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101.
The chemical and isotopic composition of pore fluids is presented for five deep-rooted mud volcanoes aligned on a transect across the Gulf of Cadiz continental margin at water depths between 350 and 3860 m. Generally decreasing interstitial Li concentrations and 87Sr/86Sr ratios with increasing distance from shore are attributed to systematically changing fluid sources across the continental margin. Although highest Li concentrations at the near-shore mud volcanoes coincide with high salinities derived from dissolution of halite and late-stage evaporites, clayey, terrigenous sediments are identified as the ultimate Li source to all pore fluids investigated. Light δ7Li values, partly close to those of hydrothermal vent fluids (δ7Li: +11.9‰), indicate that Li has been mobilized during high-temperature fluid/sediment or fluid/rock interactions in the deep sub-surface. Intense leaching of terrigenous clay has led to radiogenic 87Sr/86Sr ratios (0.7106) in pore fluids of the near-shore mud volcanoes. In contrast, non-radiogenic 87Sr/86Sr ratios (0.7075) at the distal locations are attributed to admixing of a basement-derived fluid component, carrying an isotopic signature from interaction with the basaltic crust. This inference is substantiated by temperature constraints from Li isotope equilibrium calculations suggesting exchange processes at particularly high temperatures (>200 °C) for the least radiogenic pore fluids of the most distal location.Advective pore fluids in the off-shore reaches of the Gulf of Cadiz are influenced by successive exchange processes with both oceanic crust and terrigenous, fine-grained sediments, resulting in a chemical and isotopic signature similar to that of fluids in near-shore ridge flank hydrothermal systems. This suggests that deep-rooted mud volcanoes in the Gulf of Cadiz represent a fluid pathway intermediate between mid-ocean ridge hydrothermal vent and shallow, marginal cold seep. Due to the thicker sediment coverage and slower fluid advection rates, the overall geochemical signature is shifted towards the sediment-diagenetic signal compared to ridge flank hydrothermal environments.  相似文献   
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GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.  相似文献   
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We investigate the properties of the first galaxies at   z ≳ 10  with highly resolved numerical simulations, starting from cosmological initial conditions and taking into account all relevant primordial chemistry and cooling. A first galaxy is characterized by the onset of atomic hydrogen cooling, once the virial temperature exceeds  ≃104 K  , and its ability to retain photoheated gas. We follow the complex accretion and star formation history of a  ≃5 × 107 M  system by means of a detailed merger tree and derive an upper limit on the number of Population III (Pop III) stars formed prior to its assembly. We investigate the thermal and chemical evolution of infalling gas and find that partial ionization at temperatures  ≳104 K  catalyses the formation of  H2  and hydrogen deuteride, allowing the gas to cool to the temperature of the cosmic microwave background. Depending on the strength of radiative and chemical feedback, primordial star formation might be dominated by intermediate-mass Pop III stars formed during the assembly of the first galaxies. Accretion on to the nascent galaxy begins with hot accretion, where gas is accreted directly from the intergalactic medium and shock heated to the virial temperature, but is quickly accompanied by a phase of cold accretion, where the gas cools in filaments before flowing into the parent halo with high velocities. The latter drives supersonic turbulence at the centre of the galaxy and could lead to very efficient chemical mixing. The onset of turbulence in the first galaxies thus likely marks the transition to Pop II star formation.  相似文献   
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Despite the important role played by the Sardinia‐Corsica block in the reconstruction of the Western Mediterranean geodynamics, the extent of involvement of the “Autochthonous” European margin exposed in Corsica (France) (i.e., Hercynian Corsica) in the Alpine orogeny remains uncertain. Stratigraphic and sedimentological studies in the post‐Variscan deposits on the Hercynian Corsica are scarce and even scarcer are the structural and metamorphic constraints. To face these uncertainties, we present new stratigraphic, structural and metamorphic data from the area of Razzo Bianco, Central Corsica, where a complete sequence belonging to the European continental margin is exposed. Field and structural investigations demonstrate that the sequence represents the easternmost edge of the downgoing European plate. Metamorphic studies on the Eocene deposits indicate that the margin was buried at depth up to blueschist facies conditions and, subsequently, it was progressively exhumed mainly through the activation of oblique top‐to‐the NW shear zones.  相似文献   
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