Organic carbon stable isotope ratios of continental margin sediments

Stable isotope ratios (δ¹³C) of total organic carbon were measured in surface sediments from the continental margins of the northern and western Gulf of Mexico, the north coast of Alaska and the Niger Delta. Gulf of Mexico outer-shelf isotope ratios were in the same range as has been reported for Atlantic coastal shelf sediments, ?21.5 to ?20‰. Off large rivers including the Mississippi, Niger and Atchafalaya (Louisiana), δ¹³C values increased from terrigenous-influenced (around ?24‰) to typically marine ($\text{～?20‰}$) within a few tens of kilometers from shore. This change was accompanied by a decrease in the amount of woody terrigenous plant remains in the sediment. Alaskan continental margin samples from the cold Beaufort Sea had isotopically more negative carbon (?25.5 to ?22.6‰) than did warmer-water sediments. The data indicate that the bulk of organic carbon in Recent sediments from nearshore to outer continental shelves is marine derived.     

Observation of corer penetration and sample entry during gravity coring

Gravity core samples provide the basic data source for a wide range of geological, geotechnical and geochemical studies. However, the length of the core recovered is often less than the penetration achieved by the corer, such cores being described as shortened. If the penetration of the corer has been measured, and it is assumed that no dropout of the core occurs as the barrel is withdrawn from the seabed, it is present practice to reconstruct in situ dimensions using an overall correction factor based on this penetration and the length of core recovered. However, measurements, reported here, have been made of corer penetration and sample entry and these show that the entry deficit (penetration minus sample entry) develops in some instances continuously, and in others intermittently. These results indicate that an overall correction factor is unlikely to be appropriate to any given section of the core.     

Mixed deposits of complex magmatic and phreatomagmatic volcanism: an example from Crater Hill,Auckland, New Zealand

 A series of alternating phreatomagmatic ("wet") and magmatic ("dry") basaltic pyroclastic deposits forming the Crater Hill tuff ring in New Zealand contains one unit (M1) which can only be interpreted as the products of mixing of ejecta from simultaneous wet and dry explosions at different portions of a multiple vent system. The principal characteristics of M1 are (a) rapid lateral changes in the thicknesses of, and proportions in juvenile components in individual beds, and (b) wide ranges of juvenile clast densities in every sample. M1 appears to have been associated with an elongate source of highly variable and fluctuating magma : water ratios and magma discharge rates. This contrasts with the only other documented mixed (wet and dry) basaltic pyroclastic deposits where mixing from two point sources of quite different but stable character has been inferred. Received: July 11, 1995 / Accepted: February 13, 1996     

Modeling Solar UV Variations Using Mount Wilson Observatory Indices

Understanding the magnitude and temporal structure of variations in solar ultraviolet and extreme ultraviolet irradiance is critical to understanding solar forcing of the Earth's upper and middle atmosphere and hence to assessing the relative impact of natural and anthropogenic influences on Earth's atmospheric environment. Satellite based measurements of such variations are limited to recent times, are short in duration and subject to gaps making necessary ground-based surrogates with longer and more continuous coverage. Using indices derived from synoptic solar magnetograms taken at the Mount Wilson 150-foot solar tower, we have constructed models of several UV and near EUV lines and fluxes which correlate strongly (r > 0.90) with satellite data. These lines and fluxes include the Mgii h and k core-to-wing ratio, the Lα line and the 200–205 nm flux.     

β Cephei type variability in the ultraviolet spectrum and radial velocity of PHL 346

International Ultraviolet Explorer low-resolution and optical moderate-resolution spectra are presented for the high galactic latitude β Cephei type star, PHL 346. Variability is identified in both the ultraviolet flux and the radial velocity with periods and phases consistent with those previously deduced from optical photometry. The similarity of both the flux and the radial velocity amplitude to those previously reported for the β Cephei variable, γ Pegasus, is striking and provides evidence for PHL 346 being a young core hydrogen burning star. A distance estimate for PHL 346 of approximately 7 kpc (corresponding to a z -distance of approximately 6 kpc) is obtained by scaling the distance of γ Pegasus obtained from Hipparcos observations.     

Comparison of Fiberglass and Other Polymeric Well Casings Part II. Sorption and Leaching of Trace-Level Organics

This paper contains the results of a laboratory study that was designed to compare sorption of low (mg/L) concentrations of 11 organic solutes by six polymeric materials (acrylonitrile butadiene styrene [ABS], fluorinated ethylene propylene [FEP], fiberglass-reinforced epoxy [FRE] and fiberglass-reinforced plastic [FRP], polyvinyl chloride [PVC], and poly-tetrafluoroethylene [PTFE]).
During this six-week study, ABS sorbed analytes much more rapidly and to a greater extent than did the other materials, and PVC and FRE sorbed analytes more slowly and to a lesser extent than the other materials tested.
As the study progressed, an increasing number of spurious peaks were found in the high performance liquid chromatography (HPLC) chromatograms of some of our samples, indicating that leaching of some consituents had occurred. By the end of the study, there were 11 additional peaks in the ABS samples, five in the FRP samples, and one in the FRE samples. Analysis by purge and trap gas chromatography/mass spectrometry (GC/MS) of those samples and of well water samples that were exposed to the casings for 500 hours revealed the identity of some of the leached constituents; acrylonitrile and styrene (components of ABS), chloroform and ethylbenzene (an intermediate in the production of styrene) from the ABS pipe, and toluene, 1,1,1-trichloroethane, and ethylbenzene from the FRP casing.     

Heavy-metal contaminants in Tamaki Estuary: impact of city development and growth, Auckland, New Zealand

Tamaki Estuary is a large, semi-enclosed water body on the eastern side of the Auckland metropolitan area. The long and relatively narrow channel of the estuary (ca. 17 km in length) is surrounded by an urbanised and industrialised catchment. The catchment is noted for more than 600 industrial premises in addition to a range of other human activities associated with pastoral and urban land-use changes during the last 150 years. The study of seven estuary cores shows that sedimentation rates as well as the sediment coarse fraction have increased with the development of the catchment. Significant enrichments were also found for Cd, Cu, Pb, and Zn in the upper part of the cores, compared to the much lower concentrations found below 40-50 cm (considered to represent pristine background levels). Spatial association of contaminants with industrial areas and yacht anchorages, and temporal enrichments associated with the intensive urbanisation and development of the catchment since 1945 indicate that these pollutants are related to anthropogenic activities.     

Short communications a modified design for lake-seston traps and a simple method for relocating them

A modified design of seston trap is described which has been used in Brotherswater, U.K. (Ordnance Survey NY 40 12). The trap was designed to collect larger quantities of seston than were found to collect in conventional types of seston trap. A simple concealed trap-location device is also described.     

Workshop on Indices and Indicators for Climate Extremes, Asheville, NC, USA, 3–6 June 1997 Breakout Group C: Temperature Indices for Climate Extremes

The "temperature" breakout group at the 1997 Asheville Workshop on Indicators and Indices for Climate Extremes reviewed and developed the rationale for a choice of temperature indices for monitoring changes in climate extremes, and the supporting data required. A set of basic and supplementary key indices was drawn up. The key indices are meant to be easy to interpret, be relevant to the practical concerns of policy makers and others in the public sector and provide potential inputs into the Third Assessment Review of the Intergovernmental Panel on Climate Change that is expected to report in 2001. The indices are expressed in various ways to facilitate spatial and temporal trend detection and impact analysis. There is flexibility in the number and the form of the indices identified and the choice for any particular application is subject to further analysis and prioritization. The success of this endeavor will depend on original work being done to further develop the indices and on the cooperation of organizations globally to provide the data necessary for the development and the implementation of the indices. This paper summarizes the group's recommendations.     

Land-derived organic matter in surface sediments from the Gulf of Mexico

Lignin oxidation products and ¹³C/¹²C ratios were compared as indicators of land-derived organic matter in surface sediments from the western Gulf of Mexico. Whole sediments were reacted with cupric oxide to yield phenolic oxidation products that indicated the types and relative amounts of the lignins that were present.Measurements of lignin concentration and carbon isotope abundances both indicated a sharp offshore decrease of land-derived organic matter in most areas of the western Gulf. This decrease results primarily from mixing of terrestrial and marine organic matter. The terrestrially derived material in these sediments has a lignin content similar to that of grasses and tree leaves. Flowering plants contribute most of the sedimented lignin compounds. These lignins apparently occur in the form of well-mixed plant fragments that are transported to sea by rivers and deposited primarily on the inner continental shelf.