A numerical study of mechanical behavior of a cement paste under mechanical loading and chemical leaching

Based on relevant experimental data of a petroleum cement paste under mechanical loading and chemical leaching, an elastic‐plastic model is first proposed by taking into account plastic shearing and pore collapse. The degradation of mechanical properties induced by the chemical leaching is characterized by a chemical damage variable which is defined as the increase of porosity. Both elastic and plastic properties of the cement paste are affected by the chemical damage. The proposed model is calibrated from and applied to describe mechanical responses in triaxial compression tests respectively on sound and fully leached samples. In the second part, a phenomenological chemical model is defined to establish the relationship between porosity change and calcium dissolution process. The dissolution kinetics is governed by a diffusion law taking into account the variation of diffusion coefficient with calcium concentration. The chemical model is coupled with the mechanical model, and both are applied to describe mechanical response of cement paste samples subjected to progressive chemical leaching and compressive stresses. Comparisons between experimental data and numerical results are presented.     

Preservation of Re‐Os isotope signatures in pyrite throughout low‐T,high‐P eclogite facies metamorphism

Pyrite in LT–HP eclogites from the western Tianshan orogenic belt yields a Re‐Os age of 378.1 ± 8.9 Ma, which is 30–70 Ma older than ages previously obtained for the same rocks using the Rb–Sr, Sm–Nd, Ar–Ar, U–Pb, and Lu–Hf isotope systems. The Tianshan LT–HP eclogite experienced temperatures of up to ~570 °C combined with pressures of up to 2.1 GPa during metamorphism. These conditions are below the transition of pyrite to pyrrhotite, which defines both pyrite stability and possibly its closure temperature for Re‐Os. Pyrite can preserve Re‐Os signatures through eclogite facies peak metamorphic conditions, and thus allow determination of the formation age of pyrite in the protolith.     

Energy partitioning over a semi‐arid shrubland in northern China

During the last decade, the widely distributed shrublands in northern China have shown significant signs of recovery from desertification, the result of widespread conservation practices. However, to support the current efforts in conservation, more knowledge is needed on surface energy partitioning and its biophysical controls. Using eddy‐covariance measurements made over a semi‐arid shrubland in northwest China in 2012, we examined how surface energy‐balance components vary on diurnal and seasonal scales, and how biophysical factors control bulk surface parameters and energy exchange. Sensible heat flux (H) exceeded latent heat flux (λE) during most of the year, resulting in an annual Bowen ratio (β, i.e. H/λE) of 2.0. λE exceeded H only in mid‐summer when frequent rainfall co‐occurred with the seasonal peak in leaf area index (LAI). Evapotranspiration reached a daily maximum of 3.3 mm day^?1, and summed to 283 mm yr^?1. The evaporative fraction (EF, i.e. λE/R_n), Priestley–Taylor coefficient (α), surface conductance (g_s) and decoupling coefficient (Ω) were all positively correlated with soil water content (SWC) and LAI. The direct enhancement of λE by high vapour pressure deficit (VPD) was buffered by a concurrent suppression of g_s. The g_s played a direct role in controlling EF and α by mediating the effects of LAI, SWC and VPD. Our results highlight the importance of adaptive plant responses to water scarcity in regulating ecosystem energy partitioning, and suggest an important role for revegetation in the reversal of desertification in semi‐arid areas. Copyright © 2015 John Wiley & Sons, Ltd.     

Influence of heterogeneity on unsaturated hydraulic properties: (1) local heterogeneity and scale effect

Spatial heterogeneity is ubiquitous in nature, which may significantly affect the soil hydraulic property curves. The models of a closed‐form functional relationship of soil hydraulic property curves (e.g. VG model or exponential model) are valid at point or local scale based on a point‐scale hydrological process, but how do scale effects of heterogeneity have an influence on the parameters of these models when the models are used in a larger scale process? This paper uses a two‐dimensional variably saturated flow and solute transport finite element model (VSAFT2) to simulate variations of pressure and moisture content in the soil flume under a constant head boundary condition. By changing different numerical simulation block sizes, a quantitative evaluation of parameter variations in the VG model, resulting from the scale effects, is presented. Results show that the parameters of soil hydraulic properties are independent of scale in homogeneous media. Parameters of α and n in homogeneous media, which are estimated by using the unsaturated hydraulic conductivity curve (UHC) or the soil water retention curve (WRC), are identical. Variations of local heterogeneities strongly affect the soil hydraulic properties, and the scale affects the results of the parameter estimations when numerical experiments are conducted. Furthermore, the discrepancy of each curve becomes considerable when moisture content becomes closer to a dry situation. Parameters estimated by UHC are totally different from the ones estimated by WRC. Copyright © 2012 John Wiley & Sons, Ltd.     

Mesoscale numerical simulation study of warm fog dissipation by salt particles seeding

Based on the dynamic framework of WRF and Morrison 2-moment explicit cloud scheme, a salt-seeding scheme was developed and used to simulate the dissipation of a warm fog event during 6–7 November 2009 in the Beijing and Tianjin area. The seeding effect and its physical mechanism were studied. The results indicate that when seeding fog with salt particles sized 80 μm and at a quantity of 6 gm~(-2) at the fog top, the seeding effect near the ground surface layer is negative in the beginning period, and then a positive seeding effect begins to appear at 18 min, with the best effect appearing at 21 min after seeding operation. The positive effect can last about 35 min. The microphysical mechanism of the warm fog dissipation is because of the evaporation due to the water vapor condensation on the salt particles and coalescence with salt particles.The process of fog water coalescence with salt particles contributed mostly to this warm fog dissipation. Furthermore, two series of sensitivity experiments were performed to study the seeding effect under different seeding amounts and salt particles sizes. The results show that seeding fog with salt particles sized of 80 μm can have the best seeding effect, and the seeding effect is negative when the salt particle size is less than 10 μm. For salt particles sized 80 μm, the best seeding effect, with corresponding visibility of 380 m, can be achieved when the seeding amount is 30 g m~(-2).     

Ensemble simulation of land evapotranspiration in China based on a multi-forcing and multi-model approach

In order to reduce the uncertainty of offline land surface model(LSM) simulations of land evapotranspiration(ET), we used ensemble simulations based on three meteorological forcing datasets [Princeton, ITPCAS(Institute of Tibetan Plateau Research, Chinese Academy of Sciences), Qian] and four LSMs(BATS, VIC, CLM3.0 and CLM3.5), to explore the trends and spatiotemporal characteristics of ET, as well as the spatiotemporal pattern of ET in response to climate factors over mainland China during 1982–2007. The results showed that various simulations of each member and their arithmetic mean(Ens Mean) could capture the spatial distribution and seasonal pattern of ET sufficiently well, where they exhibited more significant spatial and seasonal variation in the ET compared with observation-based ET estimates(Obs MTE). For the mean annual ET, we found that the BATS forced by Princeton forcing overestimated the annual mean ET compared with Obs MTE for most of the basins in China, whereas the VIC forced by Princeton forcing showed underestimations. By contrast, the Ens Mean was closer to Obs MTE, although the results were underestimated over Southeast China. Furthermore, both the Obs MTE and Ens Mean exhibited a significant increasing trend during 1982–98; whereas after 1998, when the last big EI Ni ?no event occurred, the Ens Mean tended to decrease significantly between 1999 and 2007, although the change was not significant for Obs MTE. Changes in air temperature and shortwave radiation played key roles in the long-term variation in ET over the humid area of China, but precipitation mainly controlled the long-term variation in ET in arid and semi-arid areas of China.