Natural Attenuation of Perchlorate in Denitrified Groundwater

Monitoring of a well‐defined septic system groundwater plume and groundwater discharging to two urban streams located in southern Ontario, Canada, provided evidence of natural attenuation of background low level (ng/L) perchlorate (ClO₄^?) under denitrifying conditions in the field. The septic system site at Long Point contains ClO₄^? from a mix of waste water, atmospheric deposition, and periodic use of fireworks, while the nitrate plume indicates active denitrification. Plume nitrate (NO₃^?‐N) concentrations of up to 103 mg/L declined with depth and downgradient of the tile bed due to denitrification and anammox activity, and the plume was almost completely denitrified beyond 35 m from the tile bed. The ClO₄^? natural attenuation occurs at the site only when NO₃^?‐N concentrations are <0.3 mg/L, after which ClO₄^? concentrations decline abruptly from 187 ± 202 to 11 ± 15 ng/L. A similar pattern between NO₃^?‐N and ClO₄^? was found in groundwater discharging to the two urban streams. These findings suggest that natural attenuation (i.e., biodegradation) of ClO₄^? may be commonplace in denitrified aquifers with appropriate electron donors present, and thus, should be considered as a remediation option for ClO₄^? contaminated groundwater.     

Electron microbeam analysis of urban road-deposited sediment,Manchester, UK: Improved source discrimination and metal speciation assessment

Road-deposited sediment (RDS) is an accumulation of particulates upon street surfaces in urban centres. It is commonly highly contaminated and has major potential impacts upon surface water quality and human health, as well as becoming a waste material upon street sweeping. Although significant research has been undertaken upon the fine fraction within these systems, there is a lack of detailed, high-resolution grain-specific mineralogical and chemical data for the coarser fractions, which contain the bulk of the contamination by mass. The study reported here utilizes backscatter electron microscopic, electron microprobe and Raman spectroscopic analysis to provide novel data on RDS material from Manchester, UK, with significant implications for the improved understanding of source discrimination and contaminant metal speciation. The RDS samples studied are highly heterogeneous and the abundant nature of anthropogenic grains is particularly apparent. The RDS material has been found to be composed of a number of grain types: (i) silicate and alumino-silicate grains derived from a wide range of sources; (ii) iron oxide grains derived from the corrosion of galvanized steel; (iii) iron-rich glass grains derived as slag material from metal and waste processing activities and (iv) spherical Fe oxide and Fe-rich glass grains derived from high temperature combustion processes. Elemental metallic grains (Fe, Cu, Pb) are also present in minor amounts.     

Ultraviolet spectroscopy of Asteroid (4) Vesta

We report a comprehensive review of the UV–visible spectrum and rotational lightcurve of Vesta combining new observations by Hubble Space Telescope and Swift Gamma-ray Burst Observatory with archival International Ultraviolet Explorer observations. The geometric albedos of Vesta from 220 nm to 953 nm are derived by carefully comparing these observations from various instruments at different times and observing geometries. Vesta has a rotationally averaged geometric albedo of 0.09 at 250 nm, 0.14 at 300 nm, 0.26 at 373 nm, 0.38 at 673 nm, and 0.30 at 950 nm. The linear spectral slope as measured between 240 and 320 nm in the ultraviolet displays a sharp minimum near a sub-Earth longitude of 20°, and maximum in the eastern hemisphere. This is consistent with the longitudinal distribution of the spectral slope in the visible wavelength. The photometric uncertainty in the ultraviolet is ∼20%, and in the visible wavelengths it is better than 10%. The amplitude of Vesta’s rotational lightcurves is ∼10% throughout the range of wavelengths we observed, but is smaller at 950 nm (∼6%) near the 1-μm band center. Contrary to earlier reports, we found no evidence for any difference between the phasing of the ultraviolet and visible/near-infrared lightcurves with respect to sub-Earth longitude. Vesta’s average spectrum between 220 and 950 nm can well be described by measured reflectance spectra of fine particle howardite-like materials of basaltic achondrite meteorites. Combining this with the in-phase behavior of the ultraviolet, visible, and near-infrared lightcurves, and the spectral slopes with respect to the rotational phase, we conclude that there is no global ultraviolet/visible reversal on Vesta. Consequently, this implies a lack of global space weathering on Vesta, as previously inferred from visible–near-infrared data.     

Developmental energetics of the southern pigfish (Teleostei: Congiopodidae)

The embryonic wet weight, dry weight, yolk volume, energy content, and oxygen consumption of the southern pigfish Congiopodus leucopaecilus (Richardson, 1846) were followed from fertilisation to yolk sac absorption, at 11.5°c and salinity of 34.5%6. Measurements of yolk energy and catabolic energy changes did not show any evidence of an energy deficit before the onset of feeding capability.     

Diplophos rebainsi Krefft & Parin, 1972, an addition to the mesopelagic fish fauna of New Zealand (note)

Plankton samples taken in the south‐western Pacific Ocean and the Tasman Sea have provided, for the first time in these waters, a series of individuals of the gonostomatid Diplophos rebainsi. Observations are presented on some of the prejuvenile and adult features and on the seasonal distribution of prejuveniles off New Zealand.     

Planktonic stages of Maurolicus muelleri (Teleostei Sternoptychidae) in New Zealand waters

The seasonality and distribution, abundance, and hydrological affinities of the planktonic stages of the sternoptychid Maurolicus muelleri (Grnelin, 1788) are described for the New Zealand region. Spawning occurred from August to March, and the planktonic stages were widespread around New Zealand. Spawning probably takes place around midday at depths greater than 250 m. Eggs and larval stages were present over temperature ranges of 9.0–15.5°c and 13–22°c respectively.     

Initial results and progress of the Mississippi delta sediment pore water pressure experiment

Abstract

This report describes the instrumentation, initial results, and progress of an experiment designed to measure and monitor submarine sediment pore water and hydrostatic pressures in a selected area of the Mississippi Delta. The experiment also is intended to monitor significant pressure perturbations during active storm periods. Initial analysis of the data revealed excess pore water pressures in the silty clay sediment at selected depths below the mudline. Continuous monitoring of the pore water and hydrostatic pressures was expected to reveal important information regarding sediment pore water pressure variations as a function of the geological processes active in the Mississippi Delta.     

Book review

Offshore Soil Mechanics edited by Philip George and David Wood. Cambridge University Engineering Department and Lloyd's Register of Shipping, London, 1976. 468 pp. £7.50 + shipping.

Beach Processes and Sedimentation by Paul D. Komar. Prentice‐Hall, Inc. Englewood Cliffs, New Jersey, 1976. 429 pp., $26.95.     

The lithospheric transition between the Delamerian and Lachlan orogens in western Victoria: new insights from 3D magnetotelluric imaging

The magnetotelluric (MT) method was used to image the crust and upper mantle beneath the Delamerian and Lachlan orogens in western Victoria, Australia. During the Cambrian time period, this region changed from being the extended passive margin of Proterozoic Australia into an Andean-style convergent margin that progressively began to accrete younger oceanic terranes. Several broadband MT transects, which were collected in stages along coincident deep (full crust imaging) seismic reflection lines, have now been combined to create a continuous 500 km east–west transect over the Delamerian–Lachlan transition region in the Stawell Zone. We present the electrical resistivity structure of the lithosphere using both 3D and 2D inversion methods. Additionally, 1D inversions of long-period AusLAMP (Australian Lithospheric Architecture Magnetotelluric Project) MT data on a 55 km regionally spaced grid were used to provide starting constraints for the 3D inversion of the 2D profile. The Delamerian to Lachlan Orogen transition region coincides with the Mortlake Discontinuity, which marks an isotopic discontinuity in Cenozoic basalts, with higher strontium isotope enrichment ratios in the Lachlan Orogen relative to the Delamerian Orogen. Phase tensor ellipses of the MT data reveal a distinct change in electrical resistivity structure near the location of the Mortlake Discontinuity, and results of 3D and 2D inversions along the MT profile image a more conductive lower crust and upper mantle beneath the Lachlan Orogen than the Delamerian Orogen. Increased conductivity is commonly ascribed to mantle enrichment and thus supports the notion that the isotope enrichment of the Cenozoic basalts at least partially reflects an enriched mantle source rather than crustal contamination. Fault slivers of the lower crust from the more conductive Lachlan region expose Cambrian boninites and island arc andesites indicative of subduction, a process that can enrich the mantle isotopically, and also electrically, by introducing carbon (graphite) and water (hydrogen).     

Geomorphic Controls on Historical Channel Planform Changes on the Lower Pages River,Hunter Valley,Australia

Historical planform changes in a 14.7 km reach of the lower Pages River were determined to assess whether they were autogenic (inherent in the river regime) or allogenic (driven by external changes) in nature so as to better focus river management activities and river restoration works. A pattern metamorphosis or complete change in river morphology occurred during the February 1955 flood. The peak discharge of this event exceeded the slope and grain size (intrinsic) threshold for braiding, converting the narrow, slightly sinuous stream to a wide, braided-like river. Five subsequent intrinsic threshold-exceeding floods did not cause further bar development because an over-widened channel already existed. Autogenic channel planform changes included sinuosity variations due to lateral migration and pattern metamorphosis due to the exceedance of a discharge–slope–grain size geomorphic threshold. Allogenic channel planform changes included: (1) realignment/channel straightening and artificial cutoffs by river training works; (2) lateral migration by increased bank erodibility due to riparian vegetation clearing; (3) lateral migration by the operation of a transitive geomorphic threshold involving the onset of a flood-dominated regime after 1946 and increased catchment runoff after 1830 due to large-scale clearing of catchment vegetation; and (4) the occurrence of a large flood in February 1955. Multiple forcing factors have clearly caused historical channel planform changes of the lower Pages River, making the design of river management and restoration works a complex matter outside the scope of simple formulaic protocols.