基于多参数指标的长江口滨岸多环芳烃来源辨析

在长江口滨岸及临近排污口、滨岸河流、城市中心城区采集悬浮颗粒物、表层沉积物、街道灰尘等样品, 分别利用GC-MS 和GC-C-IRMS 定量分析了不同环境介质中的多环芳烃 (PAHs) 与有机单体化合物稳定碳同位素(δ¹³C), 开展了基于PAH 环数、分子量特征比值和有机单体化合物稳定碳同位素组成等参数指标的长江口滨岸悬浮颗粒物与表层沉积物中PAHs 源解析研究。研究结果显示, 长江口滨岸悬浮颗粒物与表层沉积物中的PAH 化合物主要以3~4 环为主, 与吴淞排污口、石洞口污水处理厂、黄浦江、滨岸小河流以及上海中心城区等潜在来源区域不同环境介质中的PAHs 组成特征相似, 主要来源于汽油、柴油、煤炭和木材的不完全燃烧以及石油残余物的混合。其中, 木材和煤炭不完全燃烧形成的PAHs 以及石油残余物, 枯季经过滨岸河流及排污口直接输入, 洪季则为城市街道灰尘被暴雨冲刷, 随地表 径流最终汇入河口; 汽车排放(汽油、柴油不完全燃烧) 产生的PAHs 主要富集在城市交通区和商业区的街道灰尘中, 枯季借助区域盛行风迁移至河口区, 洪季则主要通过暴雨径流冲刷进入河口。     

官厅水库近三十年的水质演变时序特征

基于过去的研究成果,综述了官厅水库近三十年来的水质演变过程,分阶段探讨了官厅水库水污染的来源和特征。与此同时,从污染物的角度探讨了官厅水库典型污染物的时空变化规律。研究结果表明,官厅水库的水质演变先后经历了四个阶段,依次为1972～1975年以有机毒物和重金属污染为特征的水体污染,1981～1992年以有机污染为主体的水体再污染,1992～1995年增加了大肠杆菌污染的水体复合污染,以及1996年至今以氮磷污染为明显特征的水体有机复合污染。从主要污染物的时间变化上看,库区COD和主要重金属含量均在缓慢上升,挥发酚的含量呈现波动趋势,氨氮和总磷的含量持续大幅度上升。污染物在库区的空间分布规律相似,入库处污染物浓度明显高于出库处的污染物浓度。     

兰州市城区河道表层沉积物地球化学元素分布特征

通过对兰州市河道表层沉积物地球化学元素分析发现,兰州市河道表层沉积物41种地球化学元素富集因子多小于1,Cl、S、P、Bi、Cr、Cu、Pb、Sn、U、W、Zn富集因子值均大于2,显示了较高的污染水平。对单个采样点总富集因子的分析研究发现,R值均大于2,显示出较多的富集。其中水磨沟下游和鱼儿沟下游富集因子出现高值,显示出严重污染。元素来源研究结果显示,兰州市河道表层沉积物地球化学元素的来源可分为3类:①生活污水排放以及雨水对地面或街道的冲刷作用;②工业污染,包括冶金、电镀、农药和化肥等污水的排放;③本地土壤类型灰钙土中元素的贡献。通过粒度与元素相关性分析可知,元素P、Cl主要分布于细颗粒物质中,反映了兰州市河道表层沉积物污染物质在细颗粒中有较大量的富集。     

衡水湖湿地底泥重金属污染及潜在生态风险评价

测定了衡水湖湿地20个采样点底泥中的7种重金属含量,并与环境背景值进行了比较。结果显示,衡水湖湿地底泥中的Hg含量普遍高于环境背景值,为衡水湖湿地底泥中主要富集的重金属元素,而Cr和Cd基本无富集。用地积累指数、某种重金属的潜在生态危害系数和多种重金属的潜在生态风险指数评价了各个采样点的污染程度和潜在生态风险。结果表明,Hg为高风险元素,底泥中重金属污染主要以Hg为主;衡水湖湖内大部分地区的潜在生态风险相对较低,综合潜在生态风险最高处为魏屯闸,然后依次为南关闸、106国道、大赵闸和湖内岛,核心区的综合潜在生态风险最小。另外,还对魏屯闸处的3个采样点的多种重金属的潜在生态风险指数值进行了讨论。     

Effect of removing small (<150?μm) chironomids on inferring temperature in cold lakes

Sieving samples for chironomid analysis with a 150 μm mesh was shown to greatly reduce sample preparation time, and use of only larger specimens did not affect chironomid-inferred salinities in African lakes. Here, we tested if this method is suitable for temperature reconstruction in colder lakes at higher latitudes. Removal of specimens <150 μm in two training sets, one from Canada and one from Sweden, had little impact on the performance statistics of the calibration models. Chironomid abundance, however, decreased greatly because more than half of the head capsules in assemblages were <150 μm. This had major impacts on the temperature reconstructions. Inferences were on average 2°C warmer with the modified models (all specimens >150 μm) than those obtained with the full model (all specimens >100 μm). General patterns of temperature change were also altered. For Lake 7 on Southampton Island, Canada, a cooling trend was reconstructed with the full Canadian model while the modified Canadian model yielded a warming trend. When only specimens >150 μm were used, two to three times more wet sediment was needed to obtain a sufficient number of head capsules. These results indicate that, in cold lakes (mean July/August air temperature ≤11°C), large proportions of head capsules are <150 μm, and sieving the samples in a 150 μm mesh leads to altered temperature reconstructions.     

北京市房价与地价的动态关系——基于结构方程模型的实证分析

城市房价与地价之间的关系错综复杂,不仅受多种因素的交织影响,相互之间也存在动态关系。研究房价与地价关系的传统方法,如Granger因果检验和回归分析等,无法刻画房价与地价之间多维的网络状关系,相比之下,结构方程模型能同时处理多个内生潜变量,且不受观测指标共线性的影响,为刻画地价与房价的交互作用提供了新的工具。从住房与土地市场的供需传导机制出发,推导出房价与地价的结构模型,以北京市为例,运用2003-2013年居住用地价格和2014年在售楼盘价格,与北京市GIS电子地图相匹配,提取商服中心可达性、公共交通可达性、道路可达性、商服繁华度、设施便利性等解释变量,构建地价与房价结构方程模型,分析二者之间的结构关系。     

川东南地区茅口组岩溶古地貌恢复及特征

东吴运动造成茅口组灰岩暴露地表并经历了表生风化作用。钻井揭示,气藏储层段与古岩溶所处的位置及强度密切相关,古地貌是控制古岩溶发育与分布的主要因素。针对钻井较少且分布不均、勘探程度不高的川东南地区,将钻井与地震紧密结合,分别运用残余厚度法与印模法对茅口组岩溶古地貌进行恢复,结果对比发现,这2种方法恢复出来的古地貌趋势基本一致。结合研究区的地质特征和实际资料,认为印模法可信度更高。在古水系特征分析的基础上,结合古地质图和钻井资料,把研究区划分为岩溶高地、岩溶斜坡和岩溶盆地,其中岩溶斜坡又可分为岩溶陡坡与岩溶缓坡。研究区西南岩溶高地与蜀南岩溶高地为同一岩溶高地,呈北西—南东向展布,且相对蜀南地区隆起幅度更高。在岩溶斜坡区,地下水以径流为主,溶蚀孔洞发育,是岩溶勘探开发的有利地区。     

Experimental research on the effect of slope morphology on bank collapse in mountain reservoir

Farmers along the Amazon River each year face multiple natural hazards that threaten crop production and limit the potential for agricultural development of the expansive floodplain and active channel. In this paper we report the findings of a study of natural hazard-related risk associated with rice production on silt bars in the active channel of the Amazon River near Iquitos, Peru. Data were gathered in four rice producing communities in 2014 using household surveys (n = 83 households), focus group discussions, surveying of land elevations along the Amazon River, and interpretation of remote sensing imagery. The probability, extent, and severity of rice crop shortfalls were estimated for recent production years and the economic losses to farming households were also assessed. Our findings point to a very high risk of crop shortfalls due to natural hazards, suggesting that a good year brings rice farmers bounty and a bad year, near penury. River stage reversals (repiquetes) and edaphic conditions were found to be more problematic than the often cited hazard of high and/or early floods. Also surprisingly, farmers’ perceptions of hazards and risk diverged markedly from actual shortfalls experienced during the production years studied. Our results provide the first quantitative estimates of risk due to the multiple natural hazards along the Amazon River and point to the need to assist lowland farmers with risk mitigation so as to unlock the considerable potential of Amazon floodlands for agricultural production.     

使用NCEP数据分析新疆于田地震前异常增温

美国国家环境预测中心(NCEP)全球再分析资料为监测地震异常提供了新的数据源。分析了2008年3月21日新疆7.3级地震前一个月的NCEP数据,发现2月18日06时（UTCS世界标准时间）在震中附近的断层带上出现温度异常,随后异常持续并向震中位置靠近。20日18时,异常区域完全覆盖震中位置,增温幅度达到7 K。21日12时异常结束。分析表明：温度异常区域与断层分布具有一致性,增温中心对应未来震中位置,增温幅度和发震震级可能存在对应关系,这对预测地震具有重要意义。