Quantitative phosphorus measurement: A field test procedure for archaeological site analysis at Piedras Negras,Guatemala

Currently there is a wide interest in the use of chemical analyses for the evaluation of anthropogenically altered soils and other archaeological deposits. Because soil phosphorus levels increase in areas of human habitation, and leave a permanent signature that can only be removed by erosion of the soil itself, phosphorus mapping has become a popular field procedure to indicate areas of habitation where overt evidence of ancient occupance is absent. We have developed a methodology to obtain accurate acid‐extractable phosphorus concentrations (mg/kg) in calcareous soils under the primitive field conditions of Piedras Negras, Guatemala. Predicated on Mehlich‐II acid extractant and colorimetric methods, this procedure processed 36 samples per hour at very low cost per sample. Based on eight replicate measurements of a group of samples, the coefficient of variation of the procedure was 8.3%. Subsequent analysis of 35 soil samples in a controlled laboratory revealed a moderate correlation of 0.44 between the Mehlich‐extractable phosphorus and total phosphorus. The correlation was 0.91 between the Mehlich procedure and Olsen bicarbonate extractable phosphorus, indicating that Mehlich‐based results are similar to those obtainable using a traditional extractable phosphorus method on soils of neutral to alkaline pH. There was a moderate correlation between Mehlich P and ring‐test rating (r = 0.42). The wider dynamic range of the Mehlich extraction, coupled with the use of a battery‐operated colorimeter, facilitated the finding of a refuse midden within an area of phosphate enriched soils. Further tests indicated that phosphorus concentrations measured in the field deviated by only 7% from those made under controlled laboratory conditions. © 2000 John Wiley & Sons, Inc.     

A one-dimensional modeling study of the diurnal cycle in the equatorial Atlantic at the PIRATA buoys during the EGEE-3 campaign

A one-dimensional model is used to analyze, at the local scale, the response of the equatorial Atlantic Ocean under different meteorological conditions. The study was performed at the location of three moored buoys of the Pilot Research Moored Array in the Tropical Atlantic located at 10° W, 0° N; 10° W, 6° S; and 10° W, 10° S. During the EGEE-3 (Etude de la circulation océanique et de sa variabilité dans le Golfe de Guinee) campaign of May–June 2006, each buoy was visited for maintenance during 2 days. On board the ship, high-resolution atmospheric parameters were collected, as were profiles of temperature, salinity, and current. These data are used here to initialize, force, and validate a one-dimensional model in order to study the diurnal oceanic mixed-layer variability. It is shown that the diurnal variability of the sea surface temperatures is mainly driven by the solar heat flux. The diurnal response of the near-surface temperatures to daytime heating and nighttime cooling has an amplitude of a few tenths of degree. The computed diurnal heat budget experiences a net warming tendency of 31 and 27 W m⁻² at 0° N and 10° S, respectively, and a cooling tendency of 122 W m⁻² at 6° S. Both observed and simulated mixed-layer depths experience a jump between the nighttime convection phase and the well-stabilized diurnal water column. Its amplitude changes dramatically depending on the meteorological conditions occurring at the stations and reaches its maximum amplitude (~50 m) at 10° S. At 6° and 10° S, the presence of barrier layers is observed, a feature that is clearer at 10° S. Simulated turbulent kinetic energy (TKE) dissipation rates, compared to independent microstructure measurements, show that the model tracks their diurnal evolution reasonably well. It is also shown that the shear and buoyancy productions and the vertical diffusion of TKE all contribute to the supply of TKE, but the buoyancy production is the main source of TKE during the period of the simulation.     

The effect of Si on metal-silicate partitioning of siderophile elements and implications for the conditions of core formation

We have determined the liquid metal-liquid silicate partitioning of Ni, Co, Mo, W, V, Cr and Nb at 1.5 GPa/1923 K and 6 GPa/2123 K under conditions of constant silicate melt composition with variable amounts of Si in the Fe-rich metallic liquid. Partitioning of Ni, Co, Mo, W and V is sensitive to the Si content of the metal with, in all five cases, increasing Si tending to make the element more lithophile than for conditions where the metal is Si-free. In contrast, metal-silicate partitioning of Cr and Nb is, at constant silicate melt composition, insensitive to the Si content of the metal.The implications of our data are that if, as indicated by the Si isotopic composition of the silicate Earth ( [Georg et al., 2007] and [Fitoussi et al., 2009]), the core contains significant amounts of Si, the important siderophile elements Ni, Co, W and Mo were more lithophile during accretion and core formation than previously believed.We use our new data in conjunction with published metal-silicate partitioning results to develop a model of continuous accretion and core segregation taking explicit account of the partitioning of Si (this study) and O (from Ozawa et al., 2008) between metal and silicate and their effects on metal-silicate partitioning of siderophile elements. We find that the effect of Si on the siderophile characteristics of Ni, Co and W means that the pressures of core segregation estimated from these elements are ∼5 GPa lower than those derived from experiments in which the metal contained negligible Si (e.g., Wade and Wood, 2005). The core-mantle partitioning of Cr and Nb requires that most of Earth accretion took place under conditions which were much more reducing than those implied by the current FeO content of the mantle and that the oxidation took place late in the accretionary process. Paths of terrestrial accretion, oxidation state and partitioning which are consistent with the current mantle contents of Ni, Co, W, V, Cr and Nb lead to Si and O contents of the core of ∼4.3 wt.% and 0.15%, respectively.     

Determining policy-efficient management strategies in fisheries using data envelopment analysis (DEA)

In this paper, the authors analyze a wide range of recreational management strategies for their impacts on red snapper yield, economic surplus and the fish stock. Simulating a wide range of policies, the authors find Data Envelopment Analysis (DEA) inspired policy efficiency frontiers that lead to finding those management strategies that offer the greatest level of economic surplus for any biological target, looking at both the east and west Gulf of Mexico fisheries. Red snapper has been declared overfished since 1988 and the 2005 SEDAR 7 stock assessment declared red snapper were overfished and undergoing overfishing. In November 2009, the update of the assessment declared that overfishing was no longer occurring but that the red snapper stocks needed to be rebuilt. In this analysis, it was found that red snapper are neither overfished or undergoing overfishing. The main difference between the present model and the SEDAR 7 model is that the latest model uses a higher mortality rate for juveniles and a density dependent model. The authors also suggest that the east and west should be managed as separate units.     

An ecosystem approach for determining environmental water allocations in Australian dryland river systems: the role of geomorphology

The allocation of water for environmental purposes is a key management issue in many dryland regions. Many different methods have been developed for determining environmental water requirements but these are not directly applicable to dryland rivers because of inherent flow and habitat variability. An ecosystem approach for determining environmental water allocations in dryland regions is presented in this paper. This four-step process involves (1) a hierarchical characterisation of the river system, to assess what mesohabitats are present and where they are located; (2) the determination of flows that would inundate these habitats and perform other key ecological processes; (3) hydrological analyses in which the key hydrological signatures of the river are identified and the impact of water resource development on these is determined; and (4) the derivation of a water management decision tree that enables managers to allocate water to consumptive users during individual flood pulses (events). It is recommended that the flood pulse should be the focus for environmental flow management in dryland regions. If rivers are indeed nested hierarchies, then a change in hydrological behaviour at the scale of a flood pulse will, with time, extend throughout the hydrological hierarchy. Current environmental flow management strategies in dryland river systems are essentially focused at the flow regime and history scale; this is inappropriate given the inherent flow variability of these systems. The ecosystem approach is outlined for the Condamine-Balonne River, a large dryland system in Australia.     

Mafic Archean continental crust prohibited exhumation of orogenic UHP eclogite

The absence of ultrahigh pressure (UHP) orogenic eclogite in the geological record older than c. 0.6 Ga is problematic for evidence of subduction having begun o...     

Estimates of PAHs burdens in a population of ampeliscid amphipods at the head of the Mississippi Canyon (N. Gulf of Mexico)

The bioaccumulation of polycyclic aromatic hydrocarbons (PAHs) by a dense population of ampeliscid amphipods (12,094±2499 ind m⁻²) in the head of the Mississippi Canyon at a depth of 480 m is examined and compared with estimation for amphipods from a shallow-water location, the Houston Ship Channel. The distribution of individual PAHs in sediments varies from the distribution in the organisms both in deep and shallow water, suggesting preferential uptake/depuration or uptake from pore or bottom waters. The average bioaccumulation factor (4.36±2.55) and the biota sediment accumulation factor (0.24±0.13) of total PAHs by the ampeliscid amphipods at the canyon's head are within the range reported for other benthic invertebrates. The average bioaccumulation factors are highest for dibenzothiophenes (up to 132 for C1-dibenzothiophenes) and alkylated PAHs and lowest for parent high molecular weight PAHs (HPAHs). Shallow-water amphipods are similar to deep-water amphipods in showing high preference to bioaccumulate alkylated PAHs and low preference to bioaccumulate parent HPAHs.     

Carbon dioxide flux techniques performed during GasEx-98

A comprehensive study of air–sea interactions focused on improving the quantification of CO₂ fluxes and gas transfer velocities was performed within a large open ocean CO₂ sink region in the North Atlantic. This study, GasEx-98, included shipboard measurements of direct covariance CO₂ fluxes, atmospheric CO₂ profiles, atmospheric DMS profiles, water column mass balances of CO₂, and measurements of deliberate SF₆–³He tracers, along with air–sea momentum, heat, and water vapor fluxes. The large air–sea differences in partial pressure of CO₂ caused by a springtime algal bloom provided high signals for accurate CO₂ flux measurements. Measurements were performed over a wind speed range of 1–16 m s⁻¹ during the three-week process study. This first comparison between the novel air-side and more conventional water column measurements of air–sea gas transfer show a general agreement between independent air–sea gas flux techniques. These new advances in open ocean air–sea gas flux measurements demonstrate the progress in the ability to quantify air–sea CO₂ fluxes on short time scales. This capability will help improve the understanding of processes controlling the air–sea fluxes, which in turn will improve our ability to make regional and global CO₂ flux estimates.     

Petrogenesis of ca 1.50 Ga granitic gneiss of the Coompana Block: filling the ‘magmatic gap’ of Mesoproterozoic Australia

The Coompana Block is an essentially unknown basement province that separates the Gawler Craton of South Australia from the Yilgarn Craton of Western Australia. Previously unstudied granitic gneiss intersected by deep drilling in the Coompana Block represents an important period of within-plate magmatism during a time of relative magmatic quiescence in the Australian Proterozoic. Granitic gneiss intersected at ～1500 m depth in Mallabie 1 diamond drillhole is metaluminous and dominantly granodioritic in composition. The granodiorites have distinctive A-type chemistry characterised by high contents of Zr, Nb, Y, Ga, LREE with low Mg#, Sr, CaO and HREE. U – Pb LA-ICPMS dating of magmatic zircons provides an age of 1505 ± 7 Ma, interpreted as the crystallisation age of the granite protolith. ? _Nd values are high with respect to exposed crust of the Musgrave Province and Gawler Craton, and range from +1.2 to +3.3 at 1.5 Ga. The granitic gneiss is interpreted to be a fractionated melt of a mantle-derived parental melt. The tectonic environment into which the precursor granite was emplaced is not clear. One possibility is emplacement within an extensional environment. Regardless, the granitic gneiss intersected in Mallabie 1 represents magmatic activity during the ‘Australian Mesoproterozoic magmatic gap’ of ca 1.50 – 1.35 Ga, and is a possible source for ca 1.50 detrital zircons found in sedimentary rocks of Tasmania and Antarctica, and metasedimentary rocks of the eastern Musgrave Province.