreover,
these earlier experiences with prolonged drought as well as institution-building may be of value in helping the residents
of the Palliser Triangle adapt to predicted climate changes in the future as well as anticipate some of the barriers to effective
institutional adaptation. 相似文献
130.
Tidal inundation mapping under enhanced land subsidence in Semarang,Central Java Indonesia 总被引:3,自引:0,他引:3
Tidal inundation by high tide under enhanced land subsidence is a damaging phenomenon and a major threat to the Semarang urban
area in Indonesia. It impacts on economic activities, as well as the cost of an emergency program and causes interruption
of pubic services, danger of infectious diseases and injury to human lives. This study examines a spatial analysis tool on
the GIS-raster system for the tidal inundation mapping based on the subsidence-benchmark data and modified detail digital
elevation model. Neighborhood operation and iteration model as a spatial analysis tool have been applied in order to calculate
the encroachment of the tidal inundation on the coastal area. The resulting map shows that the tidal flood spreads to the
lowland area and causes the inundation of coastal settlement, infrastructure, as well as productive agricultural land, i.e.,
the fish-pond area. The monitoring of the vulnerable area due to the tidal inundation under the scenario of extended land
subsidence plays an important role in long-term coastal zone management in Semarang. 相似文献