Grain boundary diffusion of Si, Mg, and O in enstatite reaction rims: a SIMS study using isotopically doped reactants

Diffusion-controlled growth rates of polycrystalline enstatite reaction rims between forsterite and quartz were determined at 1,000 °C and 1 GPa in presence of traces of water. Iron-free, pure synthetic forsterite with normal oxygen and silicon isotopic compositions and quartz extremely enriched in ¹⁸O and ²⁹Si were used as reactants. The relative mobility of ¹⁸O and ²⁹Si in reactants and rims were determined by SIMS step scanning. The morphology of the rim shows that enstatite grows by a direct replacement of forsterite. Rim growth is modelled within a mass-conserving reference frame that implies advancement of reaction fronts from the initial forsterite-quartz interface in both directions. The isotopic compositions at the two reaction interfaces are controlled by the partial reactions Mg₂SiO₄=0.5 Mg₂Si₂O₆+MgO at the forsterite-enstatite, and MgO+SiO₂=0.5 Mg₂Si₂O₆ at the enstatite-quartz interface, implying that grain boundary diffusion of MgO is rate-controlling. Isotopic profiles show no silicon exchange across the propagating reaction interfaces. This propagation, controlled by MgO diffusion, is faster than the homogenisation of Si by self-diffusion behind the advancing fronts. From this, and using % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn % hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr % 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9 % vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x % fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamiramaaDa % aaleaacaWGtbGaamyAaiaacYcacaWGfbGaamOBaaqaaiaadAfacaWG % VbGaamiBaaaaaaa!3DD2! D_Si,En^VolD_{Si,En}^{Vol} at dry conditions from the literature, results a % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn % hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr % 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9 % vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x % fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGabmirayaafa % Waa0baaSqaaiaadofacaWGPbGaaiilaiaadweacaWGUbaabaaaaOGa % eqiTdqgaaa!3CCD! D￠_Si,En dD'_{Si,En}^{} \delta value of 3᎒^-24 m³ s^-1 at 1,000 °C. The isotopic profiles for oxygen are more complex. They are interpreted as an interplay between the propagation of the interfaces, the homogenisation of the isotope concentrations by grain boundary self-diffusion of O within the rim, and the isotope exchange across the enstatite-quartz interface, which was open to ¹⁸O influx from quartz. Because of overlapping diffusion processes, boundary conditions are unstable and D´_Ox,En' cannot be quantified. Using measured rim growth rates, the grain boundary diffusivity D´_MgO' of MgO in iron-free enstatite is 8᎒^-22 m³ s^-1 at 1,000 °C and 1 GPa. Experiments with San Carlos olivine (fo₉₂) as reactant reveal lower rates by a factor of about 4. Our results show that isotope tracers in rim growth experiments allow identification of the actual interface reactions, recognition of the rate-controlling component and further calculation of D´' values for specific components.     

Applications of computer modeling to the study of the genesis of stratiform sulfide deposits

Stratiform sulfide deposits are considered to have formed at or near the discharge vents of submarine hydrothermal systems. Such deposits constitute an important source of zinc, lead, copper, silver, and gold. They are often divided on the basis of the dominant host-rock lithology into volcanogenic and sediment-hosted types. In terms of their economic base metal contents, volcanogenic deposits contain either Cu and Zn or Zn, Pb, and Cu, whereas sediment-hosted deposits usually contain predominantly Zn and Pb. Mathematical models of the chemical characteristics of stratiform sulfide deposits are based on a program (B)which allows the calculation of the equilibrium distribution of aqueous species in a hydrothermal solution. Program B is front-ended by Program A, which defines the components of the chemical system, and back-ended by Program C, which controls the mode of output of the calculated results. Programs A and C are tailored to the specific problem under investigation. Results of chemical modeling of the two chemically active zones of the hydrothermal system (1. the hydrothermal reservoir in which the ore-forming solutions are generated and, 2. the site of ore deposition)suggest explanations of various characteristics of stratiform sulfide deposits, and include

1. The consistency of the metal associations and metal ratios suggest that ore-forming hydrothermal solutions are saturated with respect to the major metals in the reservoir zone. The chemistry of the solutions is determined mainly by temperature and chemical equilibrium between the hydrothermal solution and the rock-forming minerals of the reservoir.
2. Metal associations and metal ratios corroborate isotopic and other evidence that volcanogenic deposits were formed from hotter hydrothermal systems (> 200°Capprox.)than sediment-hosted (< 200°Capprox.)Metal ratios suggest that the hydrothermal reservoirs were contained in mafic rocks (ferromagnesian-feldspar mineral assemblages)for the Cu-Zn association; in felsic rocks and/or sediments (feldspar-mica; clay mineral assemblages)for the Zn-Pb-Cu association: and in sediments (dominated by clay mineral assemblages)for the Zn-Pb association.
3. Chemical zonation patterns and ore textures characteristics of volcanogenic deposits are explained by rapid cooling of the hydrothermal solution immediately above its discharge vent.
4. Chemical zonation patterns and the fine laminations of sediment-hosted deposits are explained by the comparatively slow degeneration of hydrothermal solutions that have collected as a brine pool on the ocean floor.

     

Holocene vegetational history of the Kootenai River Valley,Montana

Pollen records in the Kootenai and Fisher River drainages in western Montana reveal a fivezone sequence of Holocene vegetation change. Deposition of Glacier Peak Ash-Layer G (ca. 10,540 ± 660 yr B.P.) in the lowermost sediments (clay intermixed with pebbles) at Tepee Lake gives a minimum date for the initiation of sedimentation. Initial vegetation on the newly deglaciated terrain was dominated by Pinus (probably white bark pine) with small amounts of Gramineae, Picea and Abies, reflecting a relatively cool, moist macroclimate. Two vegetation units appear to contribute to Pollen Zone II (ca. 11,000–7100 yr B.P.): arboreal communities with pines, along with Pseudotsuga or Larix, or both, and treeless vegetation dominated by Artemisia. Pollen Zone II represents an overall warmer macroclimate than occurred upon ice withdrawal. After ca. 7100 yr B.P. (Pollen Zone III) diploxylon pines became a major pollen contributor near both Tepee Lake and McKillop Creek Pond, indicating an expansion of xerophytic forest (P. contorta and P. ponderosa) along with an increase in the prominence of Pseudotsuga menziesii or Larix occidentalis, or both. Artemisia briefly expanded coverage near Tepee Lake concomitant with the Mazama ashfall ca. 6700 yr B.P. A short-term climatic trend with more available water began after ca. 4000 yr B.P. as Abies (probably A. grandis) along with Picea engelmannii became a more regular component of the forest surrounding both sites. Emergence of the modern macroclimate is indicated primarily with the first regular appearance of Tsuga heterophylla in the pollen record by ca. 2700 yr B.P., synchronous with the development of western hemlock forest within the same latitudes in northern Idaho and northeastern Washington.     

Design and analysis of sampling experiments — A sensitivity approach

In this paper, the question of the sensitivity to experimental error of results derived from steady-state sampling experiments in separation (specifically mineral processing) plants is addressed. The main tools used are those of network topology and numerical linear algebra. The techniques developed permit the assessment of alternative experimental designs for sensitivity to experimental error, and the choice of insensitive methods of data reduction. The techniques are illustrated by analysis of two actual sampling experiments.     

Vegetation and climate changes during the Eemian interglacial in Central and Eastern Europe: comparative analysis of pollen data

Velichko, A. A., Novenko, E. Y., Pisareva, V. V., Zelikson, E. M., Boettger, T. & Junge, F. W. 2005 (May): Vegetation and climate changes during the Eemian interglacial in Central and Eastern Europe: comparative analysis of pollen data. Boreas , Vol. 34, pp. 207–219. Oslo. ISSN 0300–9483.
The article discusses pollen data from Central and Eastern Europe and provides insight into the climate and vegetation dynamics throughout the Eemian interglacial (including preceding and succeeding transitional phases). Three sections with high resolution pollen records are presented. Comparison of the data indicates that the range of climatic and environmental changes increased from west to east, whereas the main phases of vegetation development appear to have been similar throughout the latitudinal belt. At the interglacial optimum, the vegetation in both Central and Eastern Europe was essentially homogeneous. An abrupt change marks the Saalian/Eemian boundary (transition from OIS 6 to OIS 5e), where environmental fluctuations were similar to those detected at the transition from the Weichselian to the Holocene (Allerød and Dryas 3). Transition from the Eemian to the Weichselian was gradual in the western part of the transect, with forest persisting. In the east, fluctuations of climate and vegetation were more dramatic; forest deteriorated and was replaced by cold open landscapes.     

Structure of Palaeogene sediments in east Ellesmere Island: Constraints on Eurekan tectonic evolution and implications for the Nares Strait problem

The “Nares Strait problem” represents a debate about the existence and magnitude of left-lateral movements along the proposed Wegener Fault within this seaway. Study of Palaeogene Eurekan tectonics at its shorelines could shed light on the kinematics of this fault. Palaeogene (Late Paleocene to Early Eocene) sediments are exposed at the northeastern coast of Ellesmere Island in the Judge Daly Promontory. They are preserved as elongate SW–NE striking fault-bounded basins cutting folded Early Paleozoic strata. The structures of the Palaeogene exposures are characterized by broad open synclines cut and displaced by steeply dipping strike-slip faults. Their fold axes strike NE–SW at an acute angle to the border faults indicating left-lateral transpression. Weak deformation in the interior of the outliers contrasts with intense shearing and fracturing adjacent to border faults. The degree of deformation of the Palaeogene strata varies markedly between the northwestern and southeastern border faults with the first being more intense. Structural geometry, orientation of subordinate folds and faults, the kinematics of faults, and fault-slip data suggest a multiple stage structural evolution during the Palaeogene Eurekan deformation: (1) The fault pattern on Judge Daly Promontory is result of left-lateral strike-slip faulting starting in Mid to Late Paleocene times. The Palaeogene Judge Daly basin formed in transtensional segments by pull-apart mechanism. Transpression during progressive strike-slip shearing gave rise to open folding of the Palaeogene deposits. (2) The faults were reactivated during SE-directed thrust tectonics in Mid Eocene times (chron 21). A strike-slip component during thrusting on the reactivated faults depends on the steepness of the fault segments and on their obliquity to the regional stress axes.Strike-slip displacement was partitioned to a number of sub-parallel faults on-shore and off-shore. Hence, large-scale lateral movements in the sum of 80–100 km or more could have been accommodated by a set of faults, each with displacements in the order of 10–30 km. The Wegener Fault as discrete plate boundary in Nares Strait is replaced by a bundle of faults located mainly onshore on the Judge Daly Promontory.     

Mechanism of loading on plates due to explosive detonation

This paper investigates the various mechanisms and parameters that are responsible for delivering impulse to a vehicle that is unfortunate enough to detonate a buried mine. Small scale tests are used to examine the effects of air blast or ejected sand in imparting impulse to a plate that is located above the surface of the saturated soil that contains the explosive. Parameters such as confinement, stand off distance, depth of burial of the explosive, density of the soil, and saturation level of the soil are also examined.     

Did Paleogene North Atlantic rift-related eruptions drive early Eocene climate cooling?

The delivery of volcanogenic sulphur into the upper atmosphere by explosive eruptions is known to cause significant temporary climate cooling. Therefore, phreatomagmatic and phreatoplinian eruptions occurring during the final rifting stages of active flood basalt provinces provide a potent mechanism for triggering climate change.

During the early Eocene, the northeast Atlantic margin was subjected to repeated ashfall for 0.5 m.y. This was the result of extensive phreatomagmatic activity along 3000 km of the opening northeast Atlantic rift. These widespread, predominantly basaltic ashes are now preserved in marine sediments of the Balder Formation and its equivalents, and occur over an area extending from the Faroe Islands to Denmark and southern England. These ash-bearing sediments also contain pollen and spore floras derived from low diversity forests that grew in cooler, drier climates than were experienced either before or after these highly explosive eruptions. In addition, coeval plant macrofossil evidence from the Bighorn Basin, Wyoming, USA, also shows a comparable pattern of vegetation change. The coincidence of the ashes and cooler climate pollen and spore floras in northwest Europe identifies volcanism as the primary cause of climate cooling. Estimates show that whilst relatively few phreatomagmatic eruptive centres along the 3000 km opening rift system could readily generate 0.5–1 °C cooling, on an annual basis, only persistent or repeated volcanic phases would have been able to achieve the long-term cooling effect observed in the floral record. We propose that the cumulative effect of repeated Balder Formation eruptions initiated a biodiversity crisis in the northeast Atlantic margin forests. Only the decline of this persistent volcanic activity, and the subsequent climatic warming at the start of the Eocene Thermal Maximum allowed the growth of subtropical forests to develop across the region.     

Helical probe tests in residual soils of the Appalachian Piedmont

Helical probe tests (HPT) are a quick and economical means for manual field testing of soils to depths of 1.5 m with readings taken at 0.15-m intervals in only 10 min. The equipment is lightweight (only 2 kg) and thus amenable to deploy on initial site reconnaissance explorations, shallow pavement projects, earth retention walls, and/or compaction of fills. Although suitable for use in a variety of geomaterials: sands, silts, clays, and mixed soils, the specific application to residual fine sandy silts and silty fine sands of the Appalachian Piedmont and Blue Ridge geologic provinces is shown here. Existing relationships for converting the measured HPT torque reading to equivalent cone penetration testing (CPT) tip resistances are reviewed, as well as other trends.