Seasonal dynamics and exports of elements from a first‐order stream to a large inland lake in Michigan

Headwater streams are critical components of drainage systems, directly connecting terrestrial and downstream aquatic ecosystems. The amount of water in a stream can alter hydrologic connectivity between the stream and surrounding landscape and is ultimately an important driver of what constituents headwater streams transport. There is a shortage of studies that explore concentration–discharge (C‐Q) relationships in headwater systems, especially forested watersheds, where the hydrological and ecological processes that control the processing and export of solutes can be directly investigated. We sought to identify the temporal dynamics and spatial patterns of stream chemistry at three points along a forested headwater stream in Northern Michigan and utilize C‐Q relationships to explore transport dynamics and potential sources of solutes in the stream. Along the stream, surface flow was seasonal in the main stem, and perennial flow was spatially discontinuous for all but the lowest reaches. Spring snowmelt was the dominant hydrological event in the year with peak flows an order of magnitude larger at the mouth and upper reaches than annual mean discharge. All three C‐Q shapes (positive, negative, and flat) were observed at all locations along the stream, with a higher proportion of the analytes showing significant relationships at the mouth than at the mid or upper flumes. At the mouth, positive (flushing) C‐Q shapes were observed for dissolved organic carbon and total suspended solids, whereas negative (dilution) C‐Q shapes were observed for most cations (Na⁺, Mg²⁺, Ca²⁺) and biologically cycled anions (NO₃^?, PO₄^3?, SO₄^2?). Most analytes displayed significant C‐Q relationships at the mouth, indicating that discharge is a significant driving factor controlling stream chemistry. However, the importance of discharge appeared to decrease moving upstream to the headwaters where more localized or temporally dynamic factors may become more important controls on stream solute patterns.     

Mapping diversified peri-urban agriculture – potential of object-based versus per-field land cover/land use classification

High spatial resolution satellite data contribute to improving land cover/land use (LCLU) classification in agriculture. A classification procedure based on Quickbird satellite image data was developed to map LCLU of diversified agriculture at sub-communal and communal level (7 km²). Segmentation performance of the panchromatic band in combination with high pass filters (HPF) was tested first. Accuracy of field boundary delineation was evaluated by an object-based segmentation, a per-field and a manual classification, along with a quantitative accuracy assessment. Sub-communal classification revealed an overall accuracy of 84% with a κ coefficient of 0.77 for the per-field vector segmentation compared to an overall accuracy of 56–60% and a κ coefficient of 0.37–0.42 for object-based approaches. Per-field vector segmentation was thus superior and used for LCLU classification at communal level. Overall accuracy scored 83% and the κ coefficient 0.7. In diversified agriculture, per-field vector segmentation and classification achieved higher classification results.     

Forest‐Cover Change from Labor‐ and Capital‐Intensive Commercial Logging in the Southern Chocó Rainforests*

This article examines two key aspects of land‐cover change in the south of the Chocó region. First, it assesses and compares the local impact on forest condition of labor‐intensive and capital‐intensive commercial logging. Second, it assesses the regional significance and permanency of these changes. Studies of land‐cover change associated with commercial logging have focused almost exclusively on capital‐intensive extraction and have assumed that after logging, degraded forests are transformed into agricultural cover. This study shows that both capital‐ and labor‐intensive logging result in similar land‐cover changes (i.e., forest degradation) if the timber sought is the same. However, labor‐intensive loggers also seek timber species not sought by capital‐intensive loggers, and this impact is statistically different from the impact of the extraction of the first group of species. Results also show that only a small fraction (20–30 percent) of the area logged is later converted to agricultural cover types. The persistence of logged forests means that up to 20 percent of the remaining forest cover could correspond to forests with significant and lasting levels of degradation. Furthermore, the different production requirements for each group of species also mean that there is a spatial differentiation in the impact of logging in the region. Logged forests are arranged into two consecutive corridors on each side of access routes (e.g., rivers). The first corridor corresponds to a narrow (approximately 1‐km) band of high‐intensity degradation. The second, broader (approximately 2‐km) forest band, with lower levels of degradation, extends inland along first‐tier corridors. A key factor determining the permanency of this land‐cover pattern is the strong control local communities have over the land in the region. This limits the spread of patterns observed in other frontier areas, especially the conversion of logged forests into agricultural cover.     

Origin of sub-lithospheric diamonds from the Juina-5 kimberlite (Brazil): constraints from carbon isotopes and inclusion compositions

Forty-one diamonds sourced from the Juina-5 kimberlite pipe in Southern Brazil, which contain optically identifiable inclusions, have been studied using an integrated approach. The diamonds contain <20 ppm nitrogen (N) that is fully aggregated as B centres. Internal structures in several diamonds revealed using cathodoluminescence (CL) are unlike those normally observed in lithospheric samples. The majority of the diamonds are composed of isotopically light carbon, and the collection has a unimodal distribution heavily skewed towards δ¹³C ~ ?25 ‰. Individual diamonds can display large carbon isotope heterogeneity of up to ~15 ‰ and predominantly have isotopically lighter cores displaying blue CL, and heavier rims with green CL. The light carbon isotopic compositions are interpreted as evidence of diamond growth from abiotic organic carbon added to the oceanic crust during hydrothermal alteration. The bulk isotopic composition of the oceanic crust, carbonates plus organics, is equal to the composition of mantle carbon (?5 ‰), and we suggest that recycling/mixing of subducted material will replenish this reservoir over geological time. Several exposed, syngenetic inclusions have bulk compositions consistent with former eclogitic magnesium silicate perovskite, calcium silicate perovskite and NAL or CF phases that have re-equilibrated during their exhumation to the surface. There are multiple occurrences of majoritic garnet with pyroxene exsolution, coesite with and without kyanite exsolution, clinopyroxene, Fe or Fe-carbide and sulphide minerals alongside single occurrences of olivine and ferropericlase. As a group, the inclusions have eclogitic affinity and provide evidence for diamond formation at pressures extending to Earth’s deep transition zone and possibly the lower mantle. It is observed that the major element composition of inclusions and isotopic compositions of host Juina-5 diamonds are not correlated. The diamond and inclusion compositions are intimately related to subducted material and record a polybaric growth history across a depth interval stretching from the lower mantle to the base of the lithosphere. It is suggested that the interaction of slab-derived melts and mantle material combined with subsequent upward transport in channelised networks or a buoyant diapir explains the formation of Juina-5 diamonds. We conclude that these samples, despite originating at great mantle depths, do not provide direct information about the ambient mantle, instead, providing a snapshot of the Earth’s deep carbon cycle.