Diffusion of divalent cations in garnet: multi-couple experiments

We demonstrate the possibility of studying several diffusion couples in a single run, i.e. under almost similar P–T–t– conditions, allowing direct comparison of the diffusion rates in different diffusion couples. Thus the duration of experimental study and the risk of failure of expensive experimental equipment can be decreased considerably. The diffusion experiments were carried out in piston-cylinder apparatus. Gem-quality garnets of almandine, spessartine and grossular compositions together with inclusion-rich eclogitic garnets were embedded in a powder of natural pyrope and annealed together under dry conditions at P = 1.9–3.2 GPa and T = 1,070–1,400°C. Diffusion profiles were measured by electron microprobe and fitted numerically on the basis of multicomponent diffusion theory. The datasets derived from different diffusion couples yields parameters of the Arrhenius equation for Ca, Mg and Fe in natural eclogitic garnets and Mg, Mn and Fe in gem-quality garnets. We have also studied the effect of grain-boundary diffusion in the sintered pyrope matrix on interdiffusion on the basis of 2D modeling. Under conditions analogous to those of our experimental runs, we show that observed irregularities in some measured diffusion profiles (not applied for the diffusion modeling) can be directly related to the superposition of local grain-boundary diffusion on dominant volume diffusion.     

Geometric interpretation for the spectral stability in the charged three-body problem

We present a geometric interpretation of the spectral stability of the triangular libration points in the charged three-body problem. We obtain that the spectral stability varies with the position of the center of mass of the three charges with respect to the circumcenter of the triangle configuration, which does not depend directly of the charges. If the center of mass is outside or on the circumference of a well defined radius ??, then spectral stability occurs. In addition, we analyze the existence of resonances within the spectral region of stability under this geometric interpretation, determining resonance curves of order 2, 3, 4, . . ., some of them with multiple resonances.     

P–T–t estimation of deformation in low‐grade quartz‐feldspar‐bearing rocks using thermodynamic modelling and 40Ar/39Ar dating techniques: example of the Plan‐de‐Phasy shear zone unit (Briançonnais Zone,Western Alps)

Pressure–Temperature–time (P–T–t) estimates of the syn‐kinematic strain at the peak‐pressure conditions reached during shallow underthrusting of the Briançonnais Zone in the Alpine subduction zone was made by thermodynamic modelling and ⁴⁰Ar/³⁹Ar dating in the Plan‐de‐Phasy unit (SE of the Pelvoux Massif, Western Alps). The dated phengite minerals crystallized syn‐kinematically in a shear zone indicating top‐to‐the‐N motion. By combining X‐ray mapping with multi‐equilibrium calculations, we estimate the phengite crystallization conditions at 270 ± 50 °C and 8.1 ± 2 kbar at an age of 45.9 ± 1.1 Ma. Combining this P–T–t estimate with data from the literature allows us to constrain the timing and geometry of Alpine continental subduction. We propose that the Briançonnais units were scalped on top of the slab during ongoing continental subduction and exhumed continuously until collision.     

Local site effect microzonation of Lorca town (SE Spain)

Local site effect assessment based on subsurface ground conditions is often the key to evaluate urban seismic hazard. The site effect evaluation in Lorca town (south-eastern Spain) started with a classification of urban geology through the geological mapping at scale 1:10,000 and the use of geotechnical data and geophysical surveys. The 17 geological formations identified were classified into 5 geological/seismic formations according to their seismic amplification capacity obtained from ambient vibration measurements as well as from simultaneous strong motion records. The shear-wave velocity structure of each geological/seismic formation was evaluated by means of inversion of Rayleigh wave dispersion data obtained from vertical-component array records of ambient noise. Nakamura’s method was applied to determine a predominant period distribution map. The spectral amplification factors were fourfold the values recorded in a reference hard-rock site. Finally, the capability of this study for explaining the damage distribution caused by the May 11th, 2011 Lorca destructive earthquake (Mw \(=\) 5.2) was examined. The methods used in this work are of assistance to evaluate ground amplification phenomena in urban areas of complex geology as Lorca town due to future earthquakes with applicability on urban seismic risk management.     

Trace elements in Holocene sediments of the southern Doñana National Park (SW Spain): historical pollution and applications

The multidisciplinary analysis of core sediments from Doñana National Park, south Spain, permits to delimitate both the paleoenvironmental changes and the geochemical evolution of this area during the Holocene. In a first phase (10–6.5 kyr cal), this area was occupied by freshwater/brackish marshes with periodical alternation of dry periods and humid intervals. In a second phase, these marshes were inundated during the Flandrian transgression (~6.5 kyr cal), with the deposition of bioclastic sands. The third phase (6.5–3.6 kyr cal) is characterized by the transition to an old lagoon, with unpolluted, bottom sediments. The geochemical concentrations of these clayey sediments can be used as a geochemical background for present-day and future environmental evaluations of this area. In the following 600 years approximately, two tsunamis caused the partial infilling of this area with bioclastic, marine sediments. In the interval comprised between these two tsunamis, this lagoon was polluted with heavy metals derived from historical mining activities. This environmental contamination represents one of the oldest evidences of mining pollution in the world (>3 kyr cal BP).     

Dating of granulites involved in the hercynian fold-belt of Europe: An example taken from the granulite-facies orthogneisses at La Picherais,Southern Armorican Massif,France

Situated within the crystalline metamorphic complex of Champtoceaux NE of Nantes, the orthogneiss of La Picherais (near St Mars-du-Désert, Loire Atlantique, France) show relicts of a granulite facies paragenesis. Comparison with other granulitic rocks in the Hercynian fold-belt suggest possible ages ranging from Lower Proterozoic to Phanerozoic. The Rb-Sr whole rock method yields an errorchron of 570±110 m.y. for the Picherais orthogneiss, whereas the U-Pb zircon method indicates an upper intersection on Concordia at 1,880±120 m.y. and a lower intersection at 423±10 m.y. Several interpretations are possible for these data: the granite emplacement age was (1) 1,900 m.y. ago. (2) more likely Upper Proterozoic — Lower Palaeozoic. The zircons concordant at 1,900 m.y. were either present in the granitic magma at its time of origin or were introduced into the magma during emplacement. These zircons could be derived from sedimentary horizons such as found in the Lower Ordovician sandstones of the Armorican massif whose zircon age data are presented here.     

Cookeite LiAl4(Si3Al)O10(OH)8: Experimental study and thermodynamical analysis of its compatibility relations in the Li2O−Al2O3−SiO2−H2O system

Three reactions limiting the stability field of the di-trioctahedral chlorite cookeite in the presence of quartz, in the system Li₂O−Al₂O₃−SiO₂−H₂O (LASH) have been reversed in the range 290–480°C, 0.8–14 kbar, using natural material close to the end member composition. Combining our results with known and estimated thermodynamic properties of the other minerals belonging to the LASH system, the enthalpy (-8512200 J/mol) and the entropy (504.8 J/mol^*K) of cookeite are calculated by a feasible solution space approach. The knowledge of these values allowed us to draw the first P−T phase diagram involving both the hydrated Li-aluminosilicates cookeite and bikitaite, which is applicable to a large variety of natural rock systems. The low thermal extent of the stability field of cookeite+quartz (260–480°C) makes cookeite a valuable indicator of low temperature conditions within a wide range of pressure (1–14 kbar).