Dependence of clinopyroxene composition on cooling rate in basaltic magmas: Implications for thermobarometry

The compositional variation of clinopyroxene and the partitioning of major elements between clinopyroxene and melt are estimated as a function of the cooling rate. Clinopyroxenes were crystallized under variable cooling regimes (15, 9.4, 3, 2.1, and 0.5 °C/min from 1250 down to 1000 °C) and at isothermal conditions of 1000 °C from a basaltic composition at a pressure of 500 MPa under anhydrous and hydrous (H₂O = 1.3 wt.%) conditions. The clinopyroxene chemistry shows that, as the cooling rate increases, crystals are progressively depleted in Ca, Mg, Fe²⁺ and Si and enriched in Na, Fe³⁺, Al (mainly Al^IV), and Ti. Di and Hd versus CaTs and CaFeTs form a continuous binary solid solution characterized by higher amounts of tschermakitic components with increasing cooling rate. Two parameters (DH = Di + Hd and TE = CaTs + CaFeTs + En) are calculated to describe the effect of cooling rate on the clinopyroxene composition. The variation of DH/TE with increasing cooling rate evidences the kinetic process induced by rapid cooling in basic rocks under hydrous and anhydrous conditions.Dynamic crystallization conditions affect the partitioning of major elements between clinopyroxene and melt; with increasing cooling rate, the value of crystal–melt partition coefficient departs from that obtained at the isothermal condition. However, in spite of these variations, the values of ^cpx–meltKd_Fe–Mg remain almost constant. Therefore, the Fe²–Mg exchange between clinopyroxene and melt is not suitable to prove the (dis)equilibrium conditions in basaltic cooling magmas, giving rise to possible mismatches in the application of thermobarometers. The results of our study are consistent with that observed at the margin of dikes or in the exterior portions of lavas, where the cooling rate is maximized and disequilibrium compositions of clinopyroxene have been found.     

Rapid estimation of ground-shaking maps for seismic emergency management in the Campania Region of southern Italy

Strong ground-shaking mapping soon after a moderate-to-large earthquake is crucial to recognize the areas that have suffered the largest damage and losses. These maps have a fundamental role for emergency services, loss estimation and planning of emergency actions by the Civil Protection Authorities. This is particularly important for areas with high seismic risk levels, such as the Campania-Lucania Region in southern Italy. Taking advantage of the Irpinia Seismic Network (ISNet), a recently installed dense and wide dynamic seismic network, we have developed a procedure for rapid estimation of ground-shaking maps after moderate-to-large earthquakes (GRSmap). This uses an optimal data gridding scheme designed to account for bi-dimensional features of strong ground-motion fields, such as directivity, radiation patterns and focal mechanisms, to which most damage can be correlated. The basis of the mapping technique is a triangulation procedure to locally correct predicted data at the triangle barycentres where their vertices correspond to seismic stations. The method has been tested off-line using a simulated M 6.6 earthquake located at the centre of ISNet and applied to data of the 23 November 1980 Irpina M 6.9 earthquake recorded by a sparse network. This has highlighted its ability to predict peak ground-motion parameters of large magnitude earthquakes with respect to the attenuation relationships.     

Use of interaction domains for a displacement-based design of caisson foundations

Acta Geotechnica - Caisson foundations, typically adopted for both onshore and offshore structures, are usually subject to combined loading acting during working conditions and exceptional events...     

Cooling and exhumation history of deep‐seated and shallow level,late Hercynian granitoids from Calabria

The thermal and exhumation history of late Hercynian granitoids from Calabria (Sila and Serre massifs) has been studied using thermobarometry and radiometric age determinations. The uplift and erosion which followed contractional tectonics of Tertiary age exposed in Calabria a nearly complete section of the Hercynian crust. Field data, constrained by igneous thermobarometrical data, have enabled us to draw simplified crustal profiles. In both the Sila and Serre massifs, granitoids make up the intermediate portions of the crustal sections and are stacked as tabular intrusions for up to 13 km cumulative thickness. Shallow granitoids are characterized by a weak fabric, mostly developed in the magmatic stage, whereas deep‐seated granitoids display a strong fabric developed in the magmatic state and, with decreasing temperatures, in the subsolidus state. The intrusive bodies were emplaced at 300–290 Ma, at a time when the Calabrian crust was undergoing extensional tectonics and crustal thinning. The subsequent post‐Hercynian evolution is recorded by Rb‐Sr dates of micas and fission track ages of zircon and apatite obtained from granitoids emplaced at different depths. A decrease in Rb‐Sr and fission track ages is observed as depth of emplacement increases. Data on the post‐Hercynian geological evolution of Calabria were used to model in three stages the cooling and exhumation history of deep‐seated and shallow granitoids. The first stage, in Permian to Triassic times, was characterized by slow erosion. It was followed by a second stage of extensional tectonics in Jurassic times. The third stage was exhumation during the Apenninic Orogeny. The model has generated two P–T–t arrays, one for deep‐seated and the other for shallow granitoids of the Serre massif. The T–t paths suggest that the dates of micas, zircon and apatite are cooling ages. They also show that deep‐seated granitoids remained at temperatures above the brittle–plastic transition for a long time, whereas shallow granitoids cooled rapidly. Distinct P–T–t paths explain why deep‐seated and shallow granitoids display different fabric and microstructural features. Copyright © 2000 John Wiley & Sons, Ltd.     

Petrology of basic and intermediate orogenic granitoids from the Sila Massif (Calabria,southern Italy)

Hercynian gabbroic, dioritic and tonalitic rocks crop out in the neighbourhood of Rovale (Sila Grande, Calabria). They make up a crude rectangular outcrop with the western part consisting of gabbroic rocks and the eastern of dioritic and tonalitic rocks. They come into contact with medium to high grade metapelites on the western side and with heterogeneous granodiorites on the other sides. In the gabbroic body both opx ± ol bearing cumulates and amphibole differentiates occur and are characterized by the widespread presence of brown pargasite. Sporadic magmatic to subsolidus corona textures between olivine and plagioclase or orthopyroxene and plagioclase can be observed and their preservation clearly suggests a post-tectonic emplacement for the gabbroic magma. Diorites and tonalites display hypidiomorphic textures free of olivine and orthopyroxene and bearing green Mg-hornblende. The granitoids, on the basis of chemical data, display orogenic features of the continent-continent collision type. The gabbroic rocks have high Al tholeiitic composition and fractionation of orthopyroxene and plagioclase played an important part in their evolution. The Rb/Sr isochron method did not give a precise emplacement age for the granitoids as a whole. Initial ⁸⁷Sr/⁸⁶Sr ratios (at 290 Ma) are higher in the gabbroic body (0.7091–0.7095) than in diorites and tonalites (0.7083–0.7092). Thus gabbroic rocks appear more displaced than diorites and tonalites towards crustal isotopic composition. The eNd data seem to confirm this feature, thus suggesting that the gabbroic rocks and diorites derived from distinct mantle magma batches. Interestingly, small isotropic gabbroic masses occur within the diorites and show general features that allow them to be considered as possibly parental with respect to the host diorites. The evolution to the dioritic composition might have occurred through fractionation and minor mixing with a more acidic component such as the northern granodiorites. Geochemical, Sr and Nd isotopic data indicate a scenario of a composite plutonic body formed by distinct magma batches of mixed crust and mantle origin.