Altitude variation of the plasmapause signature in the main ionospheric trough

The projection of the plasmapause magnetic-field lines to low altitudes, where the light-ion chemistry is dominated by O⁺, tends to occur near the minimum electron density in the main (midlatitude) electron density trough at night. With increasing altitude in the trough, where H⁺ emerges as the dominant ion on the low-latitude boundary, we have found cases where the plasmapause field lines are located on the sharp low-latitude side of the trough as expected if this topside ionosphere H⁺ distribution varies in step with the plasmapause gradient in the distant plasmasphere. These conclusions are based on near-equatorial crossings of the plasmapause (corresponding to the steep gradient in the dominant species H⁺) by the Explorer-45 satellite as determined from electric-field measurements by Maynard and Cauffman in the early 1970s and ISIS-2 ionospheric topside-sounder measurements. The former data have now been converted to digital form and made available at http://nssdcftp.gsfc.nasa.gov. The latter provide samples of nearly coincident observations of ionospheric main trough crossings near the same magnetic-field lines of the Explorer 45-determined equatorial plasmapause. The ISIS-2 vertical electron density profiles are used to infer where the F-region transitions from an O⁺ to a H⁺ dominated plasma through the main trough boundaries.     

A sensitive search for SO2 in the martian atmosphere: Implications for seepage and origin of methane

Mars was observed near the peak of the strongest SO₂ band at 1364-1373 cm⁻¹ with resolving power of 77,000 using the Texas Echelon Cross Echelle Spectrograph on the NASA Infrared Telescope Facility. The observation covered the Tharsis volcano region which may be preferable to search for SO₂. The spectrum shows absorption lines of three CO₂ isotopomers and three H₂O isotopomers. The water vapor abundance derived from the HDO lines assuming D/H = 5.5 times the terrestrial value is 12±1.0 pr. μm, in agreement with the simultaneous MGS/TES observations of 14 pr. μm at the latitudes (50° S to 10° N) of our observation. Summing of spectral intervals at the expected positions of sixteen SO₂ lines puts a 2σ upper limit on SO₂ of 1 ppb. SO₂ may be emitted into the martian atmosphere by seepage and is removed by three-body reactions with OH and O. The SO₂ lifetime, 2 years, is longer than the global mixing time 0.5 year, so SO₂ should be rather uniformly distributed across Mars. Seepage of SO₂ is less than 15,000 tons per year on Mars which is smaller than the volcanic production of SO₂ on the Earth by a factor of 700. Because CH₄/SO₂ is typically 10⁻⁴-10⁻³ in volcanic gases on the Earth, our results show seepage is unlikely to be the source of the recently discovered methane on Mars and therefore strengthen its biogenic origin.     

Dust particles in the atmospheres of terrestrial planets and their roles for prebiotic chemistry: An overview

The available literature on sources, chemical composition, and importance of dust particles for the origins of life is analyzed. The most abundant sources of dust on the early terrestrial planets are sedimentation of interplanetary dust, meteoritic/cometary impacts, and volcanic eruptions. Interplanetary dust can originate directly from interstellar space, from evaporation of cometary bodies, from collisional destruction of asteroidal and meteoritic bodies, and nucleation in sunspots. Many rather complex organic species, including those of prebiotic interest, have been identified in the interstellar medium and cometary dust. Some of them are believed to formvia catalytic processes on the surfaces of dust particles. However, the mechanisms are not known, and even simulating experiments are difficult to perform due to insufficient knowledge of physical conditions in the space media and of chemical composition and properties of the dust. Besides the catalytic roles, cometary dust is believed to be the best delivery vehicle for organic matter of space origin to the atmospheres of terrestrial planets. Abundant sources of catalytically active fine dust can be volcanoes. Various organic and biological compounds have been found in terrestrial volcanic gases and ash, which are assumed to formvia the catalytic Fischer-Tropsch reactions. At present the eruptions on the Earth provide a unique opportunity to observein situ the formation of organic matter, and knowledge of the ash composition and local conditions allows to perform simulating experiments.     

Precise temperature monitoring in boreholes: evidence for oscillatory convection? Part II: theory and interpretation

In the previous part of this work (Cermak, Safanda and Bodri, this volume p.MMM) we have described experimental data and quantified the heterogeneity features of the microtemperature time series. The spectral analysis and the local growth of the second moment technique revealed scaling structure of all observed time series generally similar and suggested the presence of two temperature forming processes. The longer-scale part can be attributed to the heat conduction in compositional and structural heterogeneous solid rocks, further affected by various local conditions. Short-scale temperature oscillations are produced by the intra-hole fluid convection due to inherent instability of water column filling the hole. Here we present how the observational evidence is supported by the results of the computer simulations. The exact modes of intra-hole convection may be different, ranging from quasi-periodic (“quiescent”) state to close of turbulence. As demonstrated by numerical modeling and referred on laboratory experiments, at higher Rayleigh numbers the periodic character of oscillation characteristic for “quiescent” regime is superseded by stochastic features. This so called “oscillatory” convection occurs due to instability within the horizontal boundary layers between the individual convectional cells. In spite of the fact that the basic convective cell motion is maintained and convection is characterized by slow motion, the oscillatory intra-hole flow and corresponding temperature patterns exhibit typical features of turbulence. The idea of boundary layer instability as a source of stochastic temperature fluctuations could explain many distinct features of borehole temperatures that previously cannot be interpreted.     

Evaluation of landfill disposal boundary by means of electrical resistivity imaging

This paper deals with an employment of electrical resistivity imaging (ERI) for survey of leachate content on the waste disposal site in Northern Israel. The research consisted of conducting ten ERI lines and drilling investigation wells. Data simulation used a 2D EarthImager inversion program. Analysis of 2D ERI interpretation results shows that determination of the boundary between the landfill body bottom intensively saturated with leachates and underlying layers of highly water saturated fat nonconsolidated clays presents a challenge. However, statistical analysis of ERI data indicates that standard deviation and confidence interval of a set of resistivity data measured in the landfill body are significantly larger than those in underlying clays. Moreover, maximum changes of these parameters are found on the boundary between landfill body and underlying soil, thus reflecting natural differences in scattering of resistivity data measured in these two objects.     

Early diagenetic vivianite [Fe3(PO4)2 · 8H2O] in a contaminated freshwater sediment and insights into zinc uptake: A μ-EXAFS, μ-XANES and Raman study

The sediments in the Salford Quays, a heavily-modified urban water body, contain high levels of organic matter, Fe, Zn and nutrients as a result of past contaminant inputs. Vivianite [Fe₃(PO₄)₂ · 8H₂O] has been observed to have precipitated within these sediments during early diagenesis as a result of the release of Fe and P to porewaters. These mineral grains are small (<100 μm) and micron-scale analysis techniques (SEM, electron microprobe, μ-EXAFS, μ-XANES and Raman) have been applied in this study to obtain information upon the structure of this vivianite and the nature of Zn uptake in the mineral. Petrographic observations, and elemental, X-ray diffraction and Raman spectroscopic analysis confirms the presence of vivianite. EXAFS model fitting of the FeK-edge spectra for individual vivianite grains produces Fe–O and Fe–P co-ordination numbers and bond lengths consistent with previous structural studies of vivianite (4O atoms at 1.99–2.05 Å; 2P atoms at 3.17–3.25 Å). One analysed grain displays evidence of a significant Fe³⁺ component, which is interpreted to have resulted from oxidation during sample handling and/or analysis. EXAFS modelling of the Zn K-edge data, together with linear combination XANES fitting of model compounds, indicates that Zn may be incorporated into the crystal structure of vivianite (4O atoms at 1.97 Å; 2P atoms at 3.17 Å). Low levels of Zn sulphate or Zn-sorbed goethite are also indicated from linear combination XANES fitting and to a limited extent, the EXAFS fitting, the origin of which may either be an oxidation artifact or the inclusion of Zn sulphate into the vivianite grains during precipitation. This study confirms that early diagenetic vivianite may act as a sink for Zn, and potentially other contaminants (e.g. As) during its formation and, therefore, forms an important component of metal cycling in contaminated sediments and waters. Furthermore, for the case of Zn, the EXAFS fits for Zn phosphate suggest this uptake is structural and not via surface adsorption.     

Nocturnal Near-Surface Temperature,but not Flow Dynamics,can be Predicted by Microtopography in a Mid-Range Mountain Valley

We investigate nocturnal flow dynamics and temperature behaviour near the surface of a 170-m long gentle slope in a mid-range mountain valley. In contrast to many existing studies focusing on locations with significant topographic variations, gentle slopes cover a greater spatial extent of the Earth’s surface. Air temperatures were measured using the high-resolution distributed-temperature-sensing method within a two-dimensional fibre-optic array in the lowest metre above the surface. The main objectives are to characterize the spatio-temporal patterns in the near-surface temperature and flow dynamics, and quantify their responses to the microtopography and land cover. For the duration of the experiment, including even clear-sky nights with weak winds and strong radiative forcing, the classical cold-air drainage predicted by theory could not be detected. In contrast, we show that the airflow for the two dominant flow modes originates non-locally. The most abundant flow mode is characterized by vertically-decoupled layers featuring a near-surface flow perpendicular to the slope and strong stable stratification, which contradicts the expectation of a gravity-driven downslope flow of locally produced cold air. Differences in microtopography and land cover clearly affect spatio-temporal temperature perturbations. The second most abundant flow mode is characterized by strong mixing, leading to vertical coupling with airflow directed down the local slope. Here variations of microtopography and land cover lead to negligible near-surface temperature perturbations. We conclude that spatio-temporal temperature perturbations, but not flow dynamics, can be predicted by microtopography, which complicates the prediction of advective-heat components and the existence and dynamics of cold-air pools in gently sloped terrain in the absence of observations.     

Non-linear elastic behaviour of damaged rocks

The pervasive damage of rocks by microcracks and voids strongly affects their macroscopic elastic properties. To evaluate the damage effects, we derive here the macroscopic stress-strain relations for a 3-D elastic solid with non-interacting cracks embedded inside a homogeneous matrix. The cracks considered are oriented either perpendicular to the maximum tension axis, or perpendicular to the maximum compression axis. In the first case they dilate during loading and in the second case they contract during loading. We derive a solution for the elastic energy of this rock following the self-consistent scheme of Budiansky & O'Connell (1976). The solution describes the stress-strain relations in terms of Λ^d and μ^d, which are the modified Lame constants, and an additional parameter Λ. The latter accounts for the non-linear behaviour of the solid and is related to crack density. The solution predicts a non-linear elastic rheology even for an infinitesimal strain of ɛ < 0.001, and abrupt change in the elastic moduli when the loading reverses from uniaxial compression to uniaxial tension.
We use the derived solution to analyse rock-mechanics experiments in which beams of Indiana limestone were deformed under four-point loading. This configuration provides simultaneously the apparent tensile and compressive moduli for small strains. The apparent moduli fit the effective elastic moduli calculated with the present damage model well, including the differences between tensile and compressive moduli.