Calorimetric determination of the standard enthalpy of formation of stannite,Cu<Subscript>2</Subscript>FeSnS<Subscript>4</Subscript>

The standard enthalpy of formation of stannite (Cu₂FeSnS₄) was calculated from the calorimetric measurements of the reactions of its formation from simple synthetic sulfides: Cu₂S + FeS₂ + SnS → Cu₂FeSnS₄ and ₂CuS + FeS + SnS → Cu₂FeSnS₄. Using published data for the binary sulfides, the standard enthalpy of formation of stannite from the elements was determined as ΔfH°_298.15(Cu₂FeSnS₄) =–(417.28 ± 2.28) kJ mol^–1.     

Calibration of AGRS System Using Transportable Pads in India: An Application to AGRS Data of Aravalli Basin,Banswada Block,South Rajasthan

Calibration of airborne gamma ray spectrometric system (AGRS) over standard radioactive sources of known elemental abundances is essential before carrying out airborne surveys. In India, fixed calibration pads were constructed in 1985. Since then calibration of AGRS system was carried out over the fixed pads. However the fixed pads are expensive to build and maintain. Also the large pads are subject to variations in radiation output due to variable moisture content and radon loss. Alternate approach is to construct transportable calibration pads which are discussed in this paper.Atomic Minerals Directorate for Exploration & Research (AMD) under Department of Atomic Energy has recently constructed five transportable calibration pads. Three pads i.e. K, U and Th have been spiked with the respective radioelements while keeping the minor radioelements to the least in order to obtain pure spectra. A composite pad has been constructed which contains all the three radioelements. This helps in cross verifying the obtained calibration results. A background pad has also been constructed which is helpful to obtain the background values during calibration.Analysis of the data acquired over the transportable pads with airborne gamma ray spectrometer (16.8 ltr) has been carried out and presented in this paper. A comparison with the data acquired over the fixed calibration pads is also included. There is a good agreement of results which suggests the use of transportable pads in future.     

Problem of the Application of Mathematical Methods in Geology

The most characteristic errors in the application of mathematical-statistic and modeling methods encountered periodically during the peer reviewing of geological scientific journals are analyzed, and recommendations for their elimination are given. Problems of the determination of relative errors in the simplified mathematical models are discussed. Necessity of calculating parameters of the background value and eliminating its influence on computation of the “useful signal” is shown. A graphic method for determining the minimum anomalous content is also proposed for discussion and testing. Characteristic errors and necessity for maintaining constraints of the application of correlation analysis are demonstrated.     

Soil Loss Estimation based on RUSLE along the Central Hunter Valley Region,NSW, Australia

Soil erosion by water has been a major problem since man introduced agriculture in the landscape. Soil erosion is a common hazard which is steadily increasing as a result of human activities in many parts of the world. Hunter Valley of NSW is located in subtropical eastern Australia. The region is known for its diversity in landscape that includes wide floodplains, extensive estuarine wetlands, undulating country, escarpments and rugged sandstone gorges. The region is also well known for wine production. The Hunter Valley has a long history of soil erosion following the European settlement 150 years ago. Currently there have been renewed human activities in the south central part of the region for coal mining, leading to clearance of vegetation and disturbance of soil. The present study addresses the issue of soil erosion in a part of Hunter Region by employing the Revised Universal Soil Loss Equation (RUSLE, Renard et al., 1977) model. The results indicate that the average annual soil loss from the area is 0.7 kg/m²/year, which is well beyond the tolerance limit of the soil. Statistical relationships between soil loss and each parameter of the RUSLE equation were obtained and it was found that C factor has significant influence on the average soil loss in the area. An overall picture that emerges out of the study is that the region is continuing to suffer as a result of disturbance in natural environment from the historical times till present.     

Response of Mollusk Assemblages to Environmental Conditions: A Case Study from the Burullus Lagoon,Egypt

The identified mollusks from the Burullus lagoon of Egypt (Eastern Mediterranean) are represented by four bivalve species and four gastropod species. Sources of heavy metals pollution in the Burullus lagoon include phosphate fertilizers, sewage and oil spills from fishing boats.The Cerastoderma glaucum species has a wide distribution in the central part of the studied area with satisfying criteria required for good bio-monitors of pollution. High concentrations of heavy metals are found in water, at the eastern side of the lagoon, while low concentrations were detected in the central and western sides of the lagoon. Pirenella conica constitutes the total gastropods assemblages, reflecting this species tolerance to the high concentration of heavy metals. Meanwhile, the total pelecypods in bottom lagoon sediments are completely absent in the eastern parts of the lagoon, which may be due to the sensitivity of pelecypods to the accumulation of heavy metals.     

A Preliminary Evaluation on the Prospects of Hydrocarbon Potential in the Carbonaceous Shales of Spiti and Chikkim Formations,Tethys Himalaya,India

In the present investigation, an attempt has been made to explore the possibility of hydrocarbon prospects in the carbonaceous shale deposits of Spiti and Chikkim formations exposed in the Spiti valley of the Tethys Himalaya. Twenty samples, collected from successive levels of these litho-units, have been subjected to maceral analysis, Rock-Eval Pyrolysis and six samples to Fourier Transform Infra-red Spectroscopy (FTIR) and nuclear magnetic resonance (NMR) analyses. The study reveals the presence of mainly kerogen-III type of organic matter but some of the shale samples have shown a good amount of total organic carbon (TOC) to the tune of 3.19% which is sufficient to produce hydrocarbon. The results indicate the presence of methane occurring as free and fixed hydrocarbon in the shale samples. Few levels are especially rich in hydrocarbon. They have shown encouraging results with potential for generating liquid as well as lighter hydrocarbon. The data is also supported by the FTIR and NMR studies.     

Magnetic Mapping of Banded Iron Formation of Sandur Schist Belt,Dharwar Craton,India

High ground magnetic anomalies are observed at western basin of the Sandur schist belt (SSB) near Muraripura village, Karnataka. Sources for these anomalies are inferred due to presence of exposed banded iron formations hosted by metabasalts, arenaous and argillaceous rocks associated with the Donimali Formation of the schist belt. Two varieties of BIF bands are observed in the study area viz. Band 1 and Band 2. The bands 1 and 2 are displaced by lateral strike-slip fault. Band 1 is dominantly composed of banded iron formation, rich in iron ore minerals and silica chert. Band 2 is largely composed of ferruginous quartzite and quartz arenites. Qualitative analysis of the magnetic data indicates that the study area can be divided into three lithologically important BIF/BQ formations. Spectral and quantitative analysis of the magnetic data indicates, the average depth of band 1 is 70 m and band 2 is 130 m. The magnetic data results are well correlated with chemical analysis of borehole and surface rock samples data.