超声提取-固相萃取小柱净化-气相色谱法测定土壤中14种有机氯农药

对土壤中14种有机氯农药的超声提取技术和磺化、固相萃取小柱两种净化方法进行系统研究。结果表明,超声提取节省提取时间,提高分析效率;磺化法和固相萃取小柱法都有净化作用,但磺化法使样品中的艾氏剂、狄氏剂和异狄氏剂全部损失;固相萃取小柱净化当丙酮-正己烷淋洗液体积比为1∶9、淋洗液收集8 mL时回收率>90%,干扰最小。方法检出限为0.63~2.59μg/kg,精密度(RSD,n=7)为1.17%~14.66%,基体加标平均回收率为82.78%~106.94%。方法用于生态地球化学调查评价批量土壤样品的实际分析,检测结果满足评价工作需要。     

In‐situ analysis of trace elements and Sr–Pb isotopes of K‐feldspars from Tongshankou Cu–Mo deposit,SE Hubei Province,China: Insights into early potassic alteration of the porphyry mineralization system

In the Tongshankou porphyry deposit (SE Hubei Province, South China), three types of K‐feldspars are recognized: (I) the phenocryst type in the porphyry that crystalized during the magmatic stage, (II) the megacryst type and (III) the vein type in the altered porphyry and orebody that was produced by hydrothermal fluids. A detailed in‐situ analysis of trace elements and Sr–Pb isotopes was carried out on K‐feldspars in an attempt to unravel their formation processes and to trace the element sources during potassic alteration. The Type III K‐feldspars show lower Sr contents and Sr‐isotope ratios but higher Pb contents and Pb‐isotope ratios than the Type I and II K‐feldspars, possibly reflecting a contribution from the country carbonate rocks with less radiogenic Sr but more radiogenic Pb sources, and indicate that the ore‐forming fluids and materials may have been partially derived from external sources such as the host sedimentary rocks during the early potassic alteration stage.     

Integrative taxonomic description of Plakina kanaky,a new polychromatic sponge species from New Caledonia (Porifera: Homoscleromorpha)

Four similar sponges of different colors, all unknown to science, were collected in submarine caves of New Caledonia. We aimed at determining whether the four chromotypes represented different species or phenotypic variations of a unique new species. We used an integrative taxonomic approach combining morphologic, molecular and metabolomic analyses. The main traits that define these specimens are a skeleton made of monolophose, trilophose and tetralophose calthrops only, high chemical diversity and a high abundance and diversity of prokaryotic symbionts. The symbiotic community includes two unique prokaryote morphotypes, which are described for the first time in Homoscleromorpha, and appeared to be vertically transmitted. Although several features slightly differ among chromotypes, the most parsimonious conclusion was to propose a single new species Plakina kanaky sp. nov. Our phylogenetic analysis indicated the paraphyly of the Plakina genus, with P. kanaky sp. nov. belonging to a clade that includes Plakina jani and Plakina trilopha. The present work demonstrates that integrative taxonomy should be used in order to revise the entire Plakinidae family and especially the non‐monophyletic genus Plakina.     

New Reference Materials and Assessment of Matrix Effects for SIMS Measurements of Oxygen Isotopes in Garnet

Accurate ion microprobe analysis of oxygen isotope ratios in garnet requires appropriate reference materials to correct for instrumental mass fractionation that partly depends on the garnet chemistry (matrix effect). The matrix effect correlated with grossular, spessartine and andradite components was characterised for the Cameca IMS 1280HR at the SwissSIMS laboratory based on sixteen reference garnet samples. The correlations fit a second‐degree polynomial with maximum bias of ca. 4‰, 2‰ and 8‰, respectively. While the grossular composition range 0–25% is adequately covered by available reference materials, there is a paucity of them for intermediate compositions. We characterise three new garnet reference materials GRS2, GRS‐JH2 and CAP02 with a grossular content of 88.3 ± 1.2% (2s), 83.3 ± 0.8% and 32.5 ± 3.0%, respectively. Their micro scale homogeneity in oxygen isotope composition was evaluated by multiple SIMS sessions. The reference δ¹⁸O value was determined by CO₂ laser fluorination (δ¹⁸O_LF). GRS2 has δ¹⁸O_LF = 8.01 ± 0.10‰ (2s) and repeatability within each SIMS session of 0.30–0.60‰ (2s), GRS‐JH2 has δ¹⁸O_LF = 18.70 ± 0.08‰ and repeatability of 0.24–0.42‰ and CAP02 has δ¹⁸O_LF = 4.64 ± 0.16‰ and repeatability of 0.40–0.46‰.     

震源系统不稳定度指标和强震短临预报

在探讨震源系统不稳定产生的物理基础前提下，应用调制模式提出了利用小震日频次起伏加剧与外因的相关性进行强震的短临时间预报的设想，具体提出了调制小震频次起伏加剧的两个判别震源系统不稳定度的指标λ＿１和λ＿２。前者为单因子调制指标，后者为多因子调制或多因子调制强化指标。关于大震的地点预报，应用立交模式短临阶段出现调制小震通过未来大震的共轭小震活动条带进行预报。     

新疆东天山红云滩地区构造-热演化探讨:来自Ar-Ar和(U-Th)/He热年代学的约束

红云滩岩体位于东天山觉罗塔格西部,对其进行热演化历史研究对于揭示觉罗塔格地区乃至整个东天山地区的构造-热演化历史具有重要意义。本文对红云滩岩体进行黑云母Ar-Ar、锆石(U-Th)/He和磷灰石(U-Th)/He测年,并结合前人的锆石U-Pb测年结果,精细刻画出该岩体自形成以后经历的热演化过程,并据此识别出东天山红云滩地区发生过多期快速抬升冷却事件。黑云母阶段升温Ar-Ar法同位素定年得到的坪年龄为316.9±1.8Ma,单颗粒锆石和磷灰石(U-Th)/He同位素定年得到的平均年龄分别为213.7±9.6Ma和65.5±1.3Ma。热年代学数据及模拟结果表明东天山红云滩地区自晚古生代以来经历了3个快速冷却阶段,分别为:晚石炭世至早二叠世(ca.330~296Ma)、晚三叠世(222~220Ma)、晚白垩世(91~77Ma)。其中,晚石炭世至早二叠世的快速冷却作用是岩体侵位后与围岩热传导冷却及伴随天山造山隆升冷却综合作用的结果,晚三叠世和晚白垩世的两期快速冷却事件分别与羌塘-欧亚板块、Kohistan-Dras岛弧-拉萨地块碰撞的远程效应造成的东天山地区隆升作用有关。新生代以来,红云滩岩体所在的阿奇山-雅满苏地区构造活动相对较弱,未发生较为明显的隆升作用,与天山西段新生代的构造活动有着明显的差异。     

无线电波透视法探测岩溶洞穴的地质效果

应用无线电波透视法,对我国十多个大中型水利水电坝址的深部岩溶洞穴发育情况进行了探测和研究,先后圈定了许多岩溶洞穴异常和异常地段,为地质上选择坝线和工程上进行防渗处理提供了资料。其中有乌江渡水电站等坝址的透视成果已得到了验证,取得了较好的地质效果。文中着重介绍了一些应用实例。实践证明:透视法较之地面电法有不可比拟的一些优点,它是目前探测深部岩溶洞穴的最好的物探方法.在多年的实践中,也发现了该法在应用中存在着几个主要问题,影响了它在岩溶洞穴探测中的地质效果。     

Mobility Sequence of Chemical Elements During Loess Weathering—Pedogenesis,Weinan,Shaanxi Province,China

The distribution of chemical elements in the Weinan loess section shows that: (1) carbonate is the critical constituent affecting loess chemistry. The leaching of carbonates may cause “apparent” enrichment of some other constituents. (2) CaCO₃, SiO₂, FeO, MgO, K₂O and Na₂O are mobile while Al₂O₃, Fe₂O₃ and TiO₂ are inert components. The mobility sequence may follow the order of CaCO₃>FeO>MgO>Na₂O>K₂O>SiO₂>Al₂O₃>TiO₂>Fe₂O₃. (3) No obvious migration is noticed of iron, except changes in valence and forms, during the pedogenic process. Little iron has been supplied to paleosol from precipitation. (4) Carbonates and, to a lesser extent, iron are most sensitive to, and can be therefore used as good indicators of, environmental changes. This research project was financially supported by the National Natural Science Foundation of China (Grant No. 49672137).     

Discovery of the early Jurassic Gajia mélange in the Bangong–Nujiang suture zone: Southward subduction of the Bangong–Nujiang Ocean?

International Journal of Earth Sciences - Mélange records a series of geological processes associated with oceanic subduction and continental collision. This paper reports for the first time...     

滇东南富宁地区基性侵入岩与峨眉山地幔柱存在成因关系吗?——来自1∶5万洞波幅和皈朝幅地质填图的证据

在滇东南富宁地区,出露一系列以辉绿岩为主、含少量辉长辉绿岩和辉绿玢岩的基性侵入岩。根据地球化学、同位素地球化学以及锆石U-Pb年代学等分析结果,前人将这些基性侵入岩视作峨眉山大火成岩省的组成部分,源自峨眉山地幔柱。国内外研究的共识认为,峨眉山地幔柱活动发生于263~252Ma之间,持续时间极短。在开展1∶2.5万大比例尺地质调查与填图(洞波幅和皈朝幅1∶5万地质调查手图)过程中,我们发现,这些基性侵入岩不仅侵入古生代地层,还侵入了富宁县皈朝一带的晚二叠世-中三叠世岛弧玄武安山岩(255~241Ma)以及早-中三叠世地层。这些地质事实表明,富宁地区基性侵入岩的形成时代至少晚于中三叠世Anisian期或更晚,与峨眉山地幔柱活动时代存在很大的时差,岩石类型与组合上也与峨眉山大火成岩省的有很大差异。根据我们填图过程中获得的基本地质事实分析,滇东南富宁地区的基性侵入岩是华南地块与北越地块间的古特提斯分支洋盆闭合、两个地块碰撞造山(即印支造山)后的岩浆活动产物,与峨眉山地幔柱没有成因关系。