Alkoxyquinoline O-dealkylation: A new fluorimetric assay for hydrocarbon-induced cytochrome P450 in fish

The O-dealkylation of a new series of substrates, the alkoxyquinolines, provides a new easy fluorimetric assay for measuring the induction of cytochrome P450 by polycyclic aromatic hydrocarbons and drilling mud oil in fish. Expression of the results as a ratio between the inducible butyloxyquinoline O-dealkylation (BuQOD) activity and the non-inducible benzyloxyquinoline O-dealkylation (BeQOD) activity (i.e. the ‘BuQOD:-BeQOD quotient’) maximises the degree of induction measured and minimises the degree of inter-animal variation.     

Late Pleistocene glaciers in Darhad Basin, northern Mongolia

Late Pleistocene glaciers around Darhad Basin advanced to near their maximum positions at least three times, twice during the Zyrianka glaciation (at ∼ 17-19 ka and ∼ 35-53 ka), and at least once earlier. The Zyrianka glaciers were smaller than their predecessors, but the equilibrium-line altitude (ELA) difference was < 75 m. End moraines of the Zyrianka glaciers were ∼ 1600 m asl; ELAs were 2100-2400 m asl. ¹⁴C and luminescence dating of lake sediments confirm the existence of paleolake highstands in Darhad Basin before ∼ 35 ka. Geologic evidence and ¹⁰Be cosmic-ray exposure dating of drift suggests that at ∼ 17-19 ka the basin was filled at least briefly by a glacier-dammed lake ∼ 140 m deep. However, lake sediments from that time have not yet been recognized in the region. A shallower paleolake briefly occupied the basin at ∼ 11 ka, but between ∼ 11 and 17 ka and after ∼ 10 ka the basin was probably largely dry. The timing of maximum glacier advances in Darhad appears to be approximately synchronous across northern Mongolia, but different from Siberia and western Central Asia, supporting the inference that paleoclimate in Central Asia differed among regions.     

Woodcutters goldfield: Gold in an Archaean granite,Kalgoorlie, Western Australia

The 43 t (1.4 Moz) of gold in the Woodcutters goldfield 50 km north of Kalgoorlie has wide geological significance in terms of gold in Archaean granite, as well as its local commercial and exploration significance. Woodcutters is already one of the largest Archaean gold systems in granite, and is unusual in being so far laterally from the nearest greenstone belt. Gold in the Federal zone, one of the deposits making up the Woodcutters goldfield, is hosted in hornblende‐biotite granodiorite,6 km from the mapped contact with greenstone. In Federal open pit, the granodiorite is coarse‐grained in the northern half, and a fine‐grained granodiorite in the south, with both hosting gold. These two types of granodiorite are rather similar in both mineralogy and geochemistry. There is also a subordinate fine‐grained monzodiorite. The Federal gold mineralisation is in a northwest‐striking, northeast‐dipping (315° strike/60°E dip) shear zone in the Scotia granite. Variation in grainsize of the host rocks might have affected the style of deformation with more brittle fabrics in the coarse‐grained phase and more ductile fabrics prominent in the fine‐grained granodiorite. Hydrothermal alteration is extensively developed around the Federal deposit and is a useful vector towards gold mineralisation. Distal epidote alteration surrounds a proximal muscovite‐biotite alteration zone that contains quartz‐sulfide veins. The alteration shares some of the common alteration characteristics of Archaean greenstone‐hosted gold, but differs in that carbonate‐chlorite alteration is only weakly developed. This difference is readily explained in terms of host‐rock composition and lower concentrations of Fe, Mg and Ca in the granite compared with greenstone. Fluid‐inclusion studies demonstrate that the fluids associated with the hydrothermal alteration at Woodcutters shared the common characteristics of fluids in Archaean greenstone gold, namely low‐salinity and dominant H₂O–CO₂. Fluid inclusions with moderate salinity were found in one fresh sample away from mineralisation, and are inferred to represent possible magmatic fluid. There is no evidence of a granite‐derived fluid being responsible for gold mineralisation. The granodiorite host rock had cooled, crystallised and had at least started to undergo deformation prior to gold introduction. The distribution of gold mineralisation in the Woodcutters goldfield has the style, shape and orientation comparable with greenstone‐hosted gold deposits in the same region. The northwest trend, the quartz veining and simple pyrite mineralogy are all features common to other greenstone‐hosted gold deposits near Kalgoorlie such as Mt Pleasant. The alteration fluid appears to have penetrated the granite on the scale of many hundreds of metres, causing large‐scale alteration. Woodcutters gold mineralisation resulted from the same metamorphic fluid processes that led to formation of greenstone gold deposits. In this metamorphic model, granitic rocks are predicted to be less‐favourable gold hosts than mafic rocks for two reasons. Granitic rocks do not generally fracture during regional deformation in such a way as to create large‐scale dilation. Furthermore, with less iron and no carbon, granitic rocks have lower potential to precipitate gold from solution by wall‐rock reaction. The metamorphic model predicts that those granite types with higher Fe should host better gold deposits, all other factors being equal. Accordingly, tonalite‐trondhjemite and hornblende‐bearing granodiorite should provide better environments for major gold deposits compared with monzogranite, and granite sensu stricto, as borne out by Woodcutters, but mafic rocks should be better hosts than any of these felsic to intermediate rocks.     

Reconnaissance dating: A new radiocarbon method applied to assessing the temporal distribution of Southern Ocean deep-sea corals

We have developed a rapid ‘reconnaissance’ method of preparing graphite for ¹⁴C/¹²C analysis. Carbonate (～15 mg) is combusted using an elemental analyzer and the resulting CO₂ is converted to graphite using a sealed tube zinc reduction method. Over 85% (n=45 replicates on twenty-one individual corals) of reconnaissance ages measured on corals ranging in age from 500 to 33,000 radiocarbon years (Ryr) are within two standard deviations of ages generated using standard hydrolysis methods on the same corals, and all reconnaissance ages are within 300 Ryr of the standard hydrolysis ages. Replicate measurements on three individual aragonitic corals yielded ages of 1076±35 Ryr (standard deviation; n=5), 10,739±47 Ryr (n=8), and 40,146±3500 Ryr (n=9). No systematic biases were found using different cleaning methods or variable sample sizes. Analysis of ¹³C/¹²C was made concurrently with the ¹⁴C/¹²C measurement to correct for natural fractionation and for fractionation during sample processing and analysis. This technique provides a new, rapid method for making accurate, percent-level ¹⁴C/¹²C analyses that may be used to establish the rates and chronology of earth system processes where survey-type modes of age estimation are desirable. For example, applications may include creation of sediment core-top maps, preliminary age models for sediment cores, and growth rate studies of marine organisms such as corals or mollusks. We applied the reconnaissance method to more than 100 solitary deep-sea corals collected in the Drake Passage in the Southern Ocean to investigate their temporal and spatial distribution. The corals used in this study are part of a larger sample set, and the subset that was dated was chosen based on species as opposed to preservation state, so as to exclude obvious temporal biases. Similar to studies in other regions, the distribution of deep-sea corals is not constant through time across the Drake Passage. Most of the corals from the Burdwood Bank (continental shelf of Argentina) have ages ranging between 0 and 2500 calendar years, whereas most of the corals from the Sars Seamount in the Drake Passage have ages between 10,000 and 12,500 calendar years. Such differences may be caused in part by sampling biases, but may also be caused by changes in larval transport, nutrient supply, or other environmental pressures.     

准噶尔盆地南缘新生代构造特征及其与砂岩型铀矿成矿作用初析

准噶尔盆地南缘盆山结合部中新生界沉积巨厚,新生代变形强烈,是研究新盆山耦合的理想场所,也是我国砂岩型铀矿找矿的远景区段。本文在综合前人资料和野外观测分析基础上,根据新生代构造活动特征,将准噶尔盆地南缘划分为博格达山前和西部断褶带两个构造分区,博格达山前以强烈的逆冲推覆为特征,发育多条活动的逆冲推覆断裂; 乌鲁木齐以西至乌苏南的西部断褶带则发育三-四排的褶皱-逆冲断裂构造带。对采自博格达山前逆冲推覆断裂带内的方解石和断层泥,利用电子自旋共振测年手段,推测博格达山前的富康-吉木萨尔断裂带和北三台断裂带分别在0.7~1Ma和0.25Ma期间,经历了一期重要的逆冲推覆作用。结合盆地南缘砂岩型铀矿的展布规律及其成矿条件的分析,探讨了新生代构造运动对砂岩型铀矿成矿的控制作用,认为西部断褶带的第一排构造带具有较好的成矿前景,而博格达山前由于新生代构造活动强烈而相对成矿不利,为此提出了准噶尔盆地南缘砂岩型铀矿成矿“构造优先权”的构造控矿模式,进而指出了区域找矿的优选区段。     

A retrospective analysis of pan Arctic permafrost using the JULES land surface model

There is mounting evidence that permafrost degradation has occurred over the past century. However, the amount of permafrost lost is uncertain because permafrost is not readily observable over long time periods and large scales. This paper uses JULES, the land surface component of the Hadley Centre global climate model, driven by different realisations of twentieth century meteorology to estimate the pan-arctic changes in near-surface permafrost. Model simulations of permafrost are strongly dependent on the amount of snow both in the driving meteorology and the way it is treated once it reaches the ground. The multi-layer snow scheme recently adopted by JULES significantly improves its estimates of soil temperatures and permafrost extent. Therefore JULES, despite still having a small cold bias in soil temperatures, can now simulate a near-surface permafrost extent which is comparable to that observed. Changes in snow cover have been shown to contribute to changes in permafrost and JULES simulates a significant decrease in late twentieth century pan-Arctic spring snow cover extent. In addition, large-scale modelled changes in the active layer are comparable with those observed over northern Russia. Simulations over the period 1967–2000 show a significant loss of near-surface permafrost—between 0.55 and 0.81 million km² per decade with this spread caused by differences in the driving meteorology. These runs also show that, for the grid cells where the active layer has increased significantly, the mean increase is ~10 cm per decade. The permafrost degradation discussed here is mainly caused by an increase in the active layer thickness driven by changes in the large scale atmospheric forcing. However, other processes such as thermokarst development and river and coastal erosion may also occur enhancing permafrost loss.     

Hydrogeophysical Methods for Analyzing Aquifer Storage and Recovery Systems

Hydrogeophysical methods are presented that support the siting and monitoring of aquifer storage and recovery (ASR) systems. These methods are presented as numerical simulations in the context of a proposed ASR experiment in Kuwait, although the techniques are applicable to numerous ASR projects. Bulk geophysical properties are calculated directly from ASR flow and solute transport simulations using standard petrophysical relationships and are used to simulate the dynamic geophysical response to ASR. This strategy provides a quantitative framework for determining site‐specific geophysical methods and data acquisition geometries that can provide the most useful information about the ASR implementation. An axisymmetric, coupled fluid flow and solute transport model simulates injection, storage, and withdrawal of fresh water (salinity ～500 ppm) into the Dammam aquifer, a tertiary carbonate formation with native salinity approximately 6000 ppm. Sensitivity of the flow simulations to the correlation length of aquifer heterogeneity, aquifer dispersivity, and hydraulic permeability of the confining layer are investigated. The geophysical response using electrical resistivity, time‐domain electromagnetic (TEM), and seismic methods is computed at regular intervals during the ASR simulation to investigate the sensitivity of these different techniques to changes in subsurface properties. For the electrical and electromagnetic methods, fluid electric conductivity is derived from the modeled salinity and is combined with an assumed porosity model to compute a bulk electrical resistivity structure. The seismic response is computed from the porosity model and changes in effective stress due to fluid pressure variations during injection/recovery, while changes in fluid properties are introduced through Gassmann fluid substitution.     

Climate,conflict, and social stability: what does the evidence say?

Are violent conflict and socio-political stability associated with changes in climatological variables? We examine 50 rigorous quantitative studies on this question and find consistent support for a causal association between climatological changes and various conflict outcomes, at spatial scales ranging from individual buildings to the entire globe and at temporal scales ranging from an anomalous hour to an anomalous millennium. Multiple mechanisms that could explain this association have been proposed and are sometimes supported by findings, but the literature is currently unable to decisively exclude any proposed pathway. Several mechanisms likely contribute to the outcomes that we observe.     

Shifts in African crop climates by 2050, and the implications for crop improvement and genetic resources conservation

Increased understanding of the substantial threat climate change poses to agriculture has not been met with a similarly improved understanding of how best to respond. Here we examine likely shifts in crop climates in Sub-Saharan Africa under climate change to 2050, and explore the implications for agricultural adaptation, with particular focus on identifying priorities in crop breeding and the conservation of crop genetic resources. We find that for three of Africa's primary cereal crops – maize, millet, and sorghum – expected changes in growing season temperature are considerable and dwarf changes projected for precipitation, with the warmest recent temperatures on average cooler than almost 9 out of 10 expected observations by 2050. For the “novel” crop climates currently unrepresented in each country but likely extant there in 2050, we identify current analogs across the continent. The majority of African countries will have novel climates over at least half of their current crop area by 2050. Of these countries, 75% will have novel climates with analogs in the current climate of at least five other countries, suggesting that international movement of germplasm will be necessary for adaptation. A more troubling set of countries – largely the hotter Sahelian countries – will have climates with few analogs for any crop. Finally, we identify countries, such as Sudan, Cameroon, and Nigeria, whose current crop areas are analogs to many future climates but that are poorly represented in major genebanks – promising locations in which to focus future genetic resource conservation efforts.