Optimisation of a catalytic procedure for the determination of total iodine in seawater

A precise method for the determination of total iodine in seawater, which uses a Technicon Auto-Analyser II system and is based on Truesdale and Spencer's (1974) and Truesdale and Smith's (1975) earlier works with a catalytic procedure, is described. The procedure operates over a range of 30–80 μg1^?1 of iodine. As requested by Mark (1973), the way in which the procedure can be varied to suit other applications, and therefore ranges, is explained in detail. The standard deviation at the 50 μg1^?1 level was found to be 0.12 μ1^?1 showing that the method's precision exceeds most, if not all, previously published procedures for this variable. This high degree of resolution makes the procedure suitable for oceanic investigations. The effects of varying the reaction time, the temperature at which the reaction proceeds and the salinity of samples and standards are described. The advantages of using a Technicon Auto-Analyser II system rather than an Auto-Analyser I system are discussed. With slight modification the procedure can also be used in the measurement of river flow where sodium iodide is used as tracer in the dilution method.     

Miocene extensional detachments in the outcropping basement of the northern Alboran Basin (Betics) and their tectonic implications

Whether or not there are extensional detachment faults in the Alboran basement can be tested directly because a part of the Alboran Basin is now emerged. These detachments, related to crustal thinning beneath the Alboran Basin, occurred from the Aquitanian to Tortonian. The resulting extensional geometries can be described in general terms. During the Serravalian a considerable southwest extension of the basin took place, accompanied by south-southeast extension in the northern Gibraltar Arc. Other detachments affected by Serravalian extension can be found. The spreading of the Alboran was nearly coeval with roughly westward migration of the Gibraltar mountain front.     

Primary production in the eastern tropical Pacific: A review

The eastern tropical Pacific includes 28 million km² of ocean between 23.5°N and S and Central/South America and 140°W, and contains the eastern and equatorial branches of the north and South Pacific subtropical gyres plus two equatorial and two coastal countercurrents. Spatial patterns of primary production are in general determined by supply of macronutrients (nitrate, phosphate) from below the thermocline. Where the thermocline is shallow and intersects the lighted euphotic zone, biological production is enhanced. In the eastern tropical Pacific thermocline depth is controlled by three interrelated processes: a basin-scale east/west thermocline tilt, a basin-scale thermocline shoaling at the gyre margins, and local wind-driven upwelling. These processes regulate supply of nutrient-rich subsurface waters to the euphotic zone, and on their basis we have divided the eastern tropical Pacific into seven main regions. Primary production and its physical and chemical controls are described for each.Enhanced rates of macronutrient supply maintains levels of primary production in the eastern tropical Pacific above those of the oligotrophic subtropical gyres to the north and south. On the other hand lack of the micronutrient iron limits phytoplankton growth (and nitrogen fixation) over large portions of the open-ocean eastern tropical Pacific, depressing rates of primary production and resulting in the so-called high nitrate-low chlorophyll condition. Very high rates of primary production can occur in those coastal areas where both macronutrients and iron are supplied in abundance to surface waters. In these eutrophic coastal areas large phytoplankton cells dominate; conversely, in the open-ocean small cells are dominant. In a ‘shadow zone’ between the subtropical gyres with limited subsurface ventilation, enough production sinks and decays to produce anoxic and denitrified waters which spread beneath very large parts of the eastern tropical Pacific.Seasonal cycles are weak over much of the open-ocean eastern tropical Pacific, although several eutrophic coastal areas do exhibit substantial seasonality. The ENSO fluctuation, however, is an exceedingly important source of interannual variability in this region. El Niño in general results in a depressed thermocline and thus reduced rates of macronutrient supply and primary production. The multi-decadal PDO is likely also an important source of variability, with the ‘El Viejo’ phase of the PDO resulting in warmer and lower nutrient and productivity conditions similar to El Niño.On average the eastern tropical Pacific is moderately productive and, relative to Pacific and global means, its productivity and area are roughly equivalent. For example, it occupies about 18% of the Pacific Ocean by area and accounts for 22–23% of its productivity. Similarly, it occupies about 9% of the global ocean and accounts for 10% of its productivity. While representative, these average values obscure very substantial spatial and temporal variability that characterizes the dynamics of this tropical ocean.     

Growth of the Mediterranean Gorgonian Lophogorgia ceratophyta (L., 1758)

Abstract. Growth of the shallow-water gorgonian Lophogorgia ceratophyta was investigated in an infralittoral station located in La Spezia Gulf, Ligurian Sea. Mean annual height growth rate was estimated to be 2.57 cm · a^-1. The fractal dimension of the colonies was found to gradually evolve in complexity, exhibiting a simpler branching pattern in younger specimens. The maintenance of a low, invariable ramification complexity as an optimal choice in managing relationships between water and the colony's living tissues is also discussed.     

The influence of island generated eddies on the carbon dioxide system, south of the Canary Islands

Measurements of surface partial pressure of CO₂ and water column alkalinity, pH_T, nutrients, oxygen, fluorescence and hydrography were carried out, south of the Canary Islands during September 1998. Cyclonic and anticyclonic eddies were alternatively observed from the northwestern area to the central area of the Canary Islands. Nutrient pumping and vertical uplifting of the deep chlorophyll maximum by cyclonic eddies were also ascertained by upward displacement of dissolved inorganic carbon. A model was applied to determine the net inorganic carbon balance in the cyclonic eddy. The fluxes were determined considering both the diffusive and convective contributions from the upward pumping and the corresponding horizontal transport of water outside the area. An increase in the total inorganic carbon concentration in the upper layers inside the eddy field of 133 mmol C m^− 2 d^− 1 was determined. The upward flux of inorganic carbon decreased the effect of the increased primary production on the carbon dioxide chemistry. The reduced fCO₂ inside the cyclonic eddy, 15 μatm lower than that observed in non-affected surface water, was explained by thermodynamic aspects, biological activity, eddy upward pumping and diffusion and air–sea water exchange effects.     

Stratigraphic framework of gas accumulations in the Ría de Pontevedra (NW Spain)

Knowledge of marine geological environments in which shallow gas is accumulating is becoming increasingly important in global studies of climate change because a measurable proportion of the total methane source comes from continental margins. Previous studies have revealed that coastal environments represent important geological environments where microbial methane is being generated, is accumulating, and is being released. In the Ría de Pontevedra, at least 4.5 km² of seafloor in the innermost part of the ría is underlain by sediments containing natural gas. Seismic interpretation contributes new findings for the definition of periods and geological environments in which the gas could have been generated, and is accumulating and released in the Ría de Pontevedra. Groundtruthing the seismic data (facies, environments) makes it possible to identify favourable geological environments for gas generation in the sedimentary infill of the Ría de Pontevedra. Sequence stratigraphy based on high-resolution seismic profiles and post-Last Glacial Maximum sea-level records makes it possible to establish the stratigraphic architecture of the ría and to define the periods in which gas could have been generated. The results of this study show that the sedimentary infill is composed of a fifth-order sequence developed since the Last Glacial Maximum. Within this sequence, gas appears to have accumulated in the Holocene deposits associated with the latest transgressive and highstand system tracts. Seismic analysis shows that gas could have been generated in different geological environments in the Ría de Pontevedra. If coastal environments at times of lower sea level were similar to those of the present, organic-rich mud deposits (deposited mainly in lakes, estuaries and floodplains) could have survived transgression and remained buried as potential gas sources in the inner part of the ría.     

Spin rate estimation of sounding rockets using GPS wind-up

Carrier phase wind-up is a well-known effect that arises from the relative rotation between a transmitting and receiving antenna. In GPS measurements at L1 frequency, this effect translates into an error of 19.029 cm per full relative rotation of antennas. Since this effect is independent of the satellite elevation for pure rotation about the antenna boresight axis, it is usually absorbed by the clock estimation in navigation algorithms. Therefore, the impact of wind-up is usually neglected for applications that do not require accuracies to the cm level like RTK. However, in receiving platforms with high rotation rate, the accumulated wind-up value can be important and actually be larger than receiver noise or even ionospheric variations. Therefore, in such scenarios, the wind-up contribution can be isolated and used as a source of information to compute the spin rate of such platforms using an appropriate combination of GPS observables. This work shows some results of a coarse, yet simple, approach to monitor the rotation angle and spin-rate of spin stabilized sounding rockets flown by DLR.     

Presence of Hippidion at two sites of western Argentina: Diet composition and contribution to the study of the extinction of Pleistocene megafauna

The composition of Hippidion diet, and possible changes that could relate to its extinction, were evaluated in the Argentinean-Chilean Central Andes, a Neotropical environment characterized by arid to semiarid conditions (Andean hot and cold deserts). Microhistological analyses were made on feces of Hippidion found at Los Morrillos (31°43′S–68°42′W, 3000 m a.s.l.) and Gruta del Indio (34°35′S, 68°22′W, 660 m a.s.l.). At Gruta del Indio the diet of Hippidion was based mainly on woody species. At Los Morrillos, it was based on herbaceous species.This flexibility in diet composition could be a relative adaptive advantage allowing a longer permanence of this species in comparison to others recorded in the region (such as Megatheriumand Mylodon). Nevertheless, this advantage was not enough to guarantee its survival during the Holocene. Extinction could have been affected by diverse agents, such as growing aridification of the area, increasing competition with other species (mainly Lama guanicoe), and human presence, along with a relatively low population density (as expected from the limited presence of Hippidion at the archaeological and palaeontological sites of South America. At Gruta del Indio significant changes in the diet of Hippidion corresponding to different intervals of the period 31,000–9000 ¹⁴C BP are not evident. Given this evidence for similar diets for Hippidion throughout the late Quaternary, other factors need to be considered to explain the extinction of this horse.     

Tectonic Evolution and Continental Growth in Altai Orogen, China: Constrained by Geochronology and Nd Isotopic Mapping of Intrusions

The Central Asia Orogenic Belt is the world's largest Phanerozoic accretionary orogen. The Altai orogen was key to understand the orogeny. Voluminous intrusions occur in the Chinese Altai orogen.     

Simulations of 3D DC borehole resistivity measurements with a goal-oriented <Emphasis Type="Italic">hp</Emphasis> finite-element method. Part II: through-casing resistivity instruments

We simulate direct current (DC) borehole resistivity measurements acquired in steel-cased deviated wells for the assessment of rock formation properties. The assumed data acquisition configuration considers one current (emitter) and three voltage (collector) electrodes that are utilized to measure the second difference of the electric potential along the well trajectory. We assume a homogeneous, 1.27-cm-thick steel casing with resistivity equal to 10^− 5 Ω· m. Simulations are performed with two different numerical methodologies. The first one is based on transferring two-dimensional (2D) axisymmetric optimal grids to a three-dimensional (3D) simulation software. The second one automatically produces optimal 3D grids yielded by a 3D self-adaptive goal-oriented algorithm. Both methodologies utilize high-order finite elements (FE) that are specially well-suited for problems with high-contrast coefficients and rapid spatial variations of the electric field, as it occurs in simulations that involve steel-cased wells. The method based on transferring 2D-optimal grids is efficient in terms of CPU time (few seconds per logging position). Unfortunately, it may produce inaccurate 3D simulations in deviated wells, even though the error remains below 1% for the axisymmetric (vertical) well. The method based on optimal 3D grids, although less efficient in terms of CPU time (few hours per logging position), produces more accurate results that are validated by a built-in a posteriori error estimator. This paper provides the first existing simulations of through-casing resistivity measurements in deviated wells. Simulated resistivity measurements indicate that, for a 30° deviated well, measurements in conductive layers 0.01 Ω· m) are similar to those obtained in vertical wells. However, in resistive layers (10,000 Ω· m), we observe 100% larger readings in the 30° deviated well. This difference becomes 3,000% for the case of a 60° deviated well. For this highly-deviated well, readings corresponding to the conductive formation layer are about 30% smaller in magnitude than those in a vertical well. Shoulder effects significantly vary in deviated wells.