Ferrous phosphate surface precipitates resulting from the reduction of intragrain 6-line ferrihydrite by Shewanella oneidensis MR-1

The reductive biotransformation of 6-line ferrihydrite located within porous silica (intragrain ferrihydrite) by Shewanella oneidensis MR-1 was investigated and compared to the behavior of 6-line ferrihydrite in suspension (free ferrihydrite). The effect of buffer type (PIPES and NaHCO₃), phosphate (P), and an electron shuttle (AQDS) on the extent of reduction and formation of Fe(II) secondary phases was investigated under anoxic conditions. Electron microscopy and micro X-ray diffraction were applied to evaluate the morphology and mineralogy of the biogenic precipitates and to study the distribution of microorganisms on the surface of porous silica after bioreduction. Kinetic reduction experiments with free and intragrain ferrihydrite revealed contrasting behavior with respect to the buffer and presence of P. The overall amount of intragrain ferrihydrite reduction was less than that of free ferrihydrite [at 5 mmol L⁻¹ Fe(III)_T]. Reductive mineralization was not observed in the intragrain ferrihydrite incubations without P, and all biogenic Fe(II) concentrated in the aqueous phase. Irrespective of buffer and AQDS addition, rosettes of Fe(II) phosphate of approximate 20-30 μm size were observed on porous silica when P was present. The rosettes grew not only on the silica surface but also within it, forming a coherent spherical structure. These precipitates were well colonized by microorganisms and contained extracellular materials at the end of incubation. Microbial extracellular polymeric substances may have adsorbed Fe(II) promoting Fe(II) phosphate nucleation with subsequent crystal growth proceeding in different directions from a common center.     

Fast-changing processes in a medium subject to loading as detected by resistivity measurements

Making measurements of electric resistivity at 16 s intervals, the authors noticed fast changes of this parameter prior to the occurrence of the main fracture. The changes are superposed on bay pulsations of increasing amplitude and decreasing period. This finding opens prospects for a wider use of an electric resistivity method and proves the high quality of automatic instruments, in particular their high resolution. It also gives evidence for the occurrence of short-period precursors in the fracture zone while the main fracture is being formed.     

Community capacity amongst people living with HIV/AIDS

Mobilisation of people living with HIV/AIDS in the 1980s was tied to social identity and the public rendering of AIDS as a gay disease. This activism has continued in large cities alongside new streams of mobilization addressing the needs of groups such as women and Aboriginal peoples living with HIV. We draw on interviews conducted with six people living with HIV/AIDS in a small Ontario city where the population does not allow for services tailored to specific groups. We investigate experiences of social engagement amongst people living with, and affected by, HIV/AIDS and examine why efforts to establish a community-based participatory research project was unsuccessful. Drawing from indicators of community capacity developed by Jackson et al. (Health Promot Int 18(4): 339–350, 2003) we identify the role of stigma both amongst different groups living with HIV/AIDS and the wider public as undermining a common sense of community and, potentially, our efforts to establish a community-based participatory research process.     

能源与全球环境

目前,“可再生能源”这个词已进入技术发展的阶段。我们目前利用的能源是不可再生的。我们生活在都市中。由于太阳光照射1小时的能量即可满足我们一年的能源需要,今后的能源利用必定要考虑太阳能。利用地球内部的热量梯度即地热能在今后亦是诱人的。原子能尤其是聚变能的潜力极大,但尚没有迹象表明,人类非得将精力消耗在利用裂变能上不可,尽管目前这方面的技术有被滥用的趋势。     

Seismic Hazard Studies in the U.K.: Source Specification Problems of Intraplate Seismicity

Although the U.K. is in an area of only low to moderate seismicity, the seismic hazard is sufficient to pose a threat to sensitive structures such as chemical plants and nuclear facilities. In quantifying the level of hazard by conventional probabilistic methodology, however, some problems arise in attempting to interpret earthquake data in terms of geological structure and faults. In the U.K., not only is it impossible to identify any demonstrably active faults, but also it is extremely difficult to discern any relationship between the pattern of seismicity and local or regional geological structure.This study discusses the use of two zonation approaches which complement each other in such a way that the general character and trend of seismicity is preserved. In one approach, the zonation is informed by the structural geology, where possible; geological zonation is avoided if it produces sources with heterogeneous seismicity. In the other approach, the record of past earthquakes is divided up into very small zones around individual epicentres or groups of epicentres, the size of each zone usually being proportional to the uncertainty in the epicentral determination of the appropriate event. This zonation preserves an observed tendency of some British earthquakes to repeat themselves. It is suggested that, in intraplate areas such as the U.K., it is often inappropriate to attempt to model individual fault sources. No faults in the U.K. are provably active. Because an earthquake of moderate size can occur on a very short fault segment, it is impractical to restrict fault modelling to major features. Even the two largest U.K. faults, suspected to be active, pose problems in attributing historical seismicity to them as distinct features.     

Dawn; the Vesta–HED connection; and the geologic context for eucrites,diogenites, and howardites

The Dawn mission has provided new evidence strengthening the identification of asteroid Vesta as the parent body of the howardite, eucrite, and diogenite (HED) meteorites. The evidence includes Vesta's petrologic complexity, detailed spectroscopic characteristics, unique space weathering, diagnostic geochemical abundances and neutron absorption characteristics, chronology of surface units and impact history, occurrence of exogenous carbonaceous chondritic materials in the regolith, and dimensions of the core, all of which are consistent with HED observations and constraints. Global mapping of the distributions of HED lithologies by Dawn cameras and spectrometers provides the missing geologic context for these meteorites, thereby allowing tests of petrogenetic models and increasing their scientific value.     

Spatio-temporal changes of marine macrobenthic community in sub-tropical waters upon recovery from eutrophication. I. Sediment quality and community structure

A two-year study was conducted in the vicinity of a harbour in sub-tropical Hong Kong, to examine the progress of improvement in sediment quality and recovery of macrobenthic community upon cessation of organic pollution caused by sewage discharge. Median sediment particle diameter (Mdphi) and levels of total organic carbon (TOC), total Kjeldahl nitrogen (TKN), ammonia-nitrogen (NH(3)-N) and total phosphorus (TP), as well as macrobenthic species composition and abundance were determined bi-monthly at three inside-harbour and two outside-harbour locations. At the two inside-harbour locations, significantly higher levels of TOC, TKN, NH(3)-N and TP in sediments were observed than the outside-harbour locations. However, no significant temporal change of nutrient levels was detected at all sampling locations during the two-year study, except a significant decrease in TKN and NH(3)-N levels at one outside-harbour location and a decline in NH(3)-N content at another outside-harbour location. Spatially, the highest in mean total species number, individual number, species diversity H' and lowest evenness J was found at one outside-harbour location, whereas the other four locations had relatively similar values. H' was negatively correlated with TOC, TKN, NH(3)-N and TP content in sediments while J was positively correlated with MDphi. Across the study period, the patterns of macrobenthic community were significantly different among all samplings and that the spatial difference of benthic community was best correlated with MDphi, TOC, TKN and water depth. A weak sign of recovery in macrobenthic community structure was detected at inside-harbour locations, with replacement of opportunistic by ubiquitous species over the two-year study. The slow recovery of macrobenthic community was related to sediment characteristics. Results of a larval settlement bioassay using the polychaete Capitella sp. I also demonstrated that the inside-harbour sediments were still unfavourable for colonization and larval settlement of species sensitive to pollution. The slow biodegradation of the organic pollutants and continuous presence of heavy metals in the sediment may hinder settlement and colonization of benthic animals. However, increases of H' and J were observed in a longer time scale when comparing the present data with those obtained four years ago. This suggested that a detectable recovery of benthic community in the harbour may take at least three years and a complete recovery may even take longer duration.     

The geoelectric field at Vostok, Antarctica: its relation to the interplanetary magnetic field and the cross polar cap potential difference

The vertical geoelectric field measured at Vostok, Antarctica (78.5°S, 107°E, L=75.0) over the 13 month interval May 1979–May 1980 is correlated with the interplanetary magnetic field (IMF) components B_y and B_z at times when Vostok is connected to the dayside magnetosphere. No significant association with IMF B_x is found. The interaction of the solar wind and the Earth’s magnetic field generally results in anti-sunward plasma flow in the high-latitude, polar ionosphere driven by a dawn-to-dusk, cross polar cap potential difference pattern. Using the IZMEM model to infer the contribution of the cross polar cap potential difference to the potential difference between the ionosphere and the ground at Vostok for the measured IMF conditions, we show that this provides a viable mechanism for the IMF associations found. We demonstrate that the direct association of the geoelectric field with the cross polar cap potential difference is independent of a result (Park, 1976. Solar magnetic sector effects on the vertical atmospheric electric field at Vostok, Antartica. Geophysical Research Letters 3(8), 475–478) showing an 15% decrease in the vertical geoelectric field measured at Vostok, 1–3 days after the passage of IMF sector boundaries. Evidence is also presented supporting the Park result, for which a mechanism is yet to be confirmed.