Mo稳定同位素研究进展

随着表面热离子质谱(TIMS)和多接收器电感耦合等离子体质谱(MC-ICP-MS)的广泛应用以及同位素分析方法的改进,近10年来非传统稳定同位素(Cu、Zn、Fe、Se、Mo、Cr、Hg等)的研究得到迅速发展.其中,由于Mo同位素的分馏明显受氧化还原条件的控制,使其在指示古环境及古气候的变化方面有独特的地球化学指示意义.同时,Mo同位素在指示成矿物质来源和海洋Mo循环等方面也取得较大成果.因此,Mo同位素地球化学研究已成为国际地学领域的一个前沿和热点.本文综合前人的研究成果,结合近期自己的工作,论述了Mo同位素地球化学研究领域的一些重要进展,详细介绍了Mo同位素的化学分离、提纯和质谱分析技术,并对其应用前景进行了展望.     

西秦岭熊山沟岩体地球化学及构造环境分析

在区域地质调查及综合研究的基础上,对位于西秦岭天水东南部地区的原百花岩体进行了详细的岩石学、岩石地球化学、岩体接触关系、同位素年龄研究,从中解体出熊山沟岩体,并初步了解了该岩体的岩浆活动规律。熊山沟岩体早期岩石类型为斜长花岗岩,岩石化学成分K2O含量较低,K2O∕Na2O比值为0.33～0.42;晚期岩石类型为二长花岗岩,岩石相对富集K2O,K2O∕Na2O比值为1.01～1.43,岩石属拉斑-钙碱性系列;微量元素富集Th、Hf、Nb、Zr等元素;稀土元素以富集轻稀土,无铕负异常或铕负异常不明显为主要特征;氧同位素值较低（δ^18O为＋3.32‰）,岩石具Ⅰ型花岗岩的特征,岩浆来源于下地壳物质,形成于大陆弧构造环境。     

金沙县地质灾害及防治减灾对策

阐述了金沙县基本情况、地质灾害易发区域、分布特征及成因,针对辖区内存在的地质灾害隐患点采取一系列防治对策措施,并提出地质灾害防治的建议,以促进地质环境和经济建设的协调发展.     

海拉尔盆地贝西斜坡北部地区储层特征及影响因素分析

通过测井曲线的标准化处理及信息提取、岩心及录井岩屑观察、铸体薄片、物性分析、扫描电镜、压汞分析等技术手段,研究了海拉尔盆地贝西斜坡北部地区南屯组储层的主要岩性特征、物性特征、储集空间类型和影响因素.研究结果表明.海拉尔盆地南屯组以内陆湖相碎屑岩为主,主要包括角砾岩、砾岩、砂砾岩、粗砂岩、细砂岩、粉砂岩、泥质砂岩及泥岩等.南一段储层孔隙度平均值为6.15%,渗透率平均值为0.31 × 10-3μm2,为低孔特低渗型孔隙特征;南二段储层孔隙度平均值为12.18%,渗透率平均值为2.79× 10-3μm2,属于中孔低渗型孔隙特征.储集空间类型以粒间孔隙为主,发育一定的次生孔隙.喉道分为4种类型(Ⅰ类、Ⅱ类、Ⅲ类、Ⅳ类).扇三角洲前缘分支水道砂体、扇三角洲平原辫状河道砂体和滨浅湖砂坝微相砂体为该区有利的储层砂体类型.储层性质主要受沉积相和成岩作用影响.     

Diel Patterns in Chlorophyll <Emphasis Type="Italic">a</Emphasis> Specific Absorption Coefficient and Absorption Efficiency Factor of Picoplankton

Diel patterns in the chlorophyll a specific absorption coefficient of surface picoplankton, a*_pico (γ) (m²·[mg chlorophyll a]⁻¹), were studied at 7 stations under daily cycle of in situ light condition in the western subarctic Pacific and Japan Sea. All the data were normalized by dividing the anomaly with daily averaged a*_pico (γ). Opposite diel patterns were observed for the normalized a*_pico (443) and a*_pico (675) with maximum toward dawn or dusk and minimum toward midday at 4 stations under low-irradiance (LI) conditions and vice versa at 3 stations under high-irradiance (HI) conditions. The absorption efficiency factors at red absorption peak, Q _a (675), were determined by reconstruction with intracellular chlorophyll a concentration and cell diameter. The normalized Q _a (675) also showed diel pattern with maximum toward midday and minimum toward dawn or dusk under LI. The diel pattern in a*_pico (675) and Q _a (675) were primarily caused by changes in intracellular chlorophyll a concentration due to photoadaptation under LI. The diel pattern in a*_pico (443) was influenced by pigmentation, as recognized by blue to red ratio [a*_pico (443)/a*_pico (675)] under HI. This study proposed that the opposite diel pattern in a*_pico (γ) might occur for a wide range of algal species. The results presented here have important consequences for the interpretation of diel variations in optical properties observed in the open ocean.     

CO<Subscript>2</Subscript> Flux Measurements over the Sea Surface by Eddy Correlation and Aerodynamic Techniques

The measurements of the vertical transport of CO₂ were carried out over the Sea of Japan using the specially designed pier of Kyoto University on September 20 to 22, 2000. CO₂ fluxes were measured by the eddy correlation and aerodynamic techniques. Both techniques showed comparable CO₂ fluxes during sea breeze conditions: −0.001 to −0.08 mg m⁻²s⁻¹ with the mean of −0.05 mg m⁻²s⁻¹. This means that the measuring site satisfies the fetch requirement for meteorological observations under sea breeze conditions. Moreover, the eddy diffusivity coefficient used in the aerodynamic technique is found to be consistent with the coefficient used in the eddy correlation technique. The present result leads us to conclude that the aerodynamic technique may be applicable to underway CO₂ flux measurements over the ocean and may be used in place of the bulk technique. The important point is the need to maintain a measuring accuracy of CO₂ concentration difference of the order of 0.1 ppmv on the research vessels or the buoys.     

Roles of Biogeochemical Processes in the Oceanic Carbon Cycle Described with a Simple Coupled Physical-Biogeochemical Model

To evaluate the contribution of biogeochemical processes to the oceanic carbon cycle and to calculate the ratio of calcium carbonate to organic carbon downward export, we have incorporated biological and alkalinity pumps in the yoked high-latitude exchange/interior diffusion-advection (YOLDA) model. The biogeochemical processes are represented by four parameters. The values of the parameters are tuned so that the model can reproduce the observed phosphate and alkalinity distributions in each oceanic region. The sensitivity of the model to the biogeochemical parameters shows that biological production rates in the euphotic zone and decomposition depths of particulate matters significantly influence horizontal and vertical distributions of biogeochemical substances. The modeled vertical fluxes of particulate organic phosphorus and calcium carbonate are converted to vertical carbon fluxes by the biological pump and the alkalinity pump, respectively. The downward carbon flux from the surface layer to the deep layer in the entire region is estimated to be 3.36 PgC/yr, which consists of 2.93 PgC/yr from the biological pump and 0.43 PgC/yr from the alkalinity pump, which is consistent with previous studies. The modeled rain ratio is higher with depth and higher in the Pacific and Indian Oceans than in the Atlantic Ocean. The global rain ratio at the surface layer is calculated to be 0.14 to 0.15. This value lies between the lower and higher ends of the previous estimates, which range widely from 0.05 to 0.25. This study indicates that the rain ratio is unlikely to be higher than 0.15, at least in the surface waters.     

Long-Term Investigation of Spatio-Temporal Variations in Faunal Composition and Species Richness of Megabenthos in Ise Bay,Central Japan

Based on our long-term data from megabenthos sampling from 1993 to 2002 in Ise Bay, central Japan, we examined spatio-temporal variations in taxon composition, species richness and its distribution of megabenthos in the bay in relation to the occurrence of the oxygen-poor water (i.e. oxygen content less than 3 ppm) in bottom waters of the bay. A total of 261 species were identified including 6 cnidarians, 1 tentaculate, 5 annelids, 71 molluscs, 72 crustaceans, 16 echinoderms, 12 urochordates and 78 pisces. Of the most abundant 10 megabenthos species, the following 4 species of echinoderms made up more than the half of megabenthos biomass: Luidia quinaria, Echinocardium cordatum, Asterias amurensis and Astropecten scoparius. Species richness of megabenthos varied significantly between seasons and among stations. The severity and period of occurrence of the oxygen-poor water developing every summer play an important role in determining spatial distributions of species richness in the bay.     

Relationship between Salinity and Nutrients in the Subsurface Layer in the Suruga Bay

We investigated the water structure and nutrient distribution in the Suruga Bay from April 2000 to July 2002, especially the Offshore Water, which occupies a large part of the bay. The maximum salinity in the upper 200 m varied between 34.49 and 34.71, indicating a temporal change in the influence of Kuroshio Water on the Offshore Water. Seasonal variation in nutrient concentrations was largest from surface to 50 m. On the other hand, the variance in nutrient concentrations within each season was largest in the subsurface layer of 100–300 m in spring, summer and fall. In the Offshore Water, the change of nutrients was negatively correlated with that of salinity in each season. This suggests that an increasing intrusion of saline water brings about a lower nutrient concentration in the Offshore Water. Likewise, negative correlations were observed between the change of the maximum salinity and chlorophyll a (Δ [chl.a-int])/nutrients integrated in the upper 200 m. Δ[chl.a-int] was significantly correlated with the changes of nitrate and phosphorus, but there were no significant correlations between Δ[chl.a-int] and the change of silicate. These results suggest that the concentrations of chlorophyll a and nutrients in the Offshore Water were decreased due to the increasing intrusion of Kuroshio Water. The Offshore Water is likely to be related to the regulation of primary production by nitrate.     

Drag Coefficient,Dynamic Roughness and Reference Wind Speed

Surface waves are the roughness element of the ocean surface. The parameterization of the drag coefficient of the ocean surface is simplified by referencing to wind speed at an elevation proportional to the characteristic wavelength. The dynamic roughness is analytically related to the drag coefficient. Under the assumption of fetch limited wave growth condition, various empirical functions of the dynamic roughness can be converted to equivalent expressions for comparison. For datasets covering a wide range of the dimensionless frequency (inverse wave age), it is important to account for the variable rate of wave development at different wave ages. As a result, the dependence of the Charnock parameter on wave age is nonmonotonic. Finally, the analysis presented here suggests that the significant wave steepness is a sensitive property of the ocean surface and a single variable normalization of the dynamic roughness using a wavelength or wave height parameter actually produces more robust functions than bi-variable normalizations using wave height and wave slope.