Structural analysis of the gravity field over the American-Antarctic Ridge

This paper discusses the structure of the American-Antarctic Ridge based on analysis of the gravity field. Analysis of the gravity field in different reductions and its transforms allowed the revelation of zonal, regional, and local specific features in the field’s structure and their correlation with contemporary notions on the tectonic zoning of the American-Antarctic Ridge and adjacent regions. The lineament structures of the field allowed locating the areas of spreading zones and principal transform and fracture zones. Comparison between the location of these structural features and the interpretation results of shipboard magnetic measurements confirmed the reliability of the received data. Results of the performed investigations presented in the form of structural schemes are a basis for constructing a model of the tectonosphere under the American-Antarctic Ridge.     

Evolution of melt composition during intrusion of basalts into a silicic magma chamber

The article describes heat exchange between basaltic and rhyolite melts accompanied by fractional crystallization of phases in a basaltic melt. A numerical model has been developed for the homogenization mechanism of magma composition during intrusion of basaltic magma batches into felsic magma chambers. The results of numerical modeling demonstrate that the time needed for cooling the basalts and their fractionation to rhyolite melts is much shorter than the time required for chemical interaction based on diffusive mechanisms.     

Changes of deformational and reservoir properties of arenaceous-argillaceous rocks due to operation of underground gas storage facilities

This paper discusses issues of the decline of the reservoir properties of arenaceous-argillaceous rocks as a result of declining porosity due to long-term operation of underground gas storage facilities. An analysis of the many-year operation of storage facilities, as well as calculation, has revealed that the active capacity of a storage reservoir gradually decreases under certain conditions of underground storage operations. We performed a series of experiments with model specimens in order to support the hypothesis of decreasing reservoir (capacity-filtration) properties because of changes in the value and structure of the pore space. These experiments showed that the cyclic loading and unloading of arenaceous-silty rocks during long-term operation of underground gas storage facilities can significantly decrease the reservoir parameters of reservoirs created within worked out gas-and-gas condensate fields. Laboratory studies of model specimens corresponding to feldspar sandstone in their composition, porosity, and strength proved that porosity considerably decreases in such reservoirs at actually existing values of formation pressure. Tests of sand performed under conditions close to those existing during the development of hydrocarbon fields also showed that their permeability gradually decreases in the process of cyclic changes of effective pressure.     

Numerical modeling for analyzing thermal surface anomalies induced by underground coal fires

Coal seams burning underneath the surface are recognized all over the world and have drawn increasing public attention in the past years. Frequently, such fires are analyzed by detecting anomalies like increased exhaust gas concentrations and soil temperatures at the surface. A proper analysis presumes the understanding of involved processes, which determine the spatial distribution and dynamic behavior of the anomalies.In this paper, we explain the relevance of mechanical and energy transport processes with respect to the occurrence of temperature anomalies at the surface. Two approaches are presented, aiming to obtain insight into the underground coal fire situation: In-situ temperature mapping and numerical simulation. In 2000 to 2005, annual temperature mapping in the Wuda (Inner Mongolia, PR China) coal fire area showed that most thermal anomalies on the surface are closely related to fractures, where hot exhaust gases from the coal fire are released. Those fractures develop due to rock mechanical failure after volume reduction in the seams. The measured signals at the surface are therefore strongly affected by mechanical processes.More insight into causes and effects of involved energy transport processes is obtained by numerical simulation of the dynamic behavior of coal fires. Simulations show the inter-relation between release and transport of thermal energy in and around underground coal fires. Our simulation results show a time delay between the coal fire propagation and the observed appearance of the surface temperature signal. Additionally, the overall energy flux away from the burning coal seam into the surrounding bedrock is about 30-times higher than the flux through the surface. This is of particular importance for an estimation of the energy released based on surface temperature measurements. Finally, the simulation results also prove that a fire propagation rate estimated from the interpretation of surface anomalies can differ from the actual rate in the seam.     

Silica phase transformations in the petroliferous sequences

The joint evolution of organic matter and silica in petroliferous sequences is considered in the terms of the laws of transformation of dispersion systems. The dispersion systems are transformed under conditions of low-temperature solid-phase processes accompanied by the silica phase transition and dehydration that favors the evolution of organic matter.     

Ultrahigh pressure macro diamonds from Copeton (New South Wales, Australia), based on Raman spectroscopy of inclusions

Mining of Cenozoic alluvial deposits at Copeton and Bingara (Eastern Australia) has produced two million macrodiamonds (0.25 ct median size). Raman spectroscopy is used to identify included minerals within uncut Copeton diamonds, with sealed chamber remnant pressures of 31.7 to 35.6 kbar for coesite, 13.6 and 22.7 kbar for clinopyroxene, and 7.6 kbar for grossular garnet. Assuming elastic behaviour, these values generate inclusion entrapment PT loci which intersect, restricting diamond formation conditions: from 250 °C, 43 kbar to 800 °C, 52 kbar. Larger than error (± 100 °C and ± 4 kbar), this range shows a systematic variation in inclusion composition with diamond zoning and N properties. Published research shows 1) Copeton and Bingara diamonds are unique, and 2) modern alluvium in the Bingara district carries mantle-formed garnet, captured by post-tectonic alkali basalt from an extensive diamondiferous ultrahigh pressure (UHP) terrane that stalled at depth because it is dominated by mafic eclogite. The combined Raman and geological results indicate two sets of subduction UHP diamond formation conditions/protolith are required, firstly cooler oceanic slab and secondly including higher temperature continental crust. The Copeton and Bingara stones are UHP macrodiamonds, and Carboniferous ⁴⁰Ar/³⁹Ar age dates on clinopyroxene inclusions should be interpreted as ages of crystallisation, representing the termination of subduction. The characteristic features of ruptured inclusions and etched percussion marks on Copeton and Bingara diamond indicate volcanic delivery to the earth's surface. Alluvial deposits elsewhere in Eastern Australia may carry similar diamond along with diamond of different origin.     

SHRIMP zircon dating and Sm/Nd isotopic investigations of Neoproterozoic granitoids, Eastern Desert, Egypt

There is an increasing evidence for the involvement of pre-Neoproterozoic zircons in the Arabian–Nubian Shield, a Neoproterozoic crustal tract that is generally regarded to be juvenile. The source and significance of these xenocrystic zircons are not clear. In an effort to better understand this problem, older and younger granitoids from the Egyptian basement complex were analyzed for chemical composition, SHRIMP U–Pb zircon ages, and Sm–Nd isotopic compositions. Geochemically, the older granitoids are metaluminous and exhibit characteristics of I-type granites and most likely formed in a convergent margin (arc) tectonic environment. On the other hand, the younger granites are peraluminous and exhibit the characteristics of A-type granites; these are post-collisional granites. The U–Pb SHRIMP dating of zircons revealed the ages of magmatic crystallization as well as the presence of slightly older, presumably inherited zircon grains. The age determined for the older granodiorite is 652.5 ± 2.6 Ma, whereas the younger granitoids are 595–605 Ma. Xenocrystic zircons are found in most of the younger granitoid samples; the xenocrystic grains are all Neoproterozoic, but fall into three age ranges that correspond to the ages of other Eastern Desert igneous rocks, viz. 710–690, 675–650 and 635–610 Ma. The analyzed granitoids have (+3.8 to +6.5) and crystallization ages, which confirm previous indications that the Arabian–Nubian Shield is juvenile Neoproterozoic crust. These results nevertheless indicate that older Neoproterozoic crust contributed to the formation of especially the younger granite magmas.     

Extensional tectonic origin of gneissosity and related structures of the Feiran–Solaf metamorphic belt, Sinai, Egypt

The Feiran–Solaf metamorphic belt consists of low-P high-T amphibolite facies, partly migmatized gneisses, schists, amphibolites and minor calc-silicate rocks of metasedimentary origin. There are also thick concordant synkinematic sheets of diorite, tonalite and granodiorite orthogneiss and foliated granite and pegmatite dykelets. The gneissosity (or schistosity) is referred to as S₁, and is almost everywhere parallel to lithological layering, S₀. This parallelism is not due to transposition. The gneissosity formed during an extensional tectonic event (termed D1), before folding of S₀. S₁ formed by coaxial pure shear flattening strain (Z normal to S₀, i.e. vertical; with X and Y both extensional and lying in S₁). This strain also produced chocolate tablet boudinage of some layers and S₁-concordant sills and veins. S₁ has a strong stretching lineation L₁ with rodding characteristics. Within-plane plastic anisotropy (lower ductility along Y compared to along X) resulted in L₁-parallel extensional ductile shears and melt filled cracks. Continued shortening of these veins, and back-rotation of foliations on the shears produced intrafolial F₁ folds with hinges parallel to the stretching lineation. F₁ fold asymmetry variations do not support previous models involving macroscopic F₁ folds or syn-gneissosity compressional tectonics. The sedimentary protoliths of the Feiran–Solaf gneisses were probably deposited in a pre-800 Ma actively extending intracratonic rift characterizing an early stage of the break-up of Rodinia.