水溶液中聚合物在粘土上的吸附

水溶液中聚合物在粘土上的吸附对于聚合物污染防治和污水处理等都有重要意义。Scheutjens-Fleer理论是应用范围最广的聚合物吸附理论,适应于从单体到长链高聚物,从链无相互作用的稀溶液到纯聚合物的吸附研究。本文简要介绍了有关聚合物吸附的重要参数,包括吸附量、耦合分数或直接表面覆盖、平均层厚度和链段密度,以及相应的测定方法。文中分析了影响聚合物吸附研究发展的主要问题,指出水溶液中聚合物在粘土上的吸附研究的发展方向是综合研究吸附等温线和A/V效应、耦合分数、吸附层厚度、吸附分级现象和对粘土层间的影响,并与Scheutjens-Fleer理论计算结果进行比较。     

Magnetic minerals in Mid-Pleistocene sediments on the Caiwei Guyot,Northwest Pacific and their response to the Mid-Brunhes climate event

Seamounts are ubiquitous topographic units in global oceans, and their influences on local oceanic circulation have attracted great attention in physical oceanography; however, previous efforts were less made in paleoclimatology and paleoceanography. The Caiwei Guyot in the Magellan Seamounts of the western Pacific is a typical seamount, and in this study, we investigate a well-dated sediment core by magnetic properties to reveal the relationship between deep-sea sedimentary processes and global climate changes. The principal results are as follows: (1) the dominant magnetic minerals in the sediments are low-coercivity magnetite in pseudo-single domain range, probably including a biogenic contribution; (2) the variabilities of magnetic parameters can be clustered into two sections at ～500 ka, and the differences between the two units are evident in amplitudes and means; (3) changes in the grainsize-dependent magnetic parameters can be well correlated to records of global ice volume and atmospheric CO2 in the middle Pleistocene. Based on these results, a close linkage was proposed between deep-sea sedimentary processes in the Caiwei Guyot and global climate changes. This linkage likely involves different roles of biogenic magnetite in the sediments between interglacial and glacial intervals, responding to changes in marine productivity and deep-sea circulation and displaying a major change in the Mid-Brunhes climate event. Therefore, we proposed that the sedimentary archives at the bottom of the Caiwei Guyot record some key signals of global climate changes, providing a unique window to observe interactions between various environmental systems on glacial-interglacial timescales.     

Solar-, monsoon- and Kuroshio-influenced thermocline depth and sea surface salinity in the southern Okinawa Trough during the past 17,300 years

Factors influencing millennial-scale variability in the thermocline depth (vertical mixing) and sea surface salinity (SSS) of the southern Okinawa Trough (OT) during the past 17,300 years were investigated based on foraminifer oxygen isotope records of the surface dweller Globigerinoides ruber sensu stricto and the thermocline dweller Pulleniatina obliquiloculata in the AMS ¹⁴C dated OKT-3 core. The thermocline depth is influenced by surface thermal buoyancy (heat) flux, in turn controlled by the annual mean insolation at 30°N and the strength of the East Asian winter monsoon (EAWM). Strong insolation and weak EAWM tend to increase buoyancy gain (decrease buoyancy loss), corresponding to shallow thermocline depths, and vice versa. Regional SSS is influenced by the global ice volume, the Kuroshio Current (KC), and vertical mixing. A deep thermocline coincides with a high SSS because strong vertical mixing brings more, saltier subsurface KC water to the surface, and vice versa. Local SSS (excluding the global ice volume effect) became lower in the northern OT than in the southern OT after ~9.2 ka, implying that Changjiang diluted water had stronger influence in the northern sector. SSS show no major changes during the Bølling/Allerød and Younger Dryas events, probably because the KC disturbed the North Atlantic signals. This argues against earlier interpretations of sea surface temperature records of this core. Wavelet and spectral analyses of the Δδ¹⁸O_P-G (δ¹⁸O of P. obliquiloculata minus G. ruber s.s.) and δ¹⁸O_local records display 1,540-, 1,480-, 1,050-, 860-, 640-, and 630-year periods. These are consistent with published evidence of a pervasive periodicity of 1,500 years in global climate as well as EAWM and KC signatures, and a fundamental solar periodicity of 1,000 years and intermediary derived periodicity of 700 years.     

2018?2019年舟山近海浮游动物群落结构春季年际变化及其与水团的关系

根据2018?2019年春季两个航次在舟山近海进行的浮游生物调查结果,对舟山近海的浮游动物群落结构(类群组成、优势种数量)年际变化进行了研究,利用典范对应分析(Canonical Correspondence Analysis, CCA)研究了两年春季浮游动物类群组成差异、优势种变化的原因,初步探讨了春季浮游动物群落结构动态变化的机制。结果表明:根据表层温度(Sea Surface Temperature,SST)、表层盐度(Sea Surface Salinity,SSS)的聚类分析,将该区域分为3个水团:杭州湾内水团(I区)、舟山本岛上升流水团II区)、舟山近海水团(III区)。不同水团对浮游动物类群组成影响显著,引起2018年和2019年春季3个水团区差异的主要贡献种(贡献率>10%)均为中华哲水蚤,同一水团两年间年际差异的贡献种如下:I区为捷氏歪水蚤(56.91%)和真刺唇角水蚤(12.34%);II区为中华哲水蚤(72.64%)、五角水母(13.35%);III区为中华哲水蚤(41.93%)、夜光虫(22.94%)。CCA分析表明,第1 CCA轴(CCA1)和第2 CCA轴(CCA2)共解释了两年春季浮游动物优势种累计方差的46.14%和物种?环境累计方差的97.82%。CCA1主要反映了空间(近海水团和湾内水团)的差异。CCA2主要反映了2018年和2019年站位的年际差异。盐度是影响春季浮游动物群落结构空间差异的主要因素,而温度、叶绿素a浓度是春季浮游动物群落结构年际差异的主要因素。     

MODIS地表温度产品与实测资料对比分析

陆面温度是研究地表和大气之间物质交换和能量交换的重要参数。本文通过NASAMODIS地表温度产品与常规资料的分析,发现利用MODIS资料反演的地表温度在山西省分布情况与实测资料基本一致,但应用MODIS资料反演的地表温度要小于实测数据。     

Hydrologic separation and their contributions to N loss in an agricultural catchment in hilly red soil region

The impacts of hydrological processes on N loss is of great value to understand the N transport at catchment scale,which is far from clear. Rainfall, soil water, groundwater and stream water and their N concentrations were monitored from March 2017 to February 2018 in Sunjia agricultural catchment of the red soil critical zone. Objectives of this study were:(1) to determine the dynamics of N concentration of different waters and their N loads;(2) to assess their contributions to N load of streamflow in the paddy and upland mixed agricultural catchment. Our results showed that the N concentrations of soil water(4.8 mg L~(-1)) and groundwater(6.0 mg L~(-1)) were the highest, approximately 2 to 5 times higher than those of stream water(2.7 mg L~(-1)), rain water(1.7 mg L~(-1)) and irrigation water(1.2 mg L~(-1)). The N net loss of the catchment(38.2 kg ha~(-1) yr~(-1))accounted for 15% of the total fertilizer N input. Rainy season(April–June) was a high-risk period of N loss, contributing to more than one third of the total annual loss amount. Using end-member mixing analysis model(EMMA), we found groundwater(whose discharge accounted for 25% of the catchment streamflow) was an important source for the N loss in the agricultural catchment. Even in this catchment with coexisting upland and paddy field ecosystems, identified end-members could be used to predict the N load well(R~20.87, p0.001). These results can deepen our understanding of the relationship between hydrological process and N transport in the red soil critical zone and are also helpful to improve the water and fertilizer management in subtropical agricultural catchment.     

登陆台风与其外围暴雨的相互作用

本文对8116号登陆台风及其环境和外围暴雨区分别作了动能平衡的诊断分析,结果表明,动能制造是三个区域动能平衡的主要能源,动能水平辐散和摩擦消耗则是主要能汇。在台风登陆减弱过程中,暴雨区的动能增加。台风区上层动能水平辐散呈显著的不对称型。台风右侧次天气尺度强风带起了向暴雨区输送动能使暴雨得到发展的作用。暴雨发生后,通过暴雨区北界向环境输送动能,于是,台风辐散的动能通过暴雨区最后输送给环境。这种动能传递过程可能是台风与环境大气相互作用引起台风衰减的机制之一。     

Imaging the rupture process of the 10 January 2018 MW7.5 Swan island,Honduras earthquake*

The 10 January 2018 M_W7.5 Swan island, Honduras earthquake occurred on the Swan island fault, which is a transform plate boundary between the North American and Caribbean plates. Here we back-project the rupture process of the earthquake using dense seismic stations in Alaska, and find that the earthquake ruptured at least three faults (three stages) for a duration of ~40 s. The rupture speed for the longest fault (stage 3) is as fast as 5 km/s, which is much faster than the local shear wave velocity of ~4 km/s. Supershear rupture was incidentally observed on long and straight strike-slip faults. This study shows a supershear rupture that occured on a strike-slip fault with moderate length, implying that supershear rupture might commonly occur on large strike-slip earthquakes. The common occurrence of supershear rupture on strike-slip earthquakes will challenge present understanding of crack physics, as well as strong ground motion evaluation in earthquake engineering.     

地应变震兆异常信息提取方法研究

分析了怀来台体积应变观测资料的特点,研究了体积应变观测资料的气压干扰、仪器漂移的剔除方法和预处理后的资料分析方法,在分析中发现,振幅因子和非潮汐应变速率在1996年以来,在首都圈地区中西部发生的中强地震前,均有大小不同、持续时间不等的异常,这些参数可作为怀来地震台今后地震分析和地震中短期预测的指标。     

上地幔密度异常驱动小尺度对流及实验模型

建立了由密度异常驱动上地幔小尺度对流的数学 物理模型, 发展了利用地震层析成像数据反演上地幔小尺度对流的基本理论和方法. 该模型建立在三维直角坐标系框架上, 假设地震层析成像所显示的地震波速度异常对应于上地幔物质密度异常, 而该密度异常反映了上地幔小尺度热对流系统的温度异常场. 模型首先将地震层析成像确定的地震波速度异常转换为密度异常, 并视其为对流的驱动力; 进而利用三维傅立叶变换, 在波数域内, 在给定的边界条件下, 求解控制流体行为的运动方程和连续性方程, 最后求得对流的流场. 为检验本研究提出的理论和方法的有效性, 本文使用了两个简单的实验模型： 热体和冷体模型; 俯冲断离( break off)板片模型, 计算了其驱动的地幔流场. 结果表明, 本文提供的理论和方法, 可以直接应用于与区域岩石层构造动力学相关的上地幔小尺度对流的研究.