A major sulphur isotope event at c. 510 Ma: a possible anoxia–extinction–volcanism connection during the Early–Middle Cambrian transition?

A new approach to constraining seawater δ³⁴S and sulphate concentration using francolite‐bound sulphate reveals an abrupt increase in δ³⁴S to +50‰ around the Early–Middle Cambrian boundary. Such high δ³⁴S values are best explained by increased rates of pyrite burial due to ocean anoxia coupled with an increased sensitivity of the ocean sulphate reservoir to perturbations due to low sulphate concentrations of 500–700 μgL^?1. We argue that the spread of anoxic waters at this time was partly the result of greenhouse warming related to the eruption of the Kalkarindji Large Igneous Province of northern Australia and that it triggered the collapse of early metazoan reef ecosystems during the latest Early Cambrian. Mass extinctions of the last 260 Myr have all coincided with enhanced volcanic activity, while several are also associated with positive shifts in seawater δ³⁴S. Extending this correlation back in time further implicates volcanically induced climate change as a major determining factor in biosphere evolution. Terra Nova, 18, 257–263, 2006     

Amino acid analyses of Antarctic CM2 meteorites using liquid chromatography‐time of flight‐mass spectrometry

Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection.     

The HNCO ring in the Sgr B2 region

The large-scale structure associated with the 2′N HNCO peak in Sgr B2 [Minh, Y.C., Haikala, L., Hjalmarson, Å., Irvine, W.M., 1998. ApJ 498, 261 (Paper I)] has been investigated. A ring-like morphology of the HNCO emission has been found; this structure may be colliding with the Principal Cloud of Sgr B2. This “HNCO Ring” appears to be centered at (l,b) = (0.7°,−0.07°), with a radius of 5 pc and a total mass of 1.0 × 10⁵ to 1.6 × 10⁶ M. The expansion velocity of the Ring is estimated to be 30–40 km s⁻¹, which gives an expansion time scale of 1.5 × 10⁵ year. The morphology suggests that collision between the Ring and the Principal Cloud may be triggering the massive star formation in the Sgr B2 cloud sequentially, with the latest star formation taking place at the 2′N position. The chemistry related to HNCO is not certain yet, but if it forms mainly via reaction with the evaporated OCN⁻ from icy grain mantles, the observed enhancement of the HNCO abundance can be understood as resulting from shocks associated with the collision between the Principal Cloud and the expanding HNCO Ring.     

The D-CIXS X-ray mapping spectrometer on SMART-1

The D-CIXS Compact X-ray Spectrometer will provide high quality spectroscopic mapping of the Moon, the primary science target of the ESA SMART-1 mission. D-CIXS consists of a high throughput spectrometer, which will perform spatially localised X-ray fluorescence spectroscopy. It will also carry a solar monitor, to provide the direct calibration needed to produce a global map of absolute lunar elemental abundances, the first time this has been done. Thus it will achieve ground breaking science within a resource envelope far smaller than previously thought possible for this type of instrument, by exploiting two new technologies, swept charge devices and micro-structure collimators. The new technology does not require cold running, with its associated overheads to the spacecraft. At the same time it will demonstrate a radically novel approach to building a type of instrument essential for the BepiColombo mission and potential future planetary science targets.     

Mezen Bay—a key area for understanding Weichselian glaciations in northern Russia

Sediment successions in coastal cliffs around Mezen Bay, southeastern White Sea, record an unusually detailed history of former glaciations, interstadial marine and fluvial events from the Weichselian. A regional glaciation model for the Weichselian is based on new data from the Mezen Bay area and previously published data from adjacent areas. Following the Mikulinian (Eemian) interglacial a shelf‐centred glaciation in the Kara Sea is reflected in proglacial conditions at 100–90 ka. A local ice‐cap over the Timan ridge existed between 75 and 65 ka. Renewed glaciation in the Kara Sea spread southwestwards around 60 ka only, interrupted by a marine inundation, before it advanced to its maximum position at about 55–50 ka. After a prolonged ice‐free period, the Scandinavian ice‐sheet invaded the area from the west and terminated east of Mezen Bay about 17 ka. The previously published evidence of a large ice‐dammed lake in the central Arkhangelsk region, Lake Komi, finds no support in this study. Copyright © 2003 John Wiley & Sons, Ltd.     

A multi‐level parallelized substructuring‐frontal solution for coupled thermo/hydro/mechanical problems in unsaturated soil

This paper proposes a multi‐level parallelized substructuring–frontal combined algorithm for the analysis of the problem of thermo/hydraulic/mechanical behaviour of unsaturated soil. Temperature, displacement, pore water pressure and pore air pressure are treated as the primary variables in a non‐linear analysis. Details are given firstly of the substructuring–frontal combined approach. The incorporation of the algorithm in a multi‐level parallel strategy is then discussed. The parallel processing can thus be carried out at different substructural levels. The method thus developed impacts, in a positive way, on both computer storage requirement and execution time. Copyright © 2003 John Wiley & Sons, Ltd.     

An empirical model of the daily evolution of the coronal index

Global changes of the solar activity can be expressed by the coronal index that is based upon the total irradiance of the coronal 530.3 nm green line from observations at five stations. Daily mean values of the coronal index of solar activity and other well-correlated solar indices are analyzed for the period 1966–1998 covering over three solar cycles. The significant correlation of this index with the sunspot number and the solar flare index have led to an analytical expression which can reproduce the coronal index of solar activity as a function of these parameters. This expression explains well the existence of the two maxima during the solar cycles taking into account the evolution of the magnetic field that can be expressed by some sinusoidal terms during solar maxima and minima. The accuracy between observed and calculated values of the coronal index on a daily basis reaches the value of 71%. It is concluded that the representative character of the coronal index is preserved even when using daily data and can therefore allow us to study long-term, intermediate and short-term variations for the Sun as a star, in association with different periodical solar–terrestrial phenomena useful for space weather studies.