海水中甲基对硫磷和马拉硫磷的气相色谱法测定

基于《水质有机磷农药的测定－气相色谱法》,结合海水中农药的含量低可降解等特点,对检测海水中甲基对硫磷和马拉硫磷的方法进行了改进。本方法改用电子捕获检测器和玻璃填充柱用的担体,固定液;及色谱条件。实验室的验证结果表明：修改后的检测方法检测灵敏度可以满足对海水中甲基对硫磷和马拉硫磷较低含量的检测要求。     

Biostratigraphy,sedimentology and sequence stratigraphy of the Tournaisian–Viséan transitional strata in South China (Guangxi)

The biostratigraphy and sedimentological evolution of the Tournaisian–Viséan (T–V) transitional strata in South China (Guangxi) have been investigated. The sediments were deposited on a carbonate platform and in slope and basinal environments. In the T–V transitional strata, six foraminiferal associations have been distinguished which allow correlation between the shallow and deep water deposits. A careful examination of the evolutionary stages of the foraminifer Eoparastaffella provides a more accurate criterion for the definition of the T–V boundary, but does not significantly modify the historical one. The distinction of two morphotypes is based on the elevation of the last whorl and the peripheral outline. Tournaisian specimens of Eoparastaffella have a well rounded periphery (morphotype 1) contrasting with the subangular periphery of younger Viséan specimens (morphotype 2). A coefficient can be deduced from simple biometric measurements for more precisely defining the T–V boundary. The sequence stratigraphy of the T–V strata in South China has been reconstructed by combining biostratigraphical and sedimentological data. It allowed the correlation of the T–V transitional strata between the platform area and the slope and basinal locations. Late Tournaisian strata were deposited during a highstand systems tract. Near the end of the Tournaisian, a major drop in relative sea-level led to the development of an unconformity in the platform area. Lowstand deposits formed during latest Tournaisian time in the basin where a detailed biostratigraphic framework has been devised. Sediments deposited during the ensuing transgressive systems tract overlie the late Tournaisian highstand sediments in the platform area and the latest Tournaisian lowstand deposits in the basin. A major drop in relative sea-level near the end of the Tournaisian has been recognized worldwide. Therefore, the possibility of using the sequence stratigraphy of the T–V strata in South China for worldwide correlations should be investigated. © 1997 John Wiley & Sons, Ltd.     

Insights into ground response during underground coal gasification through thermo-mechanical modeling

This paper presents a coupled thermo-mechanical model to investigate the ground response during underground coal gasification (UCG). The model incorporated the temporal and spatial development of temperature, the gradual growth of the cavity, and temperature-dependent material properties. Model verification was made against two benchmarks to acquire the confidence for the predictive purpose. The first exercise demonstrated the correctness of the model implemented in COMPASS. The second exercise showed that using the ash-filled cavity to represent null or empty zones is a good option in the numerical modeling and provided highly comparable results to other models. Based on the Hanna UCG trial, different cases were simulated to investigate the effects of the cavity size in the coal seam and the thermal expansion coefficient of the caprock and base rock on key features that take place during the process of UCG. A maximum temperature in the range of 1200–1500 ℃ was induced by the gasification of coal, and a cavity with a maximum length of 13.5 m was formed after 30 days of simulation. Meanwhile, small vertical displacement in the range of -5–12 mm took place near the cavity because of the thermal expansion of the geologic materials and the reduction of the overall weight with the creation of the cavity. In addition, it was found the thermal expansion coefficients can influence the thermo-mechanical response of geologic materials, but the effects were insignificant when its order of magnitude was smaller than 10^-6 K^-1.     

鄂尔多斯盆地北部上古生界层序地层特征与储层发育规律

通过地震和测井层序地层分析,可在鄂尔多斯盆地北部上古生界识别出４个地震层序,层序界面均以区域性侵蚀面或河道冲刷面为边界。层序的发育特征反映了鄂尔多斯盆地在晚古生代经历了陆表海盆地的形成、发展、衰退和逐渐消亡的过程。储集层主要是石炭系的滨岸砂体、二叠系的河道砂体以及冲积扇砂体。在层序地层体制中,储层的纵向发育受基准面升降变化旋回的控制,而平面展布受古地貌的制约。通过地震与钻井的综合分析,具体预测出有利的储集砂体分布。     

Variations of <Emphasis Type="Italic">δ</Emphasis><Superscript>18</Superscript>O in precipitation from the Muztagata Glacier,East Pamirs

Expeditions to Muztagata (in the eastern Pamirs) during the summer seasons of 2002 and 2003 collected precipitation samples and measured their oxygen isotopes. The δ ¹⁸O in precipitation displays a wide range, varying from −17.40‰ to +1.33‰ in June-September 2002 and from −22.31‰ to +4.59‰ in May-August 2003. The δ ¹⁸O in precipitation correlates with the initial temperature of precipitation during the observing periods. The positive correlation between δ ¹⁸O and temperature suggests that δ ¹⁸O can be used as an indicator of temperature in this region. The δ ¹⁸O values in fresh-snow samples collected from two snow events at different elevations on the Muztagata Glacier show a strong “altitude effect”, with a ratio of nearly −0.40% per 100 m from 5500 m to 7450 m.     

新疆西天山金属矿床,成矿系列及形成演化规律

笔者根据对西天山北部大量矿床和矿点研究,在对西天山成矿类型及成矿控制因素分析的基础上,将该区金属矿床主要划分为３个成矿系列类型,即：①与中酸性、酸性花岗岩类有关的Ｃｕ－Ｆｅ－Ａｕ－ＭｏＯ－Ｗ－Ｓｎ－Ｐｂ－Ｚｎ成矿系列类型;②与基性－中性－酸性火山岩建造有关的Ｃｕ－Ｆｅ－Ａｕ成矿系列类型;③与沉积岩、热水沉积岩有关的层控Ｃｕ－Ｐｂ－Ｚｎ成矿系列类型。每个成矿系列类型具有不同的成矿特征和成矿背景。成矿     

江西省云水资源特征分析

利用江西周边11个探空站资料与江西省内84个站1959—2007年降水资料,根据天气学原理和数理统计学方法,对江西省大气中总水汽量、总云水量、水汽交换次数、水汽更新率、实际总降水量等进行计算分析。结果表明:总水汽量、总云水量最大值均出现在6月(1975年),最小值出现在12月(1963年);中度干旱频率区域总云水量值最大,轻度干旱频率区域总云水量值最小;水汽交换次数平均为7.23次/月;水汽更新率平均4.22天/次;总水汽量、总云水量的地理分布呈北部高、南部低趋势分布;总水汽量、总云水量、总降水量相关性比较好,年变化呈现多峰型。     

山西省不同地貌形态类型区土地覆被变化的GIS分析

基于全国1:100万数字地貌数据库,全国2000、2005、2010年土地覆被数据和山西省行政区边界数据,采用土地覆被动态度、转移概率矩阵和地貌面积频度方法,分析了2000-2010年山西省基本地貌形态类型下的土地覆被变化。结果表明：（1）山西省的土地覆被类型以耕地、林地和草地为主,面积总和占省域面积的95%以上。面积变化的总体趋势是耕地和草地缩减,林地和建设用地持续增加。通过分析转移概率矩阵,表明2000-2005年和2005-2010年2个时段内,土地利用的主要转化趋势相似,即林地与草地之间大面积的相互转化,耕地、草地分别与建设用地之间的相互转化。（2）耕地和建设用地的分布,随着起伏度的增大而逐渐减小。林地分布随着起伏度的增加而逐步增大。从面积变化来看,耕地、林地和草地变化主要位于中起伏山地;水域变化主要集中在大起伏山地;建设用地变化主要分布于平原和台地;未利用地变化主要在小起伏山地。从动态度来看,耕地、草地和水域动态度,在大起伏山地地区最大;林地动态度在平原区最大;建设用地的动态度最大位于丘陵;未利用地在小起伏山地地区最大。（3）土地覆被类型之间的主要转化在地貌上也存着差异。平原地区林地的增加主要来自草地转化。台地和丘陵地区3个主要转化类型相似,2000-2005年主要是林地向草地退化,2005-2010年主要是林地和草地的相互转化。在小起伏山地地区,主要是草地和林地之间的相互转化,但草地转化为林地的面积较林地向草地的转化多。中起伏和大起伏山地地区主要以草地和耕地向林地的转化为主,也有较高比例的建设用地转化为林地。封山育林和退耕还林主要是在起伏较大的山地地区,毁林主要发生在地形平缓地区。     

青藏高原东南缘活动断裂的地震应变能释放系统研究

本文以青藏高原东南缘为研究区域,利用G-R震级能量经验公式和Benioff地震应变能释放曲线,对该区域内1500年以来的历史地震应变能释放进行了系统性的研究。文中给出了各断裂带和断块区的地震应变能释放周期表,及相应的地震危险性。分析发现研究区域地震应变能的释放具有东强西弱,南强北弱的特征,整体上各断层断块区的历史地震应变能释放符合准周期模式,某些断层和断块区上的地震周期具有某种程度上的同步现象。青藏高原东南缘现今处于大释放期中,地震的危险性不能忽视。局部结果显示,安宁河-则木河断裂带、小江断裂带的危险性很高,对于这些危险区要重点跟踪研究。今后仍需结合不同研究方法来提高地震危险性评估的可靠性。     

Precise revision of the garnet-muscovite geothermometer

The garnet-muscovite geothermometer was refined through empirical calibration by using natural rocks metamorphosed under the physical conditions of 238—1306 MPa and 490—700℃. Input temperatures and pressures were determined through simultaneously applying the garnet-biotite geothermometer and the garnet-biotite-plagioclase-quartz barometer, assuming that all FeO in muscovite and garnet be ferrous. Garnet was treated as the asymmetric quaternary solid solution, and muscovite as the symmetric binary solid solution. Input muscovite compositions include Fe atoms between 0.03—0.19 and Mg atoms between 0.04—0.16 on the basis of 11 oxygen atoms, and input garnet compositions include spessartine fractions between 0.01—0.289, grossular fractions between 0.028—0.273, and the Fe/Mg ratio between 3.387-18.986. The resulting garnet-muscovite geothermometer reproduces temperatures within (50℃ compared with the garnet-biotite thermometer. Total random error of ±37℃ of the new thermometer may stem from the pressure uncertainty of ±200 MPa, and uncertainties of ±5% of Fe and Mg components in muscovite, and ±5% of Fe, Mg, Mn and Ca components in garnet, altogether. When there exist 10%, 20%, 30%, 40% and 50% Fe3+ in muscovite, respectively, the computed garnet-muscovite temperatures will be 1—6℃, 2—12℃, 3—16℃, 5—24℃ and 7—29℃, respectively, lower than those obtained when assuming that all FeO be ferrous. The new garnet-muscovite geothermometer can efficiently reflect temperature change of typical prograde sequences and contact aureole rocks, and may be applied to low- to high-grade and low- to high-pressure metamorphic rocks.