Response of single benthic metrics and multi-metric methods to anthropogenic pressure gradients, in five distinct European coastal and transitional ecosystems

In recent times many benthic indices have been proposed to assess the ecological quality of marine waters worldwide. In this study we compared single metrics and multi-metric methods to assess coastal and transitional benthic status along human pressure gradients in five distinct environments across Europe: Varna bay and lake (Bulgaria), Lesina lagoon (Italy), Mondego estuary (Portugal), Basque coast (Spain) and Oslofjord (Norway). Hence, 13 single metrics (abundance, number of taxa, and several diversity and sensitivity indices) and eight of the most common indices used within the European Water Framework Directive (WFD) for benthic assessment were selected: index of size spectra (ISS), Benthic assessment tool (BAT), Norwegian quality index (NQI), Multivariate AMBI (M-AMBI), Benthic quality index (BQI), (Benthic ecosystem quality index (BEQI), Benthic index based on taxonomic sufficiency (BITS), and infaunal quality index (IQI). Within each system, sampling sites were ordered in an increasing pressure gradient according to a preliminary classification based on professional judgement. The different indices are largely consistent in their response to pressure gradient, except in some particular cases (i.e. BITS, in all cases, or ISS when a low number of individuals is present). Inconsistencies between indicator responses were most pronounced in transitional waters (i.e. IQI, BEQI), highlighting the difficulties of the generic application of indicators to all marine, estuarine and lagoonal environments. However, some of the single (i.e. ecological groups approach, diversity, richness) and multi-metric methods (i.e. BAT, M-AMBI, NQI) were able to detect such gradients both in transitional and coastal environments, being these multi-metric methods more consistent in the detection than single indices. This study highlights the importance of survey design and good reference conditions for some indicators. The agreement observed between different methodologies and their ability to detect quality trends across distinct environments constitutes a promising result for the implementation of the WFD’s monitoring plans. Moreover, these results have management implications, regarding the dangers of misclassification, uncertainty in the assessment, use of conflicting indices, and testing and validation of indices.     

Internal shocks in a relativistic wind as a source for gamma-ray bursts?

We investigate the recent proposal made by Rees and Mészáros (1994) that GRBs result from internal shocks in the relativistic wind emerging from two coalesced neutron stars. Using a simple model of that wind, where a large number of layers with different Lorentz factors interact through a series of mildly relativistic shocks we compute the efficiency of the process and the time profile of the resulting burst. We show that a great variety of profiles can be obtained using plausible initial distributions of Lorentz factors in the wind. However, the rather low overall efficiency (< 10%) of the process and limits imposed on the burst duration can be used to put severe constraints on the nature of the energy source.     

Incorporation of trivalent actinides into calcite: A time resolved laser fluorescence spectroscopy (TRLFS) study

In order to characterize and quantify the substitution of Ca(II) by Cm(III) (coordination, charge compensation), homogeneous Cm(III) coprecipitated calcite was synthesized in a mixed-flow-through experiment. Two sets of experiments were conducted at pH 8.1 and at pH 12.5.At pH 8.1 two calcites, a calcite with a low Cm³⁺ concentration (LCMpH8.1) and a calcite with a high M³⁺ (Gd³⁺ and Cm³⁺) concentration (HCMpH8.1) were grown and investigated by time resolved laser fluorescence spectroscopy. The Cm(III) emission spectra of LCMpH8.1 and HCMpH8.1 show the same Cm(III) fluorescence signals for two Cm(III) species; Cm(III) species (1) with a peak maximum at 606.2 nm and Cm(III) species (2) with a peak maximum at 620.3 nm. Cm(III) species (1) has a mean lifetime of τ = 386 ± 40 μs and Cm(III) species (2) has a mean lifetime of τ = 1874 ± 200 μs. A lifetime of 386 μs correlates with 1.3 water molecule in the first coordination sphere of the Cm ion whereas a lifetime of 1874 μs indicates the total loss of the Cm(III) hydration sphere. According to the fluorescence emission peak position and the fluorescence emission lifetime, Cm(III) species (1) is identified as a surface sorbed species whereas Cm(III) species (2) is identified as a Cm(III) incorporated into the calcite lattice.Cm(III) fluorescence emission spectra of Cm(III) doped calcite grown at pH 12.5 (LCMpH12.5) show the same peak maxima which are found for LCMpH8.1 and HCMpH8.1 grown at pH 8.1 but an additional emission band at 608.2 nm (3) is found, which can be assigned to a further Cm(III) species. Fluorescence emission lifetime measurements show that this Cm(III) species (3) has a lifetime of τ = 477 ± 25 μs, which correlates with 0.9 water molecules in the first coordination sphere. Cm(III) species (3) is suggested to be a CmOH²⁺ incorporated species.     

Post-LGM sedimentation on the outer shelf-upper slope of the northernmost part of the São Paulo Bight, southeastern Brazil

Sedimentary and isotope data as well as ¹⁴C AMS dating on 15 box cores were used to identify the main post-Last Glacial Maximum (LGM) processes in the outer shelf and upper slope of the northernmost part of the São Paulo Bight, southeastern Brazil. Results show slight but significant variations in calcium carbonate, total sulphur and nitrogen contents as well as carbon and oxygen isotope ratios. Sedimentation rates, varying from 5 to 184 mm kyr⁻¹ are controlled by the shelf and upper slope morphology, the Brazil Current meander dynamics, and the Coastal Water offshore motion.     

How to evaluate the quality of coarse‐resolution DEM‐derived drainage networks

The quality of digital elevation model (DEM)‐derived river drainage networks (RDNs) is influenced by DEM quality, basin physical characteristics, scale, and algorithms used; these factors should not be neglected. However, few research studies analyse the different evaluation approaches used in the literature with respect to adequacy, meaning of the results, advantages, and limitations. Focusing on coarse‐resolution networks, this paper reviews the use of these techniques and offers new insights on these issues. Additionally, we propose adaptations for selected metrics and discuss distinct interpretations for the evaluation of RDNs derived at different spatial resolutions (1, 5, 10, 20, and 30 km) considering the Uruguay River basin (206,000 km²) as a case study. The results demonstrate that lumped basin/river characteristics and basin delineation analysis should not be used as evaluation criteria for RDN quality; however, some of these metrics offer useful complementary information. Percentage of the DEM‐derived RDN within a uniform buffer placed around a river network considered as reference and mean separation distance between these two networks are more suitable metrics, but the former is insensitive to serious errors. The change in reference from a fine‐scale network to a coarse‐resolution manual tracing network significantly augments the discrepancy of these largest errors when the mean distance metric was applied, and visual comparison analysis is necessary to interpret the results for other metrics. We recommend the use of the mean distance metric in combination with a detailed visual assessment, the importance of which increases as the resolution coarsens. In both cases, the impact of network quality can be further refined by quantifying the basin shape and river length errors.     

Tidal variation in a rocky inter‐tidal fish population: the case of white seabream Diplodus sargus juveniles

The rocky inter‐tidal habitat is a harsh and fluctuating environment, subject to frequent disturbances. Field observations of juvenile white seabream Diplodus sargus in inter‐tidal rocky habitats were conducted to analyse the spatial distribution and feeding activity of this species in relation to the tidal cycle. The depth at which fish were observed did not change in most tidal phases while feeding activity changed with tidal level, showing the occurrence of tidal migrations and that feeding may be limited by habitat availability in shallow waters and thus be dependent on tidal changes. The present results show the exploitation of available feeding areas in the rocky inter‐tidal by juvenile white seabream, which corroborates the importance of these habitats for the first developmental stages of this fish species.     

Spatio-temporal patterns of coral recruitment at Vamizi Island,Quirimbas Archipelago,Mozambique

Spatial and temporal patterns of recruitment of reef corals were assessed for the first time in Mozambique by deploying settlement plates at various spatio-temporal scales between October 2012 and October 2013. The abundance of juvenile corals (5?50?mm in diameter) was assessed along transects. Settlement of acroporids was highly seasonal, with 97% of spat settling between July and October 2013. Pocilloporids settled throughout the year, peaking slightly between October 2012 and January 2013. The annual mean larval settlement of up to 1 135 spat m^?2 was comparable to that on other East African reefs, but was dominated by acroporids, which constituted over 80% of all spat, whereas pocilloporids settle in higher densities in Kenya and South Africa. The peak settlement season also differed from other African locations. A greater proportion of variance in settlement rates occurred at the spatial scale of kilometres (between sites) and centimetres (between settlement plates) than at the scale of metres (between subsites), implying that most patchiness occurs at those scales. The peak in acroporid settlement coincided with the period of multispecific spawning, with settlement occurring as early as nine days after a spawning event. As no similar spawning events have been reported for other reefs in the area, our results suggest that these spawning events strongly influence overall annual settlement rates and promote high levels of self-seeding at Vamizi. There was no relationship between settlement of larvae to settlement plates and juvenile density on adjacent reefs, suggesting either variable levels of early post-settlement mortality or high interannual variability in settlement.     

Soil geochemical prospecting for gold at Marrancos (Northern Portugual)

This paper discusses some geochemical mapping techniques and their effectiveness in detecting of gold and its pathfinder's geochemical anomalies. The study area (Marrancos area) is situated in Northern Portugal. Gold occurs in a quartz breccia with pyrite and arsenopyrite hosted by metamorphic rocks (hornfels) and it is present in these two sulphide minerals as inclusions or disseminated in the crystal lattice. In this area, the geochemical anomalies obtained by isoconcentration mapping of single elements were difficult to interpret. The use of alternative geochemical mapping such as multielement halos (additive halos) proved to be effective in the definition of Au, As, Bi, Sb, Te and Se secondary geochemical signature.     

Water budget and vertical conductance for Lowry (Sand Hill) Lake in north-central Florida, USA

Water-budget components and the vertical conductance were determined for Lowry (Sand Hill) Lake in north-central Florida, USA. In this type of lake, which interacts with both the surface-water and groundwater systems, the inflow components are precipitation, surface-water inflow, groundwater inflow, and direct runoff (i.e. overland flow), and the outflow components are evaporation, groundwater outflow, and surface-water outflow. In a lake and groundwater system that is typical of many karst lakes in Florida, a large part of the groundwater outflow occurs by means of vertical leakage through an underlying confining unit to a deeper, highly transmissive aquifer called the upper Floridan aquifer. The water-budget component that represents vertical leakage to the upper Floridan aquifer was calculated as a residual using the water-budget equation. For the 13 month period from August 1994 to August 1995, relative to the surface area of the lake, rainfall at Lowry Lake was 1.55 m yr⁻¹, surficial aquifer inflow was 0.79 m yr⁻¹, surface-water inflow was 1.92 m yr⁻¹, and direct runoff was 0.01 m yr⁻¹. Lake evaporation was 1.11 m yr⁻¹, and surface-water outflow was 1.61 m yr⁻¹. The lake stage increased 0.07 m yr⁻¹, and the vertical leakage to the upper Floridan aquifer was 1.48 m yr⁻¹. Surficial aquifer outflow from the lake was negligible. At Lowry Lake, vertical leakage is a major component of the water budget, comprising about 35% of the outflow during the study period. The vertical conductance (K_V/b), a coefficient that represents the average of the vertical conductances of the hydrogeologic units between the bottom of a lake and the top of the upper Floridan aquifer, was determined to be 2.51 × 10⁻⁴ day⁻¹ for Lowry Lake.