The influence of salinity on the solubility of Zn and Cd sulphides in the Scheldt estuary

In the estuary of the river Scheldt, where an oxygen gradient exists in addition to the salinity gradient, redox processes will be of major importance for trace metal mobilisation. In this study, the influence of salinity and pH on the redox processes of dissolved Zn and Cd sulphides is investigated together with the effects on the ratio of the dissolved Zn and Cd concentrations. The speciation of these metals is calculated with the chemical equilibrium programme +. Zn sulphides are oxidised at lower oxygen concentrations than Cd sulphides, due to lower stability constants, causing a sudden increase or peak in the dissolved Zn/Cd ratio. The formation of dissolved Cd chloride complexes when oxidation occurs at high salinities (S=15) increases the mobility of Cd, causing a decrease in the Zn/Cd peak of the total dissolved concentrations. The peak is three to four times smaller at S=15 than when oxidation occurs at S=2. The simple model calculations compare very well with field data. The Scheldt estuary is suitable to illustrate these calculations. In the 1970s, the anoxic part of the estuary reached S=15–20, but since the early 1980s it has dropped to S=2–10. Historic data on metals in the estuary from 1978, 1987 and the 1990s were used to compare with the equilibrium calculations. The increase of the dissolved Zn/Cd peak at low salinity as a consequence, of the decreasing anoxic region is confirmed well by the data. The good agreement between model calculations and field data is a proof of the extreme importance of redox processes for the solubility of Zn and Cd sulphides in the estuary.     

Debris flow deposits of early miocene age,deadman stream,Marlborough, New Zealand

Detailed analysis is presented of a conformable succession of Early Miocene conglomerates and sandstones lying between massive marine mudstones. The coarse sediments reflect deposition by a spectrum of subaqueous debris-flow mechanisms during an early pulse of tectonism that ultimately resulted in Plio-Pleistocene eversion of the Kaikoura Mountains.Sparse pebbly mudstones and rare sandy conglomerates show disoriented clasts and reflect high-viscosity flows and slurry-creep flow mechanisms. Other deposits have little mud matrix, hence appear to reflect low-viscosity flow processes. The largest clasts in these have a preferred planar orientation, probably reflecting dispersive grain pressure, and a preferred long-axis orientation parallel to flow direction. Common sorted sandstones and some conglomeratic sandstones show diffuse parallel lamination; with rare exceptions neither grading nor traction structures are present. Other conglomeratic sandstones show trough cross-bedding which we attribute to entrained bedload movement during intersurge episodes of debris flow.Microfossil data from the mudstones indicate sedimentation in an environment of outer neritic to upper bathyal aspect. Most detritus is abraded, suggesting derivation from terrestrial or inner neritic sources, but angular calcilutitic clasts and irregular sandstone and mudstone clasts and rafts were probably derived from submarine erosion between the emergent source area and the site of accumulation. Deposits generally appear to infill broad shallow channels. Paleocurrent and fabric analysis indicate a markedly uniform flow direction throughout succession, and suggest that the locus of channeling remained relatively fixed in space throughout accumulation of hundreds of metres of superimposed, commonly amalgamated debris-flow deposits. Although lateral control away from the measured sequence is limited, we infer that the locus of deposition lay shoreward of any submarine canyon or fan.     

Estuary/ocean exchange and tidal mixing in a Gulf of Maine Estuary: A Lagrangian modeling study

A Lagrangian particle method embedded within a 2-D finite element code, is used to study the transport and ocean–estuary exchange processes in the well-mixed Great Bay Estuarine System in New Hampshire, USA. The 2-D finite element model, driven by residual, semi-diurnal and diurnal tidal constituents, includes the effects of wetting and drying of estuarine mud flats through the use of a porous medium transport module. The particle method includes tidal advection, plus a random walk model in the horizontal that simulates sub-grid scale turbulent transport processes. Our approach involves instantaneous, massive [O(500,000)] particle releases that enable the quantification of ocean–estuary and inter-bay exchanges in a Markovian framework. The effects of the release time, spring–neap cycle, riverine discharge and diffusion strength on the intra-estuary and estuary–ocean exchange are also investigated.The results show a rather dynamic interaction between the ocean and the estuary with a fraction of the exiting particles being caught up in the Gulf of Maine Coastal Current and swept away. Three somewhat different estimates of estuarine residence time are calculated to provide complementary views of estuary flushing. Maps of residence time versus release location uncover a strong spatial dependency of residence time within the estuary that has very important ramifications for local water quality. Simulations with and without the turbulent random walk show that the combined effect of advective shear and turbulent diffusion is very effective at spreading particles throughout the estuary relatively quickly, even at low (1 m²/s) diffusivity. The results presented here show that a first-order Markov Chain approach has applicability and a high potential for improving our understanding of the mixing processes in estuaries.     

Diurnal variation of the dayside, ionospheric, mid-latitude trough in the southern hemisphere at 800 km: Model and measurement comparison

Our high latitude ionospheric model predicts the existence of a pronounced “dayside” trough in plasma concentration equatorward of the auroral oval in both the Northern and Southern Hemispheres for solar maximum, winter, and low geomagnetic activity conditions. The trough in the Southern Hemisphere is much deeper than that in the Northern Hemisphere, with the minimum trough density at 800 km being 2 × 10³ cm⁻³ in the Southern Hemisphere and 10⁴ cm⁻³ in the Northern Hemisphere. The dayside trough has a strong longitudinal (diurnal) dependence and appears between 11:00 and 19:00 U.T. in the Southern Hemisphere and between 02:00 and 08:00 U.T. in the Northern Hemisphere. This dayside trough is a result of the auroral oval moving to larger solar zenith angles at those universal times when the magnetic pole is on the antisunward side of the geographic pole. As the auroral ionization source moves to higher geographic latitudes, it leaves a region of declining photoionization on the dayside. For low convection speeds, the ionosphere decays and a dayside trough forms. The trough is deeper in the Southern Hemisphere than in the Northern Hemisphere because of the greater offset between the geomagnetic and geographic poles. Satellite data taken in both the Northern and Southern Hemispheres confirm the gross features of the dayside trough, including its strong longitudinal dependence, its depth, and the asymmetry between the Northern and Southern Hemisphere troughs.     

Record of Late Pleistocene Glaciation and Deglaciation in the Southern Cascade Range. I. Petrological Evidence from Lacustrine Sediment in Upper Klamath Lake, Southern Oregon

Petrological and textural properties of lacustrine sediments from Upper Klamath Lake, Oregon, reflect changing input volumes of glacial flour and thus reveal a detailed glacial history for the southern Cascade Range between about 37 and 15 ka. Magnetic properties vary as a result of mixing different amounts of the highly magnetic, glacially generated detritus with less magnetic, more weathered detritus derived from unglaciated parts of the large catchment. Evidence that the magnetic properties record glacial flour input is based mainly on the strong correlation between bulk sediment particle size and parameters that measure the magnetite content and magnetic mineral freshness. High magnetization corresponds to relatively fine particle size and lower magnetization to coarser particle size. This relation is not found in the Buck Lake core in a nearby, unglaciated catchment. Angular silt-sized volcanic rock fragments containing unaltered magnetite dominate the magnetic fraction in the late Pleistocene sediments but are absent in younger, low magnetization sediments. The finer grained, highly magnetic sediments contain high proportions of planktic diatoms indicative of cold, oligotrophic limnic conditions. Sediment with lower magnetite content contains populations of diatoms indicative of warmer, eutrophic limnic conditions. During the latter part of oxygen isotope stage 3 (about 37–25 ka), the magnetic properties record millennial-scale variations in glacial-flour content. The input of glacial flour was uniformly high during the Last Glacial Maximum, between about 21 and 16 ka. At about 16 ka, magnetite input, both absolute and relative to hematite, decreased abruptly, reflecting a rapid decline in glacially derived detritus. The decrease in magnetite transport into the lake preceded declines in pollen from both grass and sagebrush. A more gradual decrease in heavy mineral content over this interval records sediment starvation with the growth of marshes at the margins of the lake and dilution of detrital material by biogenic silica and other organic matter.     

梅雨锋的典型结构、多样性和多尺度特征

在天气尺度梅雨锋的天气学定义基础上,利用GMS-5静止卫星红外云图、常规气象探空资料、NCEP再分析与最终分析资料对2002年长江流域典型梅雨期6月26—28日和二度梅期间7月23日、1998年5月梅雨与7月二度梅共4个梅雨锋个例进行了分析与比较,归纳了梅雨锋结构多样性;并着重对典型梅雨期的梅雨锋发展过程、水平以及垂直结构进行了多种物理量场(包括风场、温度场、急流、锋区、假相当位温、散度、垂直速度、静力稳定度等)的综合分析。结果表明,不同的个例,不同的地区和时期,一次梅雨过程的不同阶段,梅雨锋的结构和性质都有可能不同,它可以从比较接近极锋的性质过渡到接近赤道锋的性质。在水平结构上梅雨锋是在高、低纬度不同尺度的环流系统共同作用下形成的,从而造成了梅雨锋结构具有丰富的多样性。对典型梅雨锋结构进行综合分析表明梅雨锋对流层中下层锋面由强假相当位温水平梯度形成;梅雨锋南侧为暖湿气团、北侧为变性气团;梅雨锋南面为西南季风、北面为偏东气流;梅雨锋的上升运动和强降水主要发生在梅雨锋的前沿;梅雨锋上方对流层上半部存在与副热带高空急流相配合的高空副热带锋;对流层上部的高空热带东风与副热带高空西风急流构成了梅雨锋降水的高空辐散流场。根据典型期梅雨锋以及二度梅倾斜型梅雨锋的对流层上、中、下水平环流特征,给出了梅雨锋的多尺度概念模型,主要包括中低纬度系统相互作用、对流层高层的行星尺度的环流系统副热带高空西风急流、高空热带东风急流与南亚高压、对流层中层的副热带高压与北方的短波槽以及对流层低层的行星尺度季风和切变线。     

中国地区云对地气系统太阳短波吸收辐射强迫的气候研究

本文利用地球辐射平衡试验（ＥＲＢＥ）和国际卫星云气候计划（ＩＳＣＣＰ）提供的总云量、行星反射率资料,计算并分析了我国年、月平均云对地气系统太阳短波吸收辐射的强迫及其敏感性系数,揭示了它们之间的关系,最后绘制了地气系统短波辐射云强迫的全国分布图。结果表明：我国地气系统短波辐射云强迫及其敏感性系数都与总云量有较好的非线性相关,呈幂指数形式,且季节变化明显。短波辐射云强迫的地理分布与总量配合较好。     

Analysis of a large extent aeromagnetic survey near the geomagnetic equator (Minas Gerais,Brazil)

A large extent aeromagnetic survey, covering a 9°×9° degree of a Precambrian shield area in SE Brazil, was used to analyse long wavelength magnetic anomalies with the purpose of determining the magnetic structure of the lithosphere.Data analysis based on a novel approach to the estimation of the parameters in the statistical model ofSpector andGrant (1970), reveals a highly magnetized lower crust, bounded by an essentially non-magnetic upper mantle. The highly magnetized layer can be associated with a higher density lower crust model, derived from gravity and seismic data available in the area, suggesting a compositional transition from upper to lower crust.It was also verified that the operation of reduction to the pole, which is singular at the geomagnetic equator, performs quite satisfactorily at the low geomagnetic inclination of the area, bringing into accordance the long wavelength anomalies with the structural trends.     

Evaluation of the first GOCE static gravity field models using terrestrial gravity,vertical deflections and EGM2008 quasigeoid heights

Recently, four global geopotential models (GGMs) were computed and released based on the first 2 months of data collected by the Gravity field and steady-state Ocean Circulation Explorer (GOCE) dedicated satellite gravity field mission. Given that GOCE is a technologically complex mission and different processing strategies were applied to real space-collected GOCE data for the first time, evaluation of the new models is an important aspect. As a first assessment strategy, we use terrestrial gravity data over Switzerland and Australia and astrogeodetic vertical deflections over Europe and Australia as ground-truth data sets for GOCE model evaluation. We apply a spectral enhancement method (SEM) to the truncated GOCE GGMs to make their spectral content more comparable with the terrestrial data. The SEM utilises the high-degree bands of EGM2008 and residual terrain model data as a data source to widely bridge the spectral gap between the satellite and terrestrial data. Analysis of root mean square (RMS) errors is carried out as a function of (i) the GOCE GGM expansion degree and (ii) the four different GOCE GGMs. The RMS curves are also compared against those from EGM2008 and GRACE-based GGMs. As a second assessment strategy, we compare global grids of GOCE GGM and EGM2008 quasigeoid heights. In connection with EGM2008 error estimates, this allows location of regions where GOCE is likely to deliver improved knowledge on the Earth’s gravity field. Our ground truth data sets, together with the EGM2008 quasigeoid comparisons, signal clear improvements in the spectral band ~160–165 to ~180–185 in terms of spherical harmonic degrees for the GOCE-based GGMs, fairly independently of the individual GOCE model used. The results from both assessments together provide strong evidence that the first 2 months of GOCE observations improve the knowledge of the Earth’s static gravity field at spatial scales between ~125 and ~110 km, particularly over parts of Asia, Africa, South America and Antarctica, in comparison with the pre-GOCE-era.     

Post-Miocene stratigraphy and depositional environments of valley-fill sequences at the mouth of Tampa Bay, Florida

Post-Miocene sea-level low stands allowed rivers and karst processes to incise the exposed carbonate platform along the Gulf Coast of Florida. Few Miocene to mid-Pleistocene deposits survived erosion along the present coast except within incised valleys. Since their formation, these valleys have been filled and incised multiple times in response to sea-level changes. The thick sedimentary sequences underlying the mouth of Tampa Bay have been recorded as a range of depositional environments and multiple sea-level incursions and excursions during pre-Holocene time and subsequent to the accumulation of the Miocene carbonate sequences. Sediment analysis of cores collected from a north–south transect across the mouth of Tampa Bay has enabled the identification of lithofacies, ranging from well-sorted, quartz sand to dense, fossiliferous, phosphatic grainstone. These facies were deposited in freshwater, estuarine, and shallow, open marine environments. As a result of channel development and migration within the paleovalley, and cut-and-fill associated with individual transgressions and regressions, correlation of the lithofacies does not extend across the entire transect. Fining-upward sequences truncated by tidal ravinement surfaces that extend throughout the paleovalley can, however, be identified. Age determinations based on 14-C analysis, amino-acid racemization, and strontium isotope analysis dating of numerous samples yield ages of Miocene, Pliocene, early Pleistocene, and late Pleistocene, as well as Holocene for sequences that accumulated and were preserved in this valley-fill complex. Numerous inconsistencies in the stratigraphic organization of the age determinations indicate that there are bad dates, considerable reworking of shells that were dated, or both. For this reason as well as the lack of detailed correlation among the three relatively complete cores, it is not possible to place these strata in a sequence stratigraphic framework.