The formation of porphyry copper deposits

Copper is a moderately incompatible chalcophile element. Its behavior is strongly controlled by sulfides. The speciation of sulfur is controlled by oxygen fugacity. Therefore, porphyry Cu deposits are usually oxidized (with oxygen fugacities > ΔFMQ +2) (Mungall 2002; Sun et al. 2015). The problem is that while most of the magmas at convergent margins are highly oxidized, porphyry Cu deposits are very rare, suggesting that high oxygen fugacity alone is not sufficient. Partial melting of mantle peridotite even at very high oxygen fugacities forms arc magmas with initial Cu contents too low to form porphyry Cu deposits directly (Lee et al. 2012; Wilkinson 2013). Here we show that partial melting of subducted young oceanic slabs at high oxygen fugacity (>ΔFMQ +2) may form magmas with initial Cu contents up to >500 ppm, favorable for porphyry mineralization. Pre-enrichment of Cu through sulfide saturation and accumulation is not necessarily beneficial to porphyry Cu mineralization. In contrast, re-melting of porphyritic hydrothermal sulfide associated with iron oxides may have major contributions to porphyry deposits. Thick overriding continental crust reduces the “leakage” of hydrothermal fluids, thereby promoting porphyry mineralization. Nevertheless, it is also more difficult for ore forming fluids to penetrate the thick continental crust to reach the depths of 2–4 km where porphyry deposits form.     

Effects of river damming on biogenic silica turnover: implications for biogeochemical carbon and nutrient cycles

Rivers link terrestrial ecosystems and marine ecosystems, and they transport large amounts of substances into oceans each year, including several forms of silicon (Si), carbon (C), and other nutrients. However, river damming affects the water flow and biogeochemical cycles of Si, C, and other nutrients through biogeochemical interacting processes. In this review, we first summarize the current understanding of the effects of river damming on the processes of biogeochemical Si cycle, especially the source, composition, and recycling process of biogenic silica (BSi). Then, we introduce dam impacts on the cycles of C and some other nutrients. Dissolved silicon in rivers is mainly released from phytolith dissolution and silicate weathering. BSi in suspended matter or sediments in most rivers mainly consists of phytoliths and mainly originates from soil erosion. However, diatom growth and deposition in many reservoirs formed by river interception may significantly increase the contribution of diatom Si to total BSi, and thus significantly influence the biogeochemical Si, C, and nutrient cycles. Yet the turnover of phytoliths and diatoms in different rivers formed by river damming is still poorly quantified. Thus, they should be further investigated to enhance our understanding about the effects of river damming on global biogeochemical Si, C and nutrient cycles.     

Temporal and spatial characteristics of dissolved organic carbon in the Wujiang River,Southwest China

River systems play an important role in the global carbon cycle. Rivers transport carbon to the ocean and also affect the carbon cycle in the coastal ocean. The flux from land to the ocean is thought to be a very important part of the land carbon budget. To investigate the effect of dam-building on dissolved organic carbon (DOC) in rivers, three reservoirs of different trophic states in the Wujiang basin, Guizhou Province, were sampled twice per month between May 2011 and May 2012. Temporal and spatial distributions of DOC in the reservoirs and their released waters were studied. It was found that different factors controlled DOC in river water, reservoir water, and released water. DOC in the rivers tended to be affected by primary production. For reservoirs, the main controlling factors of DOC concentration varied by trophic state. For the mesotrophic Hongjiadu Reservoir, the effect of primary production on DOC concentration was obvious. For the eutrophic Dongfengdu Reservoir and the hypereutrophic Wujiangdu Reservoir, primary production was not significant and DOC came instead from soil and plant litter.     

Spatial characters of nutrients in Wujiangdu Reservoir in karst river,SW China

A preliminary assessment of the Wujiangdu Reservoir examined nutrient distribution and transport. Water samples were collected in the summer (July) of 2004, during the high-flow season. Inorganic nutrients (N, P, Si) and chlorophyll a (chl a) concentrations of the Wujiangdu Reservoir and its inflow rivers were analyzed. Other water parameters (dissolved oxygen, pH, temperature, and electrical conductivity) were measured as well. The results show gradually decreasing concentrations of NO₃ ^?-N and dissolved silicate in the surface water moving downstream to the dam of the Wujiangdu Reservoir. Additionally, soluble reactive phosphorus concentrations measured very low, with most falling below the sensitivity threshold of the method used in surface waters. Particulate phosphorus and NO₃ ^?-N were the predominant species of phosphorus and nitrogen in the reservoir, respectively. The concentration of nutrients in the Yeji River was the largest of all inflow rivers. The maximum concentration of chl a was found near the dam. These results reflect upstream conditions similar to that of a river, and reservoir conditions near the dam similar to that of a natural lake system.     

Open tensile fractures at depth in anticlines: A case study in the Tarim basin,NW China

Understanding fracture openness in the Earth's crust is crucial for understanding fracture properties and their impact on fluid flow and potentially also in reservoir modelling. Here, we present cases showing the presence of open tensile fractures at depth in anticlines by integrating borehole imaging logs, core observations, casting sections, physical modelling, in‐situ stress analysis and production data in petroleum wells, and analysing the time of fracturing by fluid inclusion analysis. The data come from the Cretaceous Bashejiqike Formation in the Kuqa Depression, Tarim basin; its current depth varies between 6,000 and 8,100 m. The results show that tensile fractures are the main fracture type in the studied formation and that their hydraulic conductivity is poorly affected by the current maximum horizontal stress direction. Furthermore, we find that fracture development is uninterrupted during continued anticline folding, although there is a dominant time of fracturing.     

Agent-based tsunami evacuation modeling of unplanned network disruptions for evidence-driven resource allocation and retrofitting strategies

The constant threat from landslides in the northeastern part of Istria, Croatia, calls for the need to apply accurate and reliable methods in landslide hazard assessment in order to prevent landslide damage and to set an early warning system if necessary. Furthermore, landslide susceptibility and hazard assessment enable optimal area management and regional urban planning. The study area is in the northeastern and central part of the Istrian Peninsula, well known as an area of frequent, small and shallow slope instability phenomena. Landslide susceptibility assessment in the area around the city of Buzet was performed using a deterministic landslide susceptibility model in the LS-RAPID software. LS-RAPID was developed to analyze stability at one single location, but the performed analysis has shown that LS-RAPID can be used as a powerful tool in landslide susceptibility and hazard assessment on regional scale. The objective of this paper is to establish the influence of the runout potential on the enlargement of the landslide-susceptible zones, due to expansion of the failure area around the initial failure zone. Performed analysis of rainfall return periods shows the frequency of landslide occurrence and provides the possible correlation with the time component of landslide hazard in the area.     

Characteristics of black shale in the Upper Ordovician Wufeng and lower Silurian Longmaxi formations in the Sichuan Basin and its periphery,China

Geochemical and mineralogical analyses, in addition to isothermal adsorption experiments on field samples, are used to characterise the sedimentary environments, reservoirs and adsorbed gas of the Upper Ordovician Wufeng–lower Silurian Longmaxi formations in the Sichuan Basin and its peripheral areas. The sedimentary environment of the Wufeng and the lower part of Longmaxi formations is a deep-water shelf with five different lithologies identified: siliceous shale, black shale, siltstone, biolithite limestone and bentonite. The black shale in the Wufeng and the lower part of Longmaxi formations is 50 m thick, with an average organic carbon content (TOC) of 3.81 wt% and a maturity (Ro) of 1.62%. Quartz comprises 54.94 vol% of the shale and positively correlates with the TOC. Micropores in the black shale include intergranular pores, intragranular pores, organic matter pores and microfractures. Among these pores, spaces between clay sheets and organic molecules represent a favourable storage space for the accumulation and preservation of oil and gas. The Langmuir volume parameter ranges between 1.52 and 3.01 cm³/g, with an average value of 2.33 cm³/g. The presence of organic matter pores and pores between clay sheets in the black shale is the main and controlling factor for accumulated gas.     

Application of low-pressure gas adsorption to nanopore structure characterisation of organic-rich lower Cambrian shale in the Upper Yangtze Platform,South China

The pores in shales are mainly on a nanometer scale, and the pore-size distribution is vital with regard to the preservation and exploitation of shale gas. This study focuses on the organic-rich lower Cambrian black shale in the Upper Yangtze Platform, South China and investigates their TOC, mineralogical composition and nanopore structure. Low-pressure N₂ and CO₂ adsorption experiments were conducted at 77.35 K and 273.15 K, respectively, and the nanopore structures were characterised by the modified Brunauer–Emmett–Teller, Dubinin–Radushkevich, t-plot, Barrett–Joyner–Halenda and density functional theory (DFT) methods. The results indicate the following. (1) The lower Cambrian shale has a high TOC content (1.77–7.23 wt%) and a high quartz content (27.7–51.6 vol%). The total specific surface area varies from 12.02 to 28.87 m²/g. Both the total specific surface area and quartz content are positively associated with the TOC content. (2) Shale samples with a higher TOC content have a greater number of micropores, resulting in more complicated nanopore structures. Micropore volumes/surface areas and non-micropore surface areas all increase with increasing TOC content, indicating that TOC is the key factor determining the nanopore structure of the lower Cambrian shale. (3) A combination of N₂ and CO₂ adsorption provides the most suitable detection range (～0.3–60 nm) and is both highly reliable and accurate with regard to nanopore structure characterisation.     

颗粒破碎对煤矸石渗透性能的影响

采用标准试验方法求得筑坝用煤矸石的最大干密度和相应的最优含水量。试验结果表明,击实作用使煤矸石的粗大颗粒发生破碎,导致其粒度组成改变,颗粒级配进一步趋于良好,有利于碾压密实。当粗粒质量分数大于60%时,煤矸石的破碎程度明显提高。当粗粒质量分数小于40%时,煤矸石的工程特性主要由细颗粒的性质决定。煤矸石的渗透系数和孔隙比之间存在指数关系。随细颗粒含量的增加,煤矸石的渗透性将显著降低。     

Experimental and numerical investigation of groundwater head losses on and nearby short intersections between disc-shaped fractures

Discrete fracture models are used for investigating precise processes of groundwater flow in fractured rocks,while a disc-shaped parallel-plates model for a single fracture is more reasonable and efficient for computational treatments.The flow velocity has a large spatial differentiation which is more likely to produce non-linear flow and additional head losses on and nearby intersections in such shaped fractures,therefore it is necessary to understand and quantify them.In this study,both laboratory experiments and numerical simulations were performed to investigate the total head loss on and nearby the intersections as well as the local head loss exactly on the intersections,which were not usually paid sufficient attention or even ignored.The investigation results show that these two losses account for 29.17%-84.97%and 0-73.57%of the entire total head loss in a fracture,respectively.As a result,they should be necessarily considered for groundwater modeling in fractured rocks.Furthermore,both head losses become larger when aperture and flow rate increase and intersection length decreases.Particularly,the ratios of these two head losses to the entire total head loss in a fracture could be well statistically explained by power regression equations with variables of aperture,intersection length,and flow rates,both of which achieved high coefficients of determination.It could be feasible through this type of study to provide a way on how to adjust the groundwater head from those obtained by numerical simulations based on the traditional linear flow model.Finally,it is practicable and effective to implement the investigation approach combining laboratory experiments with numerical simulations for quantifying the head losses on and nearby the intersections between disc-shaped fractures.