Weathering the escarpment: chemical and physical rates and processes,south‐eastern Australia

Differences in chemical weathering extent and character are expected to exist across topographic escarpments due to spatial gradients of climatic and/or tectonic forcing. The passive margin escarpment of south‐eastern Australia has a debated but generally accepted model of propagation in which it retreated (within 40 Ma) to near its current position following rifting between Australia and New Zealand 85–100 Ma before present. We focus on this escarpment to quantify chemical weathering rates and processes and how they may provide insight into scarp evolution and retreat. We compare chemical weathering extents and rates above and below the escarpment using a mass balance approach coupling major and trace element analyses with previous measurements of denudation rates using cosmogenic nuclides (¹⁰Be and ²⁶Al). We find a slight gradient in saprolite chemical weathering rate as a percentage of total weathering rate across the escarpment. The lowlands area, encompassing the region extending from the base of the escarpment to the coast, experiences a greater extent of chemical weathering than the highland region above the escarpment. Percents of denudation attributable to saprolite weathering average 57 ± 6% and 47 ± 7% at low and high sites respectively. Furthermore, the chemical index of alteration (CIA), a ratio of immobile to mobile oxides in granitic material that increases with weathering extent, have corresponding average values of 73·7 ± 3·9 and 65·5 ± 3·4, indicating lower extents of weathering above the escarpment. Finally, we quantify variations in the rates and extent of chemical weathering at the hillslope scale across the escarpment to suggest new insight into how climate differences and hillslope topography help drive landscape evolution, potentially overprinting longer term tectonic forcing. Copyright © 2009 John Wiley & Sons, Ltd.     

Impacts of El Nino-Southern Oscillation events on China＇s rice production

This paper aims to demonstrate the relationships between ENSO and rice production of Jiangxi province in order to identify the reason that ENSO might have little effect on Chinese rice production. Using a data set with measures of Jiangxi’s climate and rice production, we find the reason that during 1985 and 2004 ENSO’s well correlated with rainfall did not promote Chinese rice production. First, the largest effects of ENSO mostly occur in the months when there is no rice in the field. Second, there is almost no temperature effect. Finally, the monthly distribution of rainfall is almost the same in ENSO and neutral years because the largest effects are during months when there is the least rain. In addition, due to the high irrigation share and reliable and effective irrigation facilities of cultivated land, China’s rice production is less climate-sensitive.     

Cross-section for the dissociative photoionization of hydrogen by 584 Å radiation: The formation of protons in the Jovian ionosphere

The cross-section for dissociative photoionization of hydrogen by 584 Å radiation has been measured, yielding a value of 5 × 10^?20 cm². The process can be explained as a transition from the $\text{X}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ ground state to a continuum level of the $\text{X}{}^2\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ ionized state of H₂ The branching ratio for proton (H⁺) vs molecular ion (H₂⁺) production at this energy is 8 × 10^?3. This process is quite likely an important source of protons in the Jovian ionosphere near altitudes where peak ionization rates are found.     

Energy conversion evolution at lunar polar sites

Lunar polar environments have many advantages from the standpoint of energy supply to robotic and human surface bases. Sunlight is nearly continuous and always horizontal at peaks of perpetual light, while waste heat rejection is aided by the existence of cold, permanently shadowed regions nearby. In this paper a possible evolution of lunar polar energy systems will be described, beginning with small robotic photovoltaic landers and continuing into the development of increasingly powerful and diverse energy installations to provide not only electric power but also piped-in sunlight, air conditioning and high-temperature process heat.     

Coupling chemical weathering with soil production across soil‐mantled landscapes

Soil‐covered upland landscapes constitute a critical part of the habitable world. Our understanding of how they evolve as a function of different climatic, tectonic and geological regimes is important across a wide range of disciplines and depends, in part, on understanding the links between chemical and physical weathering processes. Extensive previous work has shown that soil production rates decrease with increasing soil column thickness, but chemical weathering rates were not measured. Here we examine a granitic, soil‐mantled hillslope at Point Reyes, California, where soil production rates were determined using in situ produced cosmogenic nuclides (¹⁰Be and ²⁶Al), and we quantify the extent as well as the rates of chemical weathering of the saprolite from beneath soil from across the landscape. We collected saprolite samples from the base of soil pits and analysed them for abrasion pH as well as for major and trace elements by X‐ray fluorescence spectroscopy, and for clay mineralogy by X‐ray diffraction spectroscopy. Our results show for the first time that chemical weathering rates decrease with increasing soil thickness and account for 13 to 51 per cent of total denudation. We also show that spatial variation in chemical weathering appears to be topographically controlled: weathering rate decreases with slope across the divergent ridge and increases with upslope contributing area in the convergent swale. Furthermore, to determine the best measure for the extent of saprolite weathering, we compared four different chemical weathering indices – the Vogt ratio, the chemical index of alteration (CIA), Parker's index, and the silicon–aluminium ratio – with saprolite pH. Measurements of the CIA were the most closely correlated with saprolite pH, showing that weathering intensity decreases linearly with an increase in saprolite pH from 4·7 to almost 7. Data presented here are among the first to couple directly rates of soil production and chemical weathering with how topography is likely to control weathering at a hillslope scale. Copyright © 2006 John Wiley & Sons, Ltd.     

The absence of memory in the climatic forcing of glaciers

Glaciers respond to both long-term, persistent climate changes as well as the year-to-year variability that is inherent to a constant climate. Distinguishing between these two causes of length change is important for identifying the true climatic cause of past glacier fluctuations. A key step in addressing this is to determine the relative importance of year-to-year variability in climate relative to more persistent climate fluctuations. We address this question for European climate using several long-term observational records: a century-long, Europe-wide atmospheric gridded dataset; longer-term instrumental measurements of summertime temperature where available (up to 250 years); and seasonal and annual records of glacier mass balance (between 30 and 50 years). After linear detrending of the datasets, we find that throughout Europe persistence in both melt-season temperature and annual accumulation is generally indistinguishable from zero. The main exception is in Southern Europe where a degree of interannual persistence can be identified in summertime temperatures. On the basis of this analysis, we conclude that year-to-year variability dominates the natural climate forcing of glacier fluctuations on timescales up to a few centuries.     

Redox-dependent removal of 27 organic trace pollutants: compilation of results from tank aeration experiments

The biodegradation of various wastewater-derived organic trace pollutants occurring in different aquatic compartments of the environment was previously reported to be influenced by the prevailing redox conditions. However, comparative studies on the redox-dependent degradation behavior of organic trace pollutants are scarce. The objective of the study presented herein, was to compile and evaluate data from several comparable previous tank experiments, thus, providing an overview on the redox-dependent removal of a total of 27 wastewater-derived trace compounds, including phenazone type compounds, antimicrobials, ß-blockers, psychoactive drugs and sulfonamides. Removal rate constants were fitted assuming first-order degradation kinetics. Six compounds were identified to be removed solely under oxic, three compounds solely under anoxic conditions. Others persisted under all experimental conditions, while some were removed under both oxic and anoxic conditions.     

Perceptions of Environmental Change and Climate Concern Among Idaho’s Farmers

Climate change public opinion research has identified conservative political ideology as the primary predictor of skepticism about climate change’s anthropogenic causes. Most farmers in Idaho are politically conservative, but they are also a unique group for whom observing their environment is part of daily life and work. We use data from in-depth interviews with 30 Idaho farmers to examine the relationship between observations of specific environmental changes and climate concern. We find that while most farmers report noticing changes in precipitation patterns, growing season length, and winter temperatures, few farmers connect these with long-term global climate change. These findings have two important implications: 1) direct experience, even in the form of disruption to an individual’s economic security, is not enough to overcome the influence of political ideology on climate change beliefs, and 2) acknowledging climate variation is not sufficient to convince individuals that the changes are produced by human activities.     

Impacts of acid emissions from Nevado del Ruiz volcano, Colombia, on selected terrestrial and aquatic ecosystems

Emissions of acidic gases and thermal waters from Nevado del Ruiz volcano have recently increased in concert with the November 13, 1985 eruption. This study examines the downwind and downstream effects of these emissions on alpine ecosystems high on the slopes of the volcano (4100 m) and on coffee plantations at lower elevations (< 2000 m) and greater distances from the active vent (> 30 km). Samples of bulk deposition, rain, soils, soil solutions, and streams were collected over a six-month period (January–July, 1987) to examine the impacts of this volcanogenic acidity.Bulk deposition falling on the higher slopes of the volcano is usually acidified; however, deposition reaching the distal coffee plantations seldom is acidic. The sources of the acids are hydrogen chloride and sulfur dioxide in the plume of the volcano. Although sulfur dioxide is by far the more abundant gas, hydrogen chloride is most responsible for acidification of rain falling on the slopes of the volcano. With distance from the vent, the chloride/sulfate ratio drops exponentially. The only major influence on regional precipitation chemistry in addition to the volcano appears to be land-use-related activities around the coffee plantations. Deposition on these areas is enriched by an order of magnitude in nitrate and base cations, compared to all other stations.Throughfall chemistry in the coffee plantations shows a dramatic response to occasional acid-rain events. A base-leaching process on coffee plant leaves is triggered by acid rain. For each equivalent of hydrogen ion in rain on the leaf surface, over 23 equivalents of potassium ion are leached from the leaf.In spite of this dramatic response by the vegetation, the plantation soils appear relatively unaffected by acidic deposition. In contrast, the alpine soils on the volcano exhibit low pHs, high sulfate and chloride concentrations in soil solutions, and high extractable sulfate concentrations. All of these factors indicate that these soils have undergone significant acid loading.While the deposition of the region is acidified by hydrogen chloride, the streams flowing off the volcano are apparently acidified by sulfuric acid in thermal waters discharging into the streams. The acidity of these streams decreases downstream, while the silica concentrations increase downstream. The composition of stream water is most influenced by thermal-water discharges as well as equilibrium dissolution of amorphous silica glass and non-equilibrium leaching of unweathered ash.The impacts of acid gases and thermal water released from the volcano appear to be restricted to ecosystems on the slope of the volcano. The only impact of Nevado del Ruiz on surrounding coffee plantations appears to be potassium leaching of coffee leaves from occasional acid-deposition events.     

The Australia Telescope 20-GHz (AT20G) Survey: the Bright Source Sample

The Australia Telescope 20-GHz (AT20G) Survey is a blind survey of the whole southern sky at 20 GHz (with follow-up observations at 4.8 and 8.6 GHz) carried out with the Australia Telescope Compact Array from 2004 to 2007.
The Bright Source Sample (BSS) is a complete flux-limited subsample of the AT20G Survey catalogue comprising 320 extragalactic     ) radio sources south of  δ=−15°  with      Jy. Of these, 218 have near simultaneous observations at 8 and 5 GHz.
In this paper we present an analysis of radio spectral properties in total intensity and polarization, size, optical identifications and redshift distribution of the BSS sources. The analysis of the spectral behaviour shows spectral curvature in most sources with spectral steepening that increases at higher frequencies (the median spectral index α, assuming   S ∝ν^α  , decreases from  α^8.6_4.8= 0.11  between 4.8 and 8.6 GHz to  α²⁰_8.6=−0.16  between 8.6 and 20 GHz), even if the sample is dominated by flat spectra sources (85 per cent of the sample has  α²⁰_8.6 > −0.5)  . The almost simultaneous spectra in total intensity and polarization allowed us a comparison of the polarized and total intensity spectra: polarized fraction slightly increases with frequency, but the shapes of the spectra have little correlation. Optical identifications provided an estimation of redshift for 186 sources with a median value of 1.20 and 0.13, respectively, for QSO and galaxies.