Particle composition and size distributions in and around a deep-pit swine operation,Ames, IA

The contribution of emissions from agricultural facilities is rapidly becoming a major concern for local and regional air quality. Characterization of particle properties such as physical size distribution and chemical composition can be valuable in understanding the processes contributing to emissions and ultimate fate of particulate matter from agricultural facilities. A measurement campaign was conducted at an Iowa, deep-pit, three-barn swine finishing facility to characterize near-source ambient particulate matter. Size-specific mass concentrations were determined using minivol samplers, with additional size distribution information obtain using optical particle counters. Particulate composition was determined via ion chromatographic analysis of the collected filters. A thermal-CO₂ elemental/organic carbon analyzer measured particulate carbon. The chemical composition and size distribution of sub-micron particles were determined via real-time aerosol mass spectrometry. Primary particulate was not found to be a major emission from the examined facility, with filter-based impactor samples showing average near-source increases (~15–50 m) in ambient PM₁₀ of 5.8 ± 2.9 μg m⁻³ above background levels. PM_2.5 also showed contribution attributable to the facility (1.7 ± 1.1 μg m⁻³). Optical particle counter analysis of the numerical size distributions showed bimodal distributions for both the upwind and downwind conditions, with maximums around 2.5 μm and below the minimum quantified diameter of 0.3 μm. The distributions showed increased numbers of coarse particles (PM₁₀) during periods when wind transport came from the barns, but the differences were not statistically significant at the 95% confidence level. The PM₁₀ aerosols showed statistically increased concentrations of sulfate, nitrate, ammonium, calcium, organic carbon, and elemental carbon when the samplers were downwind from the pig barns. Organic carbon was the major constituent of the barn-impacted particulate matter in both sub-micron (54%) and coarse size (20%) ranges. The AMS PM₁ chemical speciation showed similar species increases, with the exception of and Ca⁺², the latter not quantified by the AMS.     

Mid-level clouds over the Sahara in a convection-permitting regional model

Climate Dynamics - The simulation of Saharan mid tropospheric clouds is investigated with the weather research and forecasting (WRF) regional atmospheric model at convection permitting...     

Refined conceptualization of TOPMODEL for shallow subsurface flows

The TOPMODEL framework was used to derive expressions that account for saturated and unsaturated flow through shallow soil on a hillslope. The resulting equations were the basis for a shallow‐soil TOPMODEL (STOPMODEL). The common TOPMODEL theory implicitly assumes a water table below the entire watershed and this does not conceptually apply to systems hydrologically controlled by shallow interflow of perched groundwater. STOPMODEL provides an approach for extending TOPMODEL's conceptualization to apply to shallow, interflow‐driven watersheds by using soil moisture deficit instead of water table depth as the state variable. Deriving STOPMODEL by using a hydraulic conductivity function that changes exponentially with soil moisture content results in equations that look very similar to those commonly associated with TOPMODEL. This alternative way of conceptualizing TOPMODEL makes the modelling approach available to researchers, planners, and engineers who work in areas where TOPMODEL was previously believed to be unsuited, such as the New York City Watershed in the Catskills region of New York State. Copyright © 2002 John Wiley & Sons, Ltd.     

Mycorrhizal Colonization Affects the Survival of Vetiveria zizanioides (L.) Nash Grown in Water Containing As(III)

The presence of arsenic (As) in water is of great public concern. Arsenic exists in three common valence states viz., As(0) metalloid arsenic, As(III) (arsenite) and As(V) (arsenate). Arsenite [As(III)] is the most toxic form among arsenicals which, predominates in anaerobic conditions, generally in flooded soils and in the water with high BOD. Experiments were conducted to investigate the effect of As(III) on the mycorrhization in vetiver (Vetiveria zizanioides (L.) Nash) grass in hydroponics. Studies showed significant alteration in the mycorrhizal colonization in the roots of vetiver exposed to higher concentrations of As(III) starting from 1.0, 2.0, 3.0, 4.0 to 5.0 mg/L prepared in 5% Hoagland nutrient solution without addition of phosphate ions. Considerable reduction in the mycorrhizal intensity (M) was observed in all the treatment sets as compared to the control suggesting a negative impact of the As(III) on the mycorrhizal association. Simultaneously, the study also showed that, As(III) is toxic to the vetiver plants having mycorrhizal association however plants with non‐mycorrhizal (cleansed) roots were found to be able to survive for a longer period exposed to As(III).     

Statistical framework for scale-up of dispersivity in multi-scale heterogeneous media

A hierarchical scale-up framework is formulated to study the scaling characteristics of reservoir attributes and input dispersivities at the transport modeling scale, where heterogeneity distribution exhibits both non-stationarity (trend) and sub-scale variability. The proposed method is flexible to handle heterogeneities occurring at multiple scales, without any explicit assumption regarding the multivariate distribution of the heterogeneity. This paper extends our previous work by incorporating the effects of non-stationarity into the modeling workflow. Rock property at a given location is modeled as a random variable, which is decomposed into the sum of a trend (available on the same resolution of the transport modeling scale) and a residual component (defined at a much smaller scale). First, to scale up the residual component to the transport modeling scale, the corresponding volume variance is computed; by sampling numerous sets of “conditioning data” via bootstrapping and constructing multiple realizations of the residual components at the transport modeling, uncertainty due to this scale-up process is captured. Next, to compute the input dispersivity at the transport modeling scale, a flow-based technique is adopted: multiple geostatistical realizations of the same physical size as the transport modeling scale are generated to describe the spatial heterogeneity below the modeling scale. Each realization is subjected to particle-tracking simulation. Effective longitudinal and transverse dispersivities are estimated by minimizing the difference in effluent history for each realization and that of an equivalent average medium. Probability distributions of effective dispersivities are established by aggregating results from all realizations. The results demonstrate that both large-scale non-stationarity and sub-scale variability are both contributing to anomalous non-Fickian behavior. In comparison with our previous work, which ignored large-scale non-stationarity, the non-Fickian characteristics observed in this study is dramatically more pronounced.     

Sediment storage and release from Himalayan piggyback basins and implications for downstream river morphology and evolution

Piggyback basins developed at the mountain fronts of collisional orogens can act as important, and transient, sediment stores along major river systems. It is not clear, however, how the storage and release of sediment in piggyback basins affects the sediment flux and evolution of downstream river reaches. Here, we investigate the timing and volumes of sediment storage and release in the Dehra Dun, a piggyback basin developed along the Himalayan mountain front in northwestern India. Based on OSL dating, we show evidence for three major phases of aggradation in the dun, bracketed at ca. 41–33 ka, 34–21 ka and 23–10 ka, each accompanied by progradation of sediment fans into the dun. Each of these phases was followed by backfilling and (apparently) rapid fan‐head incision, leading to abandonment of the depositional unit and a basinward shift of the active depocentre. Excavation of dun sediment after the second and third phases of aggradation produced time‐averaged sediment discharges that were ca. 1–2% of the modern suspended‐sediment discharges of the Ganga and Yamuna rivers that traverse the margins of the dun; this sediment was derived from catchment areas that together comprise 1.5% of the drainage area of these rivers. Comparison of the timing of dun storage and release with upstream and downstream records of incision and aggradation in the Ganga show that sediment storage in the dun generally coincides with periods of widespread hinterland aggradation but that late stages of dun aggradation, and especially times of dun sediment excavation, coincide with major periods of sediment export to the Ganga Basin. The dun thus acts to amplify temporal variations in hinterland sediment supply or transport capacity. This conceptual model appears to explain morphological features of other major river systems along the Himalayan front, including the Gandak and Kosi Rivers, and may be important for understanding sediment flux variations in other collisional mountain belts.     

Response of active tectonics on the alluvial Baghmati River, Himalayan foreland basin, eastern India

Active tectonics in a basin plays an important role in controlling a fluvial system through the change in channel slope. The Baghmati, an anabranching, foothills-fed river system, draining the plains of north Bihar in eastern India has responded to ongoing tectonic deformation in the basin. The relatively flat alluvial plains are traversed by several active subsurface faults, which divide the area in four tectonic blocks. Each tectonic block is characterized by association of fluvial anomalies viz. compressed meanders, knick point in longitudinal profiles, channel incision, anomalous sinuosity variations, sudden change in river flow direction, river flow against the local gradient and distribution of overbank flooding, lakes, and waterlogged area. Such fluvial anomalies have been identified on the repetitive satellite images and maps and interpreted through DEM and field observations to understand the nature of vertical movements in the area. The sub-surface faults in the Baghmati plains cut across the river channel and also run parallel which have allowed us to observe the effects of longitudinal and lateral tilting manifested in avulsions and morphological changes.     

Terrestrial laser scanning to estimate plot-level forest canopy fuel properties

This paper evaluates the potential of a terrestrial laser scanner (TLS) to characterize forest canopy fuel characteristics at plot level. Several canopy properties, namely canopy height, canopy cover, canopy base height and fuel strata gap were estimated. Different approaches were tested to avoid the effect of canopy shadowing on canopy height estimation caused by deployment of the TLS below the canopy. Estimation of canopy height using a grid approach provided a coefficient of determination of R² = 0.81 and an RMSE of 2.47 m. A similar RMSE was obtained using the 99th percentile of the height distribution of the highest points, representing the 1% of the data, although the coefficient of determination was lower (R² = 0.70). Canopy cover (CC) was estimated as a function of the occupied cells of a grid superimposed upon the TLS point clouds. It was found that CC estimates were dependent on the cell size selected, with 3 cm being the optimum resolution for this study. The effect of the zenith view angle on CC estimates was also analyzed. A simple method was developed to estimate canopy base height from the vegetation vertical profiles derived from an occupied/non-occupied voxels approach. Canopy base height was estimated with an RMSE of 3.09 m and an R² = 0.86. Terrestrial laser scanning also provides a unique opportunity to estimate the fuel strata gap (FSG), which has not been previously derived from remotely sensed data. The FSG was also derived from the vegetation vertical profile with an RMSE of 1.53 m and an R² = 0.87.     

Estimation of snow and glacial melt contribution through stable isotopes and assessment of its impact on river morphology through stream power approach in two Himalayan river basins

The impact of increased temperature on the Third Pole, as the Himalayas is referred to, and the likely cascading impacts on the general downstream hydrology have been widely noted. However, the impact on fluvial geomorphology has not received specific attention. Change in the glacial domain in terms of melt increase will change discharge and sediment flux into fluvial system, which will induce changes in fluvial processes and forms. The present work attempts to study this process-based glacio-fluvial coupling in the two neighbouring glaciated river basins in the Northwest Himalaya, viz., the Sutlej and the Yamuna river basins till the mountain front. A total of 194 samples of river, tributary and groundwater of pre- and post-monsoon seasons in the two river basins were analysed for stable isotopes. The trend of δ¹⁸O and electrical conductivity along the mainstream gives qualitative idea on the influence of headwaters in the downstream of the catchment thereby allowing inference on melt contribution. Further, two component mixing model using stable oxygen isotope of two seasons water samples showed that melt contributes about 41.1–66.8 and 6.6–10.6% at different points to the total river discharge in the Sutlej and the Tons River (the glaciated, major tributary of the Yamuna River) basins, respectively. For different scenarios of increase in melt, stream power increase in the Sutlej River basin is significant as opposed to the Tons River. River channel in the Sutlej River basin will be significantly more impacted in comparison with the Yamuna River system.     

A Comprehensive Review on Microalgae-Based Biorefinery as Two-Way Source of Wastewater Treatment and Bioresource Recovery

In the past few years, microalgae have gained huge recognition from the scientific community due to their potential applications in the production of a broad array of bio-based products varying from biofuels to nanoparticles. Due to their elevated growth rate, high tolerance to various types of abiotic stresses, and complex metabolic capacity, microalgae can be used as promising tools for the attainment of a circular bioeconomy. Moreover, they can simply utilize nutrients from wastewater for biorefinery purposes, resulting in resource recovery coupled with wastewater treatment. However, due to their sub-optimal yields and high production costs, microalgae-based bio-products have not yet been commercialized. This review provides insights into the employment of microalgae as an efficient bioresource for the treatment of wastewater with simultaneous enactment as a biorefinery to produce biofuels, biochar, bioplastic, fertilizers, and other high-value bioproducts. Furthermore, the application of microalgal nanoparticles in wastewater treatment and prospects for genetic modification of microalgae for enhanced biorefinery capabilities have also been briefly highlighted.