Performance evaluation of normalized difference chlorophyll index in northern Gulf of Mexico estuaries using the Hyperspectral Imager for the Coastal Ocean

The Hyperspectral Imager for the Coastal Ocean (HICO) was used to derive chlorophyll-a (chl-a) based on the normalized difference chlorophyll index (NDCI) in two Gulf of Mexico coastal estuaries. Chl-a data were acquired from discrete in situ water sample analysis and above-water hyperspectral surface acquisition system (HyperSAS) remote sensing reflectance in Pensacola Bay (PB) and Choctawhatchee Bay (CB). NDCI algorithm calibrations and validations were completed on HICO data. Linear and best-fit (polynomial) calibrations performed strongly with R² of 0.90 and 0.96, respectively. The best validation of NDCI resulted with an R² of 0.74 and root-mean-square error (RMSE) of 1.64 µg/L. A strong spatial correspondence was observed between NDCI and chl-a, with higher NDCI associated with higher chl-a and these areas were primarily located in the northern PB and eastern CB at the river mouths. NDCI could be effectively used as a qualitative chl-a monitoring tool with a reduced need for site-specific calibration.     

On the affinity of Chuaria–Tawuia complex: A multidisciplinary study

In this study, biometric and structural engineering tool have been used to examine a possible relationship within Chuaria–Tawuia complex and micro-FTIR (Fourier Transform Infrared Spectroscopy) analyses to understand the biological affinity of Chuaria circularis Walcott, collected from the Mesoproterozoic Suket Shales of the Vindhyan Supergroup and the Neoproterozoic Halkal Shales of the Bhima Group of peninsular India. Biometric analyses of well preserved carbonized specimens show wide variation in morphology and uni-modal distribution. We believe and demonstrate to a reasonable extent that C. circularis most likely was a part of Tawuia-like cylindrical body of algal origin. Specimens with notch/cleft and overlapping preservation, mostly recorded in the size range of 3–5 mm, are of special interest. Five different models proposed earlier on the life cycle of C. circularis are discussed. A new model, termed as ‘Hybrid model’ based on present multidisciplinary study assessing cylindrical and spherical shapes suggesting variable cell wall strength and algal affinity is proposed. This model discusses and demonstrates varied geometrical morphologies assumed by Chuaria and Tawuia, and also shows the inter-relationship of Chuaria–Tawuia complex.Structural engineering tool (thin walled pressure vessel theory) was applied to investigate the implications of possible geometrical shapes (sphere and cylinder), membrane (cell wall) stresses and ambient pressure environment on morphologically similar C. circularis and Tawuia. The results suggest that membrane stresses developed on the structures similar to Chuaria–Tawuia complex were directly proportional to radius and inversely proportional to the thickness in both cases. In case of hollow cylindrical structure, the membrane stresses in circumferential direction (hoop stress) are twice of the longitudinal direction indicating that rupture or fragmentation in the body of Tawuia would have occurred due to hoop stress. It appears that notches and discontinuities seen in some of the specimens of Chuaria may be related to rupture suggesting their possible location in 3D Chuaria.The micro-FTIR spectra of C. circularis are characterized by both aliphatic and aromatic absorption bands. The aliphaticity is indicated by prominent alkyl group bands between 2800–3000 and 1300–1500 cm⁻¹. The prominent absorption signals at 700–900 cm⁻¹ (peaking at 875 and 860 cm⁻¹) are due to aromatic CH out of plane deformation. A narrow, strong band is centred at 1540 cm⁻¹ which could be COOH band. The presence of strong aliphatic bands in FTIR spectra suggests that the biogeopolymer of C. circularis is of aliphatic nature. The wall chemistry indicates the presence of ‘algaenan’—a biopolymer of algae.     

Discovery of animal eggs and embryos from the Ediacaran (Terminal Proterozoic) Chambaghat Formation,Krol Group,Himachal Lesser Himalaya

The globular to suboval microfossils with distinctively ornamented outer coverings interpreted as animal eggs and embryos have been discovered from the black phosphatic chert lentils of the Ediacaran (Terminal Proterozoic) Chambaghat Formation (Krol sandstone), Krol Group, Himachal Lesser Himalaya, India. Similar animal eggs and embryos have earlier been recorded only from the phosphorites of the uppermost Neoproterozoic Doushantuo Formation (Ca. 570±20 Ma) exposed at Weng’an, South China. Present record of eggs and embryos is comparable with extant eggs and embryos of cnidarians and bilaterians like molluscs, annelids and arthropods. The eggs and embryos from the Terminal Proterozoic rocks of India are the only one recorded from the equivalent stratigraphic horizon outside China. This discovery of eggs and embryos adds to the understanding the evolutionary trends in the Proterozoic metazoan life.     

Satellite-based monitoring of recent heavy flooding over north-eastern states of India in July 2019

Natural Hazards - South-west monsoon of 2019 advanced towards northern parts of India during the first week of July. Heavy-to-very-heavy rainfall events during July 05–16 resulted in severe...     

Controlled blasting in a limestone mine using electronic detonators: A case study

Except for very deep-seated deposits, open cast mining method has been recognized as the safest and most productive mode for mining minerals. Ever growing demand in minerals and coal has compelled the mine operators to increase the size of mine, which has resulted in an increasing trend towards large capacity open cast projects. Explosives and blasting techniques play a significant role in efficient opencast mining operations. There have been constant technological developments towards safer, faster, economical and more efficient blasting systems. Further, globally increased competitiveness has necessitated to carryout blasts in such a way that the desired degree of fragmentation is achieved in the primary blast, with minimum undesired side effects such as ground vibration, air blast/noise, flyrock, generation of oversize boulders, formation of toe, and over break or back break. Hence, the ultimate objective of the blasting engineer is to ensure that the blasts are carried out in an eco-friendly manner. This paper presents a case study of limestone mine where a controlled blasting was conducted near a green structure of wagon tippler (at 2 m) being constructed for foundation work of belt conveyor as the mine management wants to double the existing production. This paper deals with controlled blast design and its implementation using electronic detonators with signature hole technique.     

Prediction of hydraulic conductivity for soil–bentonite mixture

Owing to its low hydraulic conductivity, soil and bentonite mixture is applied as a liner material. However, the experimental determination of hydraulic conductivity, which is controlled by various physical, chemical and mineralogical factors, requires an expensive and time-consuming setup. In the present work, multigene symbolic, genetic programming was used to model functional relationships for hydraulic conductivity. The developed model was able to generalize highly nonlinear variations in data as well as predict system behavior from experimental observations. It was found that the predictions obtained from developed model agree well with experimental observations.     

Chronometry and formation pathways of gypsum using Electron Spin Resonance and Fourier Transform Infrared Spectroscopy

Gypsum is an authigenic precipitate that forms under periods of accentuated aridity and occurs widely in arid zones. However its use in quantitative paleoclimatology has been limited due to the absence of a method to determine the timing of its formation. We present here the results of a feasibility study that demonstrates that the timing of the formation event of gypsum can be estimated using Electron Spin Resonance (ESR) analysis. We used well documented samples from White Sands in New Mexico, USA, the Thar Desert, India and lakes in the Simpson Desert and Mallee Region, Australia and found that ESR ages could be obtained using radiation sensitive SO₄^?, SO₃^? radicals and a photobleachable signal O₃^?. ESR signals were consistent with control ages based on contextual information. These suggest that the dating signals (SO₄^?, SO₃^?) are stable over time scales >100 ka. We propose that this stability of the SO₄^? signals over geological time scales arises due to hydrogen bonding between the water proton and the SO₄^? radical and that the suitability of these radiation-induced radicals comes from their being a part of the host matrix. Further, ESR along with Fourier Transform Infrared (FT-IR) Spectroscopy methods additionally inform on the geochemical pathways for gypsum formation and help elucidate complex formation processes even in samples that appeared unambiguous gypsum precipitates. Thus, the presence of Hannebachite (CaSO₃.½H₂O) and Mn²⁺ in Thar and Australian samples suggested a reducing environment such that low valence sulfur reacted with CaCO₃ to form hannebachite and eventually gypsum. The presence of sulfur, partially as sulfite in Thar gypsum samples suggested that redox cycles were mediated by microbial activity. Absence of these features in White Sands samples suggested oxic conditions during gypsum precipitation.     

High energy transgressive deposits from the Late Jurassic of Wagad,Eastern Kachchh,India

The whole sedimentary succession (ca 600 m thick) of Wagad area ranging in age from Callovian to Early Kimmeridgian has been divided in to three Formations namely Washtawa, Kanthkot and Gamdau in ascending order. Prograding Kanthkot Formation was frequently interrupted by transgressions. Field and petrographic investigations revealed that the Kanthkot Formation represents three fossiliferous marker beds corresponding to Transgressive sequence I; Transgressive sequence II and Transgressive sequence III. These transgressive sequences are composed of two lithounits: medium to coarse grained/gritty, graded to massive, sheetlike, fossiliferous calcareous sandstone (storm lag unit I) and fossiliferous mudrocks (swell lag unit II). The thickness of the unit I varies from 5 to 75 cm and contains mostly convexly oriented shell fragments and whole shell of Pelecypods, Cephalopods and Brachiopods. Unit II (5–15 cm) is distinguished by sheetlike, massive or laminated, yellowish colour, soft fossiliferous mudrocks. This unit is intercalated with moderately bioturbated sandy siltstone. Unit I is dominant over Unit II in the sequences.Study suggests that the transgressive units were deposited close to wave base by high energy storm flows followed by low energy marine swells during transgression. The intense storms played a major role in the distribution of siliciclastics and nonclastic materials. Storms are evidenced by the occurrence of two distinctly different types of units (storm lags and swell lags). High energy levels are characterized by sand dominated sequence, abundance of reworked sediment particles, high proportion broken shells with convex up orientation and erosional and sharp nature of basal contacts of units together with well preserved bioclasts. Sudden short term changes from high to low energy during transgression are explained by the occurrence of medium to coarse grained siliciclastics interbedded with moderately bioturbated mudrocks. Moderately bedded individual strata, high content of coarse clastics along with polished granule size quartz and abundance of comminuted shells indicate a significant change in depositional setting, possibly closure approach of the source of terrigenous fraction or source uplift. Synrift sedimentation in the present study is documented by an abundance of coarse clastics and an over all aggradational nature of transgressive sequences.