Some regularity in the process of re-awakening of andesite and dacite volcanoes: specific features of the 1982 El Chichón volcano,México reactivation

El Chichón volcano is an andesite stratovolcano in southern México. It erupted in March 1982, after about 550 years of quiescence. The 1982 eruption of El Chichón has not been followed by the growth of a lava dome within the newly formed crater. This is rather anomalous since the construction of a new dome after the destruction of an old one is a common process during the eruptions at andesite and dacite volcanoes. To discuss this anomalous aspect of the El Chichón eruption, some regularity in the process of re-awakening of dormant (here defined as a period of quiescence of more than 100 years) andesite and dacite volcanoes are studied based on the seismic activity recorded at the volcanoes Bezymianny, Mount St. Helens, El Chichón, Unzen, Pinatubo and Soufrière Hills. Three stages were identified in the re-awakening activity of these volcanoes: (1) preliminary seismic activity, leading up to the first phreatic explosion; (2) activity between the first and the largest explosions; (3) post-explosion dome-building process. The eruptions were divided into two groups: low-VEI (Volcanic Explosivity Index) and the long duration stage-1 events (Unzen, 1991 and Soufrière Hills volcano, 1995) and high-VEI and the short duration stage-1 events (Bezymianny, 1956; Mount St. Helens, 1980; El Chichón, 1982 and Pinatubo, 1992). The comparative analysis of the seismo-eruptive activity of two eruptions of the second group, the 1980 of Mt. St. Helens and the 1982 of El Chichón, produced an explanation the absence of new dome building during the 1982 eruption of El Chichón volcano. It may be explained in terms of the unusually rapid emission of gas and water from the magmatic and hydrothermal system beneath the volcano during a relatively short sequence of large explosions that could have sharply increased the viscosity of the magma making impossible its exit to the surface.     

Fumarolic activity of Avachinsky and Koryaksky volcanoes, Kamchatka, from 1993 to 1994

 Volcanic gas and condensate samples were collected in 1993–1994 from fumaroles of Koryaksky and Avachinsky, basaltic andesite volcanoes on the Kamchatka Peninsula near Petropavlovsk–Kamchatsky. The highest-temperature fumarolic discharges, 220  °C at Koryaksky and 473  °C at Avachinsky, are water-rich (940–985 mmol/mol of H₂O) and have chemical and isotopic characteristics typical of Kamchatka–Kurile, high- and medium-temperature volcanic gases. The temperature and chemical and water isotopic compositions of the Koryaksky gases have not changed during the past 11 years. They represent an approximate 2 : 1 mixture of magmatic and meteoric end members. Low-temperature, near-boiling-point discharges of Avachinsky Volcano are water poor (≈880 mmol/mol); Their compositions have not changed since the 1991 eruption, and are suggested to be derived from partially condensed magmatic gases at shallow depth. Based on a simple model involving mixing and single-step steam separation, low water and high CO₂ contents, as well as the observed Cl concentration and water isotopic composition in low-temperature discharges, are the result of near-surface boiling of a brine composed of the almost pure condensed magmatic gas. High methane content in low-temperature Avachinsky gases and the 220  °C Koryaksky fumarole, low C isotopic ratio in CO₂ at Koryaksky (–11.8‰), and water isotope data suggest that the "meteoric" end member contains considerable amounts of the regional methane-rich thermal water discovered in the vicinity of both volcanoes. Received: 2 May 1996 / Accepted: 5 November 1996     

Seismicity of an andesitic volcano during block-lava effusion: Volcán de Colima, México, November 1998–January 1999

The block-lava effusion at Volcán de Colima, México began on November 20, 1998, after 12 months of seismic activity, and ended about 80 days later. Three types of seismic events were observed during the lava effusion. Volcano—tectonic earthquakes occurred mainly at the very beginning and after the termination of lava effusion. Explosion earthquakes occurred frequently during the period of the maximum rate in lava effusion. The remainder of the seismic signals were associated with pyroclastic flows and rockfalls from the lava dome. These latter signals increased sharply in number at the onset of lava effusion. The rate of occurrence remained high when the lava discharge rate decreased but gradually decreased after the termination of lava effusion. Maximum daily durations of seismic signals are proportional to the daily volumetric output of lava, indicating the dependence of the number of pyroclastic flows on the rate of lava output. A log-log plot of seismic signal duration vs. number of events with this duration displays a linear relationship. The short-period seismic signals can be divided into three categories based on duration: short events with durations less than 100 s; intermediate events with durations between 100 and 250 s; and long events with durations longer than 250 s. We infer that long events correspond to pyroclastic flows with mean deposit volume 2×10⁵ m³, and intermediate events represent pyroclastic flows with mean deposit volume 1×10³ m³.Editorial responsibility: J McPhie     

Relation Between Normalized Axial Stress and Failure Strain in Heterogeneous Carbonate Rocks Exhibiting Large Axial Strains

A semi-analytical equation for the modeling of stress–strain relationship for heterogeneous carbonate rocks exhibiting large axial strains (ε_af > 1%) is formulated. The equation is derived by modifying the stress–strain model based on Haldane’s distribution proposed by Palchik (2006) for carbonate rocks exhibiting ε _af ≤ 1%. The developed exponential model is used to relate normalized axial stress (σ _a/σ _c) over the whole pre-failure strain range to current axial strain (ε _a) and failure strain (ε _af). For carbonate rocks exhibiting ε _af > 1%, the value of pre-calculated parameter δ involved in the stress–strain model is not constant, but dependent on the failure strain value (ε _af). The normalized stress–strain model can be used to calculate the failure strain in terms of uniaxial compressive strength and stress–strain measurement at one point only. The advantages of the failure strain model and ways of its use in engineering practice are discussed.     

The methodology of quantification of volcanic explosions from broad-band seismic signals and its application to the 2004–2005 explosions at Volcán de Colima, Mexico

A methodology is proposed for the quantification of volcanic explosions based on three parameters derived from broad-band seismic signals: the counter force of the eruption F , the power of the explosion P and the duration of the upward movement of the gas slug in the conduit to the free surface of magma, D . This methodology was applied to the 2004–2005 sequence of explosions at Volcán de Colima, Mexico. The broad-band records of more than 100 explosive events were obtained at a distance of 4 km from the crater. We determined the counter force of the eruption by modelling the low-frequency impulse of the seismic records of 66 volcanic explosions and estimated the power of 116 explosions from the spectra of the high-frequency impulse. The power of Colima explosions spans five orders of magnitude; the counter force spans four orders of magnitude. We show that the power of a volcanic explosion is proportional to the counter force of the eruption. These parameters may be used for the elaboration of a scale of volcanic explosions.     

Uranium Behavior in the Process of Primary Pitchblende Ores Alteration by the Post‐ore Hydrothermal Solutions: An Application to Assessment of Uranium Migration from Underground Spent Nuclear Fuel Repositories

It has been shown that the main uranium ore mineral, pitchblende (uranium dioxide), is a natural analog of synthetic uraninite (also uranium dioxide), which constitutes 96% of spent nuclear fuel (SNF). Geochronological studies of the U‐Pb isotope systems in unaltered pitchblende from the orebodies reveal that these systems remained completely closed over the entire period (approximately 135 Ma) since the formation of the deposits. The bulk of the primary uranium ores within the Streltsovskoye ore field was influenced to various degrees by post‐ore hydrothermal solutions that led to pitchblende spherulites being replaced by pseudomorphs of an amorphous phase with a U‐Si composition; this phase also re‐precipitated in veinlets proximal to the pitchblende pseudomorphs. A technique specially developed by the authors was used to carry out quantitative counts of the abundance of uranium minerals by calculating the uranium mass balance in one of the orebodies subjected to hydrothermal alteration. The calculations reveal minimal uranium loss from the orebody. Uranium liberated in the process of the pseudomorphic replacement of pitchblende was immediately fixed, in situ, in the newly formed coffinite‐like amorphous U‐Si phase as a result of the development of an efficient geochemical barrier that prevented the long‐distance migration of uranium. In assessing the long‐term safety of underground SNF repositories, the results of the present study give us confidence that SNF uraninite, in terms of the preservation of its integrity as a mineral phase, provides for the reliable long‐term isolation of uranium, transuranium elements, and fission products that are “sealed” in the uraninite matrix. In the case of the mineral transformation of the uraninite matrix by hydrothermal solutions, the liberated uranium would be efficiently immobilized by the newly formed amorphous U‐Si phase.     

Relationship between tilt changes and effusive-explosive episodes at an andesitic volcano: the 2004–2005 eruption at Volcán de Colima,México

Continuous tilt changes during the 2004–2005 effusive-explosive episodes at Volcán de Colima (México) were recorded simultaneously by two tiltmeters installed on opposite sides of the volcano at elevations of 2200 m and 3060 m above sea level. Data indicate that the 2004 lava extrusion was preceded by an inflation accompanied by a deflation. The 2005 explosion sequences were associated with a deflationary–inflationary tilt. The period between the 2004 extrusion and the 2005 explosions was characterized by an inflationary tilt during a 3 month period. Two deformation sources were located. The first was situated at a depth between 300 m and 1800 m beneath the crater at the northern flank of the volcano and was responsible for volcano deformation during the preliminary September 2004 stage, the October 2004 extrusion, and the initial stage of the transition period and the March 2005 explosion sequence. The second source was located at a depth between 1800 m and 2800 m beneath the crater at the southern flank of the volcano and was responsible for volcano deformation during the final stage of the transition period and the May–June 2005 explosion sequence.     

On the Ratios between Elastic Modulus and Uniaxial Compressive Strength of Heterogeneous Carbonate Rocks

The ratios M _R = E/σ _c for 11 heterogeneous carbonate (dolomites, limestones and chalks) rock formations collected from different regions of Israel were examined. Sixty-eight uniaxial compressive tests were conducted on weak-to-strong (5 MPa < σ _c < 100 MPa) and very strong (σ _c > 100 MPa) rock samples exhibiting wide ranges of elastic modulus (E = 6100–82300 MPa), uniaxial compressive strength (σ _c = 14–273.9 MPa), Poisson's ratio (ν = 0.13–0.49), and dry bulk density (ρ = 1.7–2.7 g/cm³). The observed range of M _R = 60.9–1011.4 and mean value of M _R = 380.5 are compared with the results obtained by Deere (Rock mechanics in engineering practice, Wiley, London, pp 1–20, 1968) for limestones and dolomites, and the statistical analysis of M _R distribution is performed. Mutual relations between E, σ _c, ρ, M _R for all studied rocks, and separately for concrete rock formations are revealed. Linear multiple correlations between E on the one hand and σ _c and ρ on the other for Nekorot and Bina limestone and Aminadav dolomite are obtained. It is established that the elastic modulus and M _R in very strong carbonate samples are more correlated with ρ−σ _c combination and ε _a max, respectively, than in weak to strong samples. The relation between M _R and maximum axial strain (ε _a max) for all studied rock samples (weak-to-strong and very strong) is discussed.