Advanced frame element for seismic analysis of masonry structures: model formulation and validation

This paper presents a masonry panel model for the nonlinear static and dynamic analysis of masonry buildings suitable for the seismic assessment of new and existing structures. The model is based on an equivalent frame idealization of the structure and stems from previous research on force‐based frame elements. The element formulation considers axial, bending, and shear deformations within the framework of the Timoshenko beam theory. A phenomenological cyclic section law that accounts for the shear panel response is coupled, through equilibrium between shear and bending forces along the element, with a fiber‐section model that accounts for the axial and bending responses. The proposed panel model traces with a low computational burden and numerical stability the main aspects of the structural behavior of masonry panels and is suitable for analyses of multi‐floor buildings with a relatively regular distribution of openings and with walls and floors organized to grant a box‐like behavior under seismic loads. The model capabilities are validated though analyses of simple unreinforced masonry panels and comparisons with published experimental results. The model accuracy is strongly dependent on the fiber and shear constitutive laws used. However, the formulation is general, and laws different from those employed in this study are easily introduced without affecting the model formulation. Copyright © 2015 John Wiley & Sons, Ltd.     

40Ar–39Ar dating of volcanogenic products from the AND-2A core (ANDRILL Southern McMurdo Sound Project, Antarctica): correlations with the Erebus Volcanic Province and implications for the age model of the core

The AND-2A drillcore (Antarctic Drilling Program—ANDRILL) was successfully completed in late 2007 on the Antarctic continental margin (Southern McMurdo Sound, Ross Sea) with the aim of tracking ice proximal to shallow marine environmental fluctuations and to document the 20-Ma evolution of the Erebus Volcanic Province. Lava clasts and tephra layers from the AND-2A drillcore were investigated from a petrographic and stratigraphic point of view and analyzed by the ⁴⁰Ar–³⁹Ar laser technique in order to constrain the age model of the core and to gain information on the style and nature of sediment deposition in the Victoria Land Basin since Early Miocene. Ten out of 17 samples yielded statistically robust ⁴⁰Ar–³⁹Ar ages, indicating that the AND-2A drillcore recovered ≤230 m of Middle Miocene (∼128–358 m below sea floor, ∼11.5–16.0 Ma) and >780 m of Early Miocene (∼358–1093 m below sea floor, ∼16.0–20.1 Ma). Results also highlight a nearly continuous stratigraphic record from at least 358 m below sea floor down hole, characterized by a mean sedimentation rate of ∼19 cm/ka, possible oscillations of no more than a few hundreds of ka and a break within ∼17.5–18.1 Ma. Comparison with available data from volcanic deposits on land, suggests that volcanic rocks within the AND-2A core were supplied from the south, possibly with source areas closer to the drill site for the upper core levels, and from 358 m below sea floor down hole, with the “proto-Mount Morning” as the main source.     

Thick self-standing bent crystals as optical elements for a Laue lens for applications in astrophysics

In this paper we report progresses in the realization of self-standing bent crystals, which are suitable as optical elements for Laue lenses, i.e. for optic to focus hard X-rays in the 100–1000 keV energy range. The curvature of the crystals is a key factor to enhance diffraction efficiency and energy bandpass for such an optic. In particular, two bent crystals featuring a thickness of 5 mm, made of Si and Ge respectively, were produced at the Sensor and Semiconductor Laboratory in Ferrara, Italy. The crystals were bent through the application of a carbon fibre composite. This proved to be a relatively low cost method for crystal bending, suitable for mass production. The manufactured samples were characterised via optical interferometry, and showed a fairly uniform curvature. Finally, the samples were tested exploiting hard X-ray diffraction at the ID11 facility of the European Synchrotron Radiation Facility (ESRF) in Grenoble, France. A careful analysis of the experimental data highlighted that the samples feature large energy bandpass, wide geometrical acceptance for incoming hard X-rays, and high diffraction efficiency. We therefore conclude that such self-standing crystals are good candidates as Laue lens components for astrophysics applications.     

Removal of Lead, Copper, Zinc and Cadmium from Water Using Phosphate Rock

Removal of Pb2 ,Cu~(2 ),Zn~(2 )and Cd~(2 )from aqueous solutions by sorption on a natural phosphate rock(FAP)was investigated.The effects of the contact time and initial metal concentration were examined in the batch method.The percentage sorption of heavy metals from solution ranges generally between 50% and 99%.The amount of sorbed metal ions follows the order Cu>Pb>Cd>Zn. Heavy metal immobilization was attributed to both surface complexation of metal ions on the surface of FAP grains and partial dissolution and precipitation of a heavy metal-containing phosphate.The very low desorption ratio of heavy metals further supports the effectiveness of FAP as an alternative and low-cost material to remove toxic Pb~(2 ),Cu~(2 ),Zn~(2 )and Cd~(2 )from polluted waters.     

Testing a new rill flow resistance approach using the Water Erosion Prediction Project experimental database

In this paper, a recently theoretically deduced rill flow resistance equation, based on a power‐velocity profile, was tested using the Water Erosion Prediction Project database. This database includes measurements of flow velocity, water depth, cross section area, wetted perimeter, and bed slope that were made in rills shaped on experimental sites distributed across the continental United States. In particular, three different experimental conditions (only rainfall, only flow, and rain with flow) were examined, and for each condition, the theoretically based relationship for estimating the Γ function of the power velocity profile was calibrated. The results established that (a) the Darcy‐Weisbach friction factor can be accurately estimated using the proposed theoretical approach, and (b) the flow resistance increases with the effect of rainfall impact.     

Comparing Beerkan infiltration tests with rainfall simulation experiments for hydraulic characterization of a sandy‐loam soil

Saturated soil hydraulic conductivity, K _s , data collected by ponding infiltrometer methods and usual experimental procedures could be unusable for interpreting field hydrological processes and particularly rainfall infiltration. The K _s values determined by an infiltrometer experiment carried out by applying water at a relatively large distance from the soil surface could however be more appropriate to explain surface runoff generation phenomena during intense rainfall events. In this study, a link between rainfall simulation and ponding infiltrometer experiments was established for a sandy‐loam soil. The height of water pouring for the infiltrometer run was chosen, establishing a similarity between the gravitational potential energy of the applied water, E _p , and the rainfall kinetic energy, E _k . To test the soundness of this procedure, the soil was sampled with the Beerkan estimation of soil transfer parameters procedure of soil hydraulic characterization and two heights of water pouring (0.03 m, i.e., usual procedure, and 0.34 m, yielding E _p  = E _k ). Then, a comparison between experimental steady‐state infiltration rates, i _sR , measured with rainfall simulation experiments determining runoff production and K _s values for the two water pouring heights was carried out in order to discriminate between theoretically possible (i _sR  ≥ K _s ) and impossible (i _sR  < K _s ) situations. Physically possible K _s values were only obtained by applying water at a relatively large distance from the soil surface, because i _sR was equal to 20.0 mm h^?1 and K _s values were 146.2–163.9 and 15.2–18.7 mm h^?1 for a height of water pouring of 0.03 and 0.34 m, respectively. This result suggested the consistency between Beerkan runs with a high height of water pouring and rainfall simulator experiments. Soil compaction and mechanical aggregate breakdown were the most plausible physical mechanisms determining reduction of K _s with height. This study demonstrated that the height from which water is poured onto the soil surface is a key parameter in infiltrometer experiments and can be adapted to mimic the effect of high intensity rain on soil hydraulic properties.     

Clinopyroxene/liquid trace element partitioning in natural trachyte–trachyphonolite systems: insights from Campi Flegrei (southern Italy)

Trace element partition coefficients between clinopyroxenes and associated glassy matrix (^Cpx/L D) have been determined for 13 REE, HFSE^4+,5+, U, Th, Sr, Pb, Sc and V from combined LA-ICP-MS/EMP analyses in selected trachytes and trachyphonolites from Campi Flegrei. Composition of clinopyroxene and glass is pretty homogeneous in the trachyphonolites, pointing to an overall attainment of the equilibrium conditions. In trachytes, conversely, phases show some compositional heterogeneity (due to the presence of clinopyroxene xenocrysts) that requested a more careful petrographic and geochemical inspection of the samples to assess the equilibrium clinopyroxene composition. In the trachyte clinopyroxenes, REE are compatible from Nd to Lu (^Cpx/L D up to 2.9), like Y, Ti, Sc and V. The ^Cpx/L D for Eu is lower than those of the adjacent REE, highlighting Eu²⁺ contribution. High D values are also shown by U, Th, Pb, Zr, Hf, Nb and Ta relatively to basaltic and andesitic systems, whereas the D _Sr is roughly similar to that found for less evolved magmas. Trachyphonolites are characterized by an overall decrease of the ^Cpx/L D for highly-charged cations (with the exception of V), and by a slight increase of D _Sr. REE are still compatible from Nd to Lu (^Cpx/L D up to 2.1), like Ti, Y, Sc and V. This variation is also predicted for REE and Y by models based on the elastic strain theory, being consistent with the slightly lower polymerization degree estimated for the trachyphonolites. However, the observed ^Cpx/L D _(REE,Y) are matched by the modelled ones only considering very low T (≤825°C), which are believed unlikely. This mismatch cannot be attributed to effects induced by the water-rich composition of the trachyte–trachyphonolite suite, since they would lower the observed ^Cpx/L D _(REE,Y). Moreover, the anomalous inflections of measured ^Cpx/L D for HREE suggests some crystal-chemical control, such as the entrance of these elements in a site distinct from M2. It is concluded that the large ^Cpx/L D determined for trachytes and trachyphonolites are likely induced by hitherto unconstrained changes of the Z³⁺ activities related to the composition of melt and/or solid. All these considerations strongly highlight the importance of a direct characterization of trace element partitioning in natural samples from magmatic systems poorly characterized by experimental studies. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Spatial analysis of thickness variability applied to an Early Jurassic carbonate platform in the central Southern Alps (Italy): a tool to unravel syn‐sedimentary faulting

Early Jurassic syn‐sedimentary extensional tectonics in the central Southern Alps controlled patterns of deposition within the Calcari Grigi carbonate platform. We used variogram maps to gather model‐independent information on the spatial distribution of thicknesses of selected platform units and investigated whether major syn‐sedimentary faults outlined subsiding domains during platform growth. Thicknesses display a spatial organization that suggests that large fault belts, often coincident with exposed Jurassic extensional structures, transected large parts of the platform. The network of four fault systems (trending NNW–SSE and NE–SW) displays orthorhombic symmetry, suggesting non‐Andersonian faulting and a true triaxial strain field with N100°E maximum extension or transfer shear zones connecting major NNW–SSE‐trending extensional faults. In both cases, inherited structures of Permian to Triassic age may have played a primary role in Jurassic faulting. If confirmed throughout the South‐Alpine domain, this arrangement could shed new light on Early Jurassic rifting mechanisms in the Southern Alps.