Mineral Chemistry of Peridotites from Paleozoic, Mesozoic and Cenozoic Lithosphere: Constraints on Mantle Evolution beneath Eastern China

Major- and trace-element data on the constituent minerals ofgarnet peridotite xenoliths hosted in early Paleozoic (457–500Ma) kimberlites and Neogene (16–18 Ma) volcanic rockswithin the North China Craton are compared with those from thepre-pilot hole of the Chinese Continental Scientific DrillingProject (CCSD-PP1) in the tectonically exhumed Triassic (220Ma) Sulu ultrahigh-pressure (UHP) terrane along its southernmargin. P–T estimates for the Paleozoic and Neogene peridotitexenoliths reflect different model geotherms corresponding tosurface heat flows of 40 mW/m² (Paleozoic) and 80 mW/m² (Neogene).Garnet peridotite xenoliths or xenocrysts from the Paleozoickimberlites are strongly depleted, similar to peridotites fromother areas of cratonic mantle, with magnesium olivine (meanFo_92.7), Cr-rich garnet and clinopyroxene with high La/Yb. Garnet(and spinel) peridotite xenoliths hosted in Neogene basaltsare derived from fertile mantle; they have high Al₂O₃ and TiO₂contents, low-Mg-number olivine (mean Fo_89.5), low-Cr garnetand diopside with flat rare earth element (REE) patterns. Thedifferences between the Paleozoic and Neogene xenoliths suggestthat a buoyant refractory lithospheric keel present beneaththe eastern North China Craton in Paleozoic times was at leastpartly replaced by younger, hotter and more fertile lithosphericmantle during Mesozoic–Cenozoic times. Garnet peridotitesfrom the Sulu UHP terrane have less magnesian olivine (Fo_91.5),and lower-Cr garnet than the Paleozoic xenoliths. The diopsideshave low heavy REE (HREE) contents and sinusoidal to light REE(LREE)-enriched REE patterns. These features, and their highMg/Si and low CaO and Al₂O₃ contents, indicate that the CCSD-PP1peridotites represent a moderately refractory mantle protolith.Details of mineral chemistry indicate that this protolith experiencedcomplex metasomatism by asthenosphere-derived melts or fluidsin Mesoproterozoic, and subsolidus re-equilibration involvingfluids/melts derived from the subducted Yangtze continentalcrust during UHP metamorphism in the early Mesozoic. Tectonicextension of the subcontinental lithospheric mantle of the NorthChina Craton and exhumation of the Sulu UHP rocks in the earlyMesozoic induced upwelling of the asthenosphere. Peridotitessampled by the Neogene basalts represent newly formed lithospherederived by cooling of the upwelling asthenospheric mantle inJurassic–Cretaceous and Paleogene time. KEY WORDS: garnet peridotite xenoliths; North China Craton; lithospheric thinning; Sulu UHP terrane; UHP lithosphere evolution; mantle replacement     

The isotopic composition of strontium in non-marine carbonate rocks: the Flagstaff Formation of Utah*

The isotopic composition of strontium in surface water in continental basins is determined primarily by the geology of the basin and to a lesser extent by climatic conditions. Consequently, the ⁸⁷Sr/⁸⁶Sr ratios of brines in such basins can change only as a result of changes in the geology or climate. This principle of isotope geology was studied by analysis of a suite of non-marine carbonate rocks from the Flagstaff Formation (Palaeocene-Eocene) of Utah. The samples were collected from a section in Fairview Canyon of Sanpete County. They include both limestone and dolomite and were selected to have low non-carbonate residues. The concentrations of strontium in calcites averages 383 ± 128 p.p.m., while those of dolomites increase from 354 ± 74 p.p.m. in the lower 43 m of section to a maximum of 2259 p.p.m. higher up. The increase in the strontium content of dolomite is interpreted as evidence for a change from steady-state to progressively more evaporitic conditions. Two dolomites have isotopic compositions of oxygen expressed as δ¹⁸O = -2.75‰ (relative to the PDB standard) and are enriched in ¹⁸O relative to two calcites whose average δ¹⁸O value is -9.9‰. The ⁸⁷Sr/⁸⁶Sr ratios of the carbonate minerals range from 0.70890 to 0.71260. These values are clearly greater than the ⁸⁷Sr/⁸⁶Sr ratio of marine carbonates of Early Eocene age which is 0.70744. The variation of the ⁸⁷Sr/⁸⁶Sr ratio in this section of the Flagstaff Formation is real and reflects the occurrence of geological events which changed the isotopic composition of Sr entering Lake Flagstaff. The non-carbonate fractions of six carbonate rocks and one sandstone fit a straight line on the strontium mixing diagram in co-ordinates of initial ⁸⁷Sr/⁸⁶Sr and 1/Sr concentration. These results suggest that the isotopic composition of strontium in Lake Flagstaff may have been modulated by periodic input of volcanogenic detritus of felsic composition.     

WATER MANAGEMENT—A GENERAL REPORT

Abstract

This analysis was undertaken to develop appropriate extreme flood design criteria for a nuclear power plant at Halileh, near Bushehr, Iran, adjacent to the Persian Gulf. Graphical relationships presented provide a convenient means of estimating the probable maximum precipitation and the 2- to 100-year return period rainfall events with durations from 5 min to 24 h. The relationships may be applied for drainage areas up to 25 km². Probable maximum precipitation and 2- to 100-year return period rainfall events were estimated. Precipitation depth-duration relationships were derived.     

Shallow erosion beneath turbidity currents and its impact on the architectural development of turbidite sheet systems

Erosion by turbidity currents changes the morphology of the sea floor. The relief of the scoured surface may affect the dynamics of the flow and thereby the pattern of deposition; this could, in turn, affect flow and deposition patterns in subsequent events. This study investigates shallow, centimetre to decimetre scale erosion beneath turbidite sheet sandstones of the Oligocene Macigno Formation of North‐west Italy, where erosion and deposition are variably coupled at the bed scale in a net‐aggradational setting. The research focus was on: (i) the recognition of scour edges and erosive surfaces; (ii) quantification of spatial differences in the amount of erosion; and (iii) an investigation of how this differential erosion can be compensated by the deposits directly overlying the erosional surfaces. Where they can be observed, scour edges commonly have sills of the overlying sandstone intruding beneath blocks and wings of the substrate that is being eroded. A consequence of this de‐laminating scouring style is that erosional surfaces are bedding parallel when followed away from the scour edges, giving the appearance of normal conformable bed bases. Despite their cryptic nature, such bedding‐parallel scour surfaces can be recognized by comparing serial detailed sedimentary logs (here, 16 bed‐parallel scour surfaces were identified in a succession comprising 95 beds). Different styles of compensation by the overlying turbidite beds are defined based on differential sedimentation inside and outside of the scour relief. It is found that differential erosion is on average under‐compensated by differential sedimentation. In some cases, the overlying deposits anti‐compensate, being thinner at the location where more erosion has occurred. Unequal spatial distribution of differential erosion in the study area combines with sedimentary under‐compensation to result in a trend of accumulating section thickness differences over multiple beds. In one ca 25 m thick package, the maximum cumulative change in lateral gradient during some 20 events reached 0·17°, before being reset by a single event. This process can be interpreted either as a lobe compensation effect, or as a scour enhancement effect, depending on the orientation of the palaeohorizontal datum. If allowed to proceed, the latter process could force the system past a channellization threshold, prompting a change from sheet to channelled architecture. This type of shallow substrate scouring and differential deposition is likely to be an important process in the build‐up of sheet turbidite sandstone units and could play a major role in autocyclic adjustment of local sea‐floor gradients.     

Calcium and magnesium‐limited dolomite precipitation at Deep Springs Lake,California

Dolomite [Ca,Mg(CO₃)₂] precipitation from supersaturated ionic solutions at Earth surface temperatures is considered kinetically inhibited because of the difficulties experienced in experimentally reproducing such a process. Nevertheless, recent dolomite is observed to form in hypersaline and alkaline environments. Such recent dolomite precipitation is commonly attributed to microbial mediation because dolomite has been demonstrated to form in vitro in microbial cultures. The mechanism of microbially mediated dolomite precipitation is, however, poorly understood and it remains unclear what role microbial mediation plays in natural environments. In the study presented here, simple geochemical methods were used to assess the limitations and controls of dolomite formation in Deep Springs Lake, a highly alkaline playa lake in eastern California showing ongoing dolomite authigenesis. The sediments of Deep Springs Lake consist of unlithified, clay‐fraction dolomite ooze. Based on δ¹⁸O equilibria and textural observations, dolomite precipitates from oxygenated and agitated surface brine. The Na‐SO₄‐dominated brine contains up to 500 mm dissolved inorganic carbon whereas Mg²⁺ and Ca²⁺ concentrations are ca 1 and 0·3 mm , respectively. Precipitation in the subsurface probably is not significant because of the lack of Ca²⁺ (below 0·01 mm ). Under such highly alkaline conditions, the effect of microbial metabolism on supersaturation by pH and alkalinity increase is negligible. A putative microbial effect could, however, support dolomite nucleation or support crystal growth by overcoming a kinetic barrier. An essential limitation on crystal growth rates imposed by the low Ca²⁺ and Mg²⁺ concentrations could favour the thermodynamically more stable carbonate phase (which is dolomite) to precipitate. This mode of unlithified dolomite ooze formation showing δ¹³C values near to equilibrium with atmospheric CO₂ (ca 3‰) contrasts the formation of isotopically light (organically derived), hard‐lithified dolomite layers in the subsurface of some less alkaline environments. Inferred physicochemical controls on dolomite formation under highly alkaline conditions observed in Deep Springs Lake may shed light on conditions that favoured extensive dolomite formation in alkaline Precambrian oceans, as opposed to modern oceans where dolomites only form diagenetically in organic C‐rich sediments.     

Overgrowth Textures, Disequilibrium Zoning, and Cooling History of a Glassy Four-Pyroxene Boninite Dyke from New Caledonia

Pyroxenes in a low-Ca boninite from a dyke show remarkable growthand overgrowth textures and chemical zoning, which are usedto infer crystallization mechanisms and kinetics. The rock comprisesnearly 50 vol.% fresh glass, phenocrysts and glomerocrysts ofclinoenstatite sensu lato ({small tilde}32 vol.%), microphenocrystsof orthopyroxene and Ca-rich clinopyroxene ({small tilde}17vol.%), and microlites of amphibole and oxides ({small tilde}3vol.%). Clinoenstatite, which inverted from protoenstatite,is skeletal with glass and chrome-spinel inclusions and thinovergrowth zones of Ca-rich clinopyroxene and amphibole; thecrystals are occasionally broken. Orthopyroxene is often skeletal,sometimes slightly resorbed with the same inclusions and overgrowthzones. Ca-rich clinopyroxene and amphibole occur mainly in pyroxeneovergrowth zones. Chrome-spinel in contact with glass is overgrownby magnetite-maghemite or amphibole. The rock is andesitic witha high mg-number of 0.78, and is quartz- and strongly hypersthene-and feldspar-normative. The glass is dacitic with an mg-numberof 0.15, strongly quartz- and feldspar-normative, and rich inwater ({small tilde}5.6wt.%). Strong chemical zoning occurs in all minerals, oscillatory zoningoccurring only in clinoenstatite and orthopyroxene. The mg-numberin clinoenstatite sensu lato ranges from 0.95 (clinoenstatitesensu stricto) to 0-68 (clinohypersthene), the largest rangeso far described, and from 0.88 to 0.43 in orthopyroxene. TheWo content of the former (0.21–1.56 with rare higher values)is considerably smaller than and does not overlap that of thelatter (1.36–4.84X Wo generally increasing with Fs. Thecores of both are chromian (up to 0–018 atoms per formulaunit), and Cr falls to or below the detection limit for Fs>25.The Fs-rich zones of clinohypersthene have {small tilde}2wt%A1₂O₃ and (M6wt% TiO₂, whereas those of orthopyroxene reachnearly 10 and 04 wt. %, respectively. Ca-rich clinopyroxenevaries from pigeonite through subcalcic augite and augite toferroaugite, the outer zones reaching 12wt.% A1₂O₃ and 1–8wt% TiO₂. Amphibole is magnesio-hornblende on pyroxene or tschermakitichornblende on oxide. The relative times of nucleation, growth, partial resorption,and fracturing of the crystals were determined from the texturesand the chemistry of the overgrowths. Protoenstatite and chrome-spinelnucleated from the melt and were overgrown in places by allsucceeding minerals. Orthopyroxene nucleated mainly from themelt, whereas the other phases occur only as overgrowths. Orthopyroxenemay show weak resorption at intermediate stages. Protoenstatitecrystals were occasionally broken, the relative times beingshown by the nature of the overgrowths. Minor-element concentrationsvary strongly with the growth stage, chromium soon being usedup in the melt and aluminium and titanium being strongly concentratedin the crystals during the last stages. Plagioclase and quartzare absent because of suppression of their nucleation in a water-richmelt on rapid cooling. Crystallization probably occurred intwo main stages, an early one of moderately fast cooling atlow undercooling probably in a shallow magma chamber (correspondingto the growth of the protoenstatite phenocrysts) and a laterone over a period of less than a day of faster cooling at higherundercooling after uprise and injection into the dyke (correspondingto the fracturing of protoenstatite and growth of the microphenocrystsand microlites).     

The Oshkosh Meteorite

Abstract In the fall of 1961, fragments of an olivine-bronzite chondrite were found about 2 miles NNW of Oshkosh, Wisconsin, the total weight being 144.8 g. This paper fixes the exact location and describes the circumstances of the find.     

The Australian Wool Crisis: Farm Adjustment Pressures and Strategies

Farm adjustment has resulted from the present crisis of production within the Australian agricultural sector. Farm adjustment pressures of the wool growers of the Southern Tablelands of New South Wales are outlined. The primary management strategies adopted by the wool producers are identified. Three farm adjustment strategies were noted; extensification, diversification and expansion. Choice of farm strategy was dependent on the characteristics of both the individual farm and farmer.     

Stratigraphic base level and fluvial architecture: Ericson Sandstone (Campanian), Rock Springs Uplift, SW Wyoming, USA

The concept of stratigraphic base level, or the ratio between accommodation and sediment supply (A/S ratio), has been used to analyse the Rusty and Canyon Creek Members of the Campanian Ericson Sandstone in the Rock Springs Uplift, SW Wyoming, USA. The Ericson Sandstone was deposited under fluvial to estuarine conditions in a foreland basin setting influenced both by Sevier-style (thrust belt) tectonism and by more local, Laramide-style, foreland uplifts. The depositional setting was situated several tens to a few hundred kilometres from the nearest shoreline. Therefore, sea level change at the contemporaneous shoreline probably had little, if any, influence on the development of the sedimentary architecture. The Rusty Member shows an alternation between incised valleys filled by multi-storey estuarine channel sandstones showing palaeoflow to the south and delta plain sediments with single-storey channels with no evidence of tidal influence, which show palaeoflow to the east. This cyclicity is interpreted as recording repeated uplift of the Wind River Range to the north, causing valley incision and reduction of the A/S ratio. During quiescent periods, the A/S ratio increased allowing the valleys to fill and delta plain conditions to be subsequently re-established because of increased sediment supply from the thrust belt in the west. A regional unconformity at the base of the Canyon Creek Member truncates the Rusty Member, and represents a significant reduction of the A/S ratio caused by Laramide tectonic uplift. The Canyon Creek Member is a multi-storey, multi-lateral fluvial channel sandstone, where channel preservation and thickness increase upwards, suggesting an increase of the A/S ratio. The Canyon Creek Member channels are interpreted to have been sinuous, meandering channels from the observed sedimentary structures and fill patterns, despite their sand-rich nature. It is argued that grain size is a poor indicator of channel planform, and that there was very low preservation potential for fine material because of a relatively low A/S ratio. The top of the Canyon Creek Member is a regionally correlative surface marking an abrupt increase of the A/S ratio. This surface is termed an expansion surface, denoting an abrupt increase in accommodation. The overlying Almond Formation shows a single-storey alluvial architecture with a very high preservation of fine-grained material. An assumed correspondence in time of the Late Absaroka thrust phase in the Sevier belt to the west and the formation of the sharp top of the Canyon Creek Member suggests that the thrust phase caused a basin-wide abrupt increase of subsidence that changed the alluvial architecture. As an alternative to sequence stratigraphic nomenclature defined for strata controlled by shoreline movements, a scheme relating systems tracts and surfaces to changes in stratigraphic base level is proposed. Such a scheme is useful where correlations to shoreline strata are ambiguous or cannot be made, or where tectonics and climate are important controls.