Insights into the formation of rock varnish in prevailing dusty regions

The characteristics of rock varnish from the Campo de Piedra Pomez (CPP, Andes Argentina) provides new insights into the development of rock varnish under severe dusty conditions. The CPP varnish has been analysed using SEM‐EDAX and Raman techniques. The rock coating is tens of microns in thickness and under the microscope shows a micro to cryptocrystalline appearance and a general granular texture. Silica (quartz, cristobalite and amorphous silica) is the main phase forming these coverings followed by Al, K and Na compounds. Minor Fe oxides and Mn oxides are the source for the orange (Fe) and brown (Fe and Mn) hues of the coating. The results obtained for the CPP coating show that desert varnish developed under dusty circumstances does not have the appearance of typical rock varnish. Textural characteristics include high crystallinity and granular arrangement of the components. Moreover the absence of typical microlaminations is related to the presence of aeolian mineral grains which inhibit their development. The main mechanism of formation of rock varnish under such environmental circumstances is the direct incorporation of aeolian mineral grains into the varnish. However, other physicochemical processes are also required to explain the formation of varnish components such as amorphous silica or iron oxides phases. Although the development of the desert varnish may act as a protector of the underlying pyroclastic rock, the extreme and persistent windy conditions in the CPP field are high enough to weather and erode not only the rock coating but also the original ignimbrite. As other warm desert sites on Earth, the CPP area can also be considered as possible terrestrial analogue to Mars. Some environmental attributes might be similar to those expected on the Martian surface and thus, textural similarities between the CPP varnish and the rock varnish‐like coating of Mars are likely. Copyright © 2014 John Wiley & Sons, Ltd.     

Organohalogen contaminants and trace metals in North-East Atlantic porbeagle shark (Lamna nasus)

The North-East Atlantic porbeagle (Lamna nasus) population has declined dramatically over the last few decades and is currently classified as ‘Critically Endangered’. As long-lived, apex predators, they may be vulnerable to bioaccumulation of contaminants. In this study organohalogen compounds and trace elements were analysed in 12 specimens caught as incidental bycatch in commercial gillnet fisheries in the Celtic Sea in 2011. Levels of organohalogen contaminants were low or undetectable (summed CB and BDE concentrations 0.04–0.85 mg kg⁻¹ wet weight). A notably high Cd concentration (7.2 mg kg⁻¹ wet weight) was observed in one mature male, whereas the range observed in the other samples was much lower (0.04–0.26 mg kg⁻¹ wet weight). Hg and Pb concentrations were detected only in single animals, at 0.34 and 0.08 mg kg⁻¹ wet weight, respectively. These contaminant levels were low in comparison to other published studies for shark species.     

Methods for estimating the velocities of the Brazil Current in the pre-salt reservoir area off southeast Brazil (23∘ S–26∘ S)

The Brazil Current (BC) is likely the least observed and investigated subtropical western boundary current in the world. This study proposes a simple and systematic methodology to estimate quasi-synoptic cross-sectional speeds of the BC within the Santos Basin (23^° S–26^° S) based on the dynamic method using several combinations of data: Conductivity, temperature, and depth (CTD), temperature profiles, CTD and vessel-mounted Acoustic Doppler Current Profiler (VMADCP), and temperature profiles and VMADCP. All of the geostrophic estimates agree well with lowered Acoustic Doppler Current Profiler (LADCP) velocity observations and yield volume transports of -5.56 ±1.31 and 2.50 ±1.01 Sv for the BC and the Intermediate Western Boundary Current (IWBC), respectively. The LADCP data revealed that the BC flows southwestward and is ～100 km wide, 500 m deep, and has a volume transport of approximately -5.75 ±1.53 Sv and a maximum speed of 0.59 m s^?1. Underneath the BC, the IWBC flows northeastward and has a vertical extent of approximately 1,300 m, a width of ～60 km, a maximum velocity of ～0.22 m s?¹, and a volume transport of 4.11 ± 2.01 Sv. Our analysis indicates that in the absence of the observed velocities, the isopycnal (σ ₀) of 26.82 kg m^?3 (～500 dbar) is an adequate level of no motion for use in geostrophic calculations. Additionally, a simple linear relationship between the temperature and the specific volume anomaly can be used for a reliable first estimate of the BC-IWBC system in temperature-only transects.     

Investigating the molecular systematic relationships amongst selected Plesionika (Decapoda: Pandalidae) from the Northeast Atlantic and Mediterranean Sea

Despite the high number of species and ecological diversity of pandalid shrimps, there has been no previous attempt to resolve evolutionary relationships of several genera using molecular tools. Although mitochondrial DNA cytochrome oxidase I (COI) is widely used in barcoding studies to delimit species boundaries, additional insights into phylogenetic affinities can be obtained, especially when used in combination with data from additional genes. The knowledge of molecular diversity is essential to understand phylogenetic relationships and will help systematic clarifications. Based on partial fragments of the 16S and COI genes, we have focused specifically on addressing the systematic relationships of the economically and ecologically important shrimp genus Plesionika within a framework of five genera from within the Pandalidae. Our results showed that species within Plesionika are substantially divergent when compared with other genera, exhibiting the highest average nucleotide divergence, with 0.1123 and 0.0846 in COI and 16S genes, respectively. In addition, sequence divergence was found to vary greatly within the genus Plesionika (COI/16S): 0.0247/0.0016 between Plesionika antigai and Plesionika heterocarpus and 0.1616/0.098 between Plesionika heterocarpus and Plesionika edwardsii. We did not find amino acid sequence divergence between P. heterocarpus and P. antigai compared with P. heterocarpus and P. edwardsii (8.10%, K2P distance). Three species of Plesionika (P. antigai, P. heterocarpus and Plesionika scopifera) appear well separated from other Plesionika species in both maximum likelihood and Bayesian analyses. The present study confirms the utility of COI over 16S as a genetic marker to resolve relationships between different species of Plesionika from the Northeast Atlantic and Mediterranean Sea, in addition to species delimitation. The findings highlight the need to further review paraphyly within Plesionika in an attempt to recognize a concordance in the evolutionary history of Plesionika with major ecological and geological events.     

Magnetic susceptibility and its relationship with paleoenvironments, diagenesis and remagnetization: examples from the Devonian carbonates of Belgium

To better understand the origin of the initial magnetic susceptibility (??_in) signal in carbonate sequences, a rock magnetic investigation that includes analysis of acquisition curves of the isothermal remanent magnetization (IRM) and hysteresis parameters, was undertaken on Devonian carbonates from the Villers and Tailfer sections, Belgium. Both sections are divided into a lower unit, dominated by biostromal and external ramp facies (biostromal unit) and an upper unit, only consisting of lagoonal facies (lagoonal unit). The variations in ??_in signal are mainly driven by magnetite variation, mostly pseudo-single-domain (PSD) magnetite. Clay minerals, pyrite, hematite and obviously calcite and dolomite are also present but their contribution to the ??_in pattern is not significant. There is a correlation between detrital proxies (Zr, Rb, Al₂O₃, TiO₂) and ??_in for the Tailfer biostromal unit and the entire Villers section. The pervasive presence of fine-grained magnetite is interpreted as related to remagnetization. In absence of external fluids, the iron released during the smectite to illite transition remains in situ. In those situations ??_in may reflect an inherited primary synsedimentary signal. In the lagoonal unit of the Tailfer section, remagnetization appears to have obscured the original detrital information prompting the need for an evaluation of the composition of the susceptibility signal for individual case studies.     

Experimental testing, numerical modelling and seismic strengthening of traditional stone masonry: comprehensive study of a real Azorian pier

Stone masonry is one of the oldest building techniques used worldwide and it is known to exhibit poor behaviour under seismic excitations. In this context, this work aims at assessing the in-plane behaviour of an existing double-leaf stone masonry pier by experimental testing. Additionally, a detailed 3D finite element numerical analysis based on micro-modelling of the original pier is presented (fully describing the geometry and division of each individual elements, namely infill, blocks and joints) aiming at simulating the experimental test results. This numerical strategy can be seen as an alternative way of analysing this type of constructions, particularly useful for laboratory studies, and suitable for the calibration of simplified numerical models. As part of a wider research activity, this work is further complemented with the presentation of an effective retrofit/strengthening technique (reinforced connected plaster) to achieve a significant improvement of its in-plane cyclic response which is experimentally verified in the results presented herein.     

Performance of masonry enclosure walls: lessons learned from recent earthquakes

This paper discusses the issue of performance requirements and construction criteria for masonry enclosure and infill walls.Vertical building enclosures in European countries are very often constituted by non-load-bearing masonry walls, using horizontally perforated clay bricks.These walls are generally supported and confined by a reinforced concrete frame structure of columns and beams/slabs.Since these walls are commonly considered to be nonstructural elements and their influence on the structural response is ignored,their consideration in the design of structures as well as their connection to the adjacent structural elements is frequently negligent or insufficiently detailed.As a consequence,nonstructural elements,as for wall enclosures,are relatively sensitive to drift and acceleration demands when buildings are subjected to seismic actions. Many international standards and technical documents stress the need for design acceptability criteria for nonstructural elements,however they do not specifically indicate how to prevent collapse and severe cracking,and how to enhance the overall stability in the case of moderate to high seismic loading.Furthermore,a review of appropriate measures to improve enclosure wall performance and both in-plane and out-of-plane integrity under seismic actions is addressed.     

Low Visibility Formation and Forecasting on the Northern Coast of Brazil

Visibility analysis and forecast at the Maceio International Airport in the Brazilian Northeast (NEB) was the principal goal of this investigation. Surface meteorological data of the Maceio International Airport were used for low visibility frequency study. Low visibility in NEB was provoked more frequently by light fog (LF) formation (1,098 or 92 h month^?1 on average). Haze and fog were very rare (81 h and one event per year, respectively on average). Light fog with a visibility less than 2 km usually was detected together with rain or drizzle. Low visibility was observed more frequently at night and during the rainy season. Applications of the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model for light fog forecast were tested. Thermodynamic processes were studied by vertical profile, elaborated by: (1) National Centers for Environmental Prediction (NCEP) reanalysis data for Maceio (because of some radiosonde absence) and (2) forecast vertical temperature and humidity profiles were produced, using Air Parcels Trajectories of the HYSPLIT model at the pattern levels. The synoptic situations before and during low visibility phenomena were analyzed using different products of NCEP reanalysis, the high resolution (10 km) ETA model and infrared satellite images. Wave disturbance in the trade winds field, localized on the northwest periphery of the South Atlantic subtropical High, usually accompanied the phenomena. A humidity advection, weak ascendant movement and thermal inversion absence at the low levels were created by these waves. The middle level’s descendent movement provoked the humidity accumulation at levels below. Satisfactory results of the HYSPLIT model applications for light fog forecast were obtained with 12 h antecedence. In particular, stable level forecast by the ETA model was forecast satisfactorily with 12 h antecedence; vertical movements were predicted better with up to 48 h antecedence. The PSU/NCAR mesoscale model (MM5) and PAFOG models were tested for analysis and forecast of an intensive fog event. Intensive fog provoked a fatal accident of a small airplane near the Maceio Airport in 2007. These fog formation processes were studied by NCEP reanalysis data, the high resolution regional model MM5, and satellite and radar data. Fog formation was simulated by PAFOG model and satisfactory results were obtained with 10 h antecedence.